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317L Stainless Steel (UNS S31703): Composition, Properties, and Uses

Introduction

In the ever-evolving world of materials science, stainless steel continues to stand out as a versatile and indispensable alloy. Among its many grades, 317L stainless steel (UNS S31703) captures attention for its exceptional corrosion resistance and durability. This low-carbon variant of 317 stainless steel is specifically engineered to withstand harsh environments, making it a popular choice in industries ranging from chemical processing to marine applications. In this article, we will delve into the composition and properties of 317L stainless steel, exploring its unique characteristics that set it apart from other grades. Additionally, we will examine its diverse applications, shedding light on why this alloy is a preferred material for engineers and manufacturers alike. Whether you’re a professional in the field or simply curious about the science behind this remarkable metal, join us as we uncover the essential aspects of 317L stainless steel and its significant role in modern manufacturing.

Introduction

Overview of 317L Stainless Steel

317L stainless steel, also known as UNS S31703, is a high-performance, low-carbon austenitic stainless steel. Renowned for its superior corrosion resistance and excellent mechanical properties, 317L is crucial in various demanding industrial applications due to its high molybdenum content. This molybdenum content makes it highly resistant to pitting and crevice corrosion, especially in environments with chlorides and other halides.

Importance of 317L Stainless Steel

The development and use of 317L stainless steel address the need for materials that withstand harsh chemical environments while maintaining their structural integrity. Its superior corrosion resistance makes it perfect for applications in chemical processing, petrochemical industries, and other areas where aggressive chemicals are prevalent. Additionally, the low carbon content prevents sensitization during welding, reducing the risk of intergranular corrosion and making it a preferred choice for welded structures.

Comparison with Other Stainless Steel Grades

Compared to grades like 304 and 316L, 317L offers better performance in corrosive environments due to higher chromium, nickel, and molybdenum levels. These elements help resist attacks from acids such as sulfuric, phosphoric, and acetic acids. While 316L is also known for its corrosion resistance, 317L provides even greater protection, especially against pitting and crevice corrosion.

Applications and Versatility

Beyond chemical processing, 317L stainless steel’s unique properties make it suitable for power generation, food and beverage processing, pulp and paper manufacturing, and marine environments. Its versatility and durability ensure it meets the stringent requirements of these industries, providing long-lasting performance and reliability.

Key Attributes

  • Exceptional corrosion resistance in environments with chlorides and sulfuric acid.
  • High tensile and yield strength, good elongation, and hardness ensure robustness.
  • Low carbon content reduces intergranular corrosion risk, making it ideal for welding.
  • Maintains structural integrity and resists oxidation at high temperatures.

Chemical Composition

Chemical Composition of 317L Stainless Steel

The chemical composition of 317L stainless steel is crucial for its high performance and corrosion resistance. This low-carbon austenitic alloy consists primarily of iron and several key elements that significantly enhance its properties.

  • Carbon (C): Limited to a maximum of 0.030%, it helps prevent intergranular corrosion during welding.
  • Manganese (Mn): Present up to 2.00%, it enhances the steel’s strength and toughness.
  • Silicon (Si): Capped at 0.75%, it improves oxidation resistance and casting fluidity.
  • Chromium (Cr): Ranging from 18.00% to 20.00%, it provides significant corrosion resistance and strength.
  • Nickel (Ni): With a range of 11.00% to 15.00%, it improves ductility and toughness.
  • Molybdenum (Mo): Between 3.00% and 4.00%, it enhances resistance to pitting and crevice corrosion in chloride environments.
  • Phosphorus (P): Limited to 0.045%, it helps improve machinability.
  • Sulfur (S): Capped at 0.030%, it can enhance machinability but must be controlled to prevent brittleness.
  • Nitrogen (N): Present in 0.10% to 0.20%, it increases strength and corrosion resistance.
  • Iron (Fe): The main component, making up the balance of the alloy.

Compared to 316L and 304 stainless steels, 317L features a higher molybdenum content, which improves performance in corrosive environments, especially those with chlorides. Additionally, the elevated levels of chromium and nickel enhance its mechanical properties and resistance to acids. The precise balance of these elements ensures that 317L stainless steel meets the demands of harsh chemical environments while maintaining durability and structural integrity.

Physical and Mechanical Properties

Physical and Mechanical Properties of 317L Stainless Steel

Tensile Strength

317L stainless steel is known for its excellent tensile strength, which measures the maximum stress it can endure while being stretched or pulled before breaking. With an ultimate tensile strength (UTS) of at least 75 ksi (kilopounds per square inch), 317L is ideal for applications requiring high strength and durability.

Yield Strength

The yield strength of 317L stainless steel, indicating the stress at which it starts to deform plastically, is a minimum of 30 ksi. This ensures the material maintains its shape and structural integrity under substantial loads.

Elongation

Elongation measures how much the steel can stretch before breaking. With a minimum elongation of 40% over 2 inches, 317L demonstrates excellent ductility, making it ideal for forming and shaping without cracking.

Hardness

317L stainless steel has a maximum Rockwell B hardness of 95 and a Brinell hardness of 217, reflecting its resistance to deformation and wear, essential for abrasive environments.

Density

The density of 317L stainless steel is around 0.285 lb/in³, typical for austenitic stainless steels, balancing strength and weight for various structural and industrial applications.

Thermal Conductivity

With a thermal conductivity of 8.7 Btu/ft hr°F, 317L stainless steel efficiently conducts heat, important for heat exchangers and thermal systems.

Electrical Resistivity

The electrical resistivity of 317L stainless steel is 33.5 x 10^-6 Ω-inch, crucial for managing electrical conductivity in components and enclosures.

Coefficient of Thermal Expansion

The coefficient of thermal expansion for 317L stainless steel varies with temperature, from 9.2 to 10.8 x 10^-6 in/in-°F, indicating how much it expands or contracts with temperature changes.

Specific Heat

The specific heat capacity of 317L stainless steel is 0.11 Btu/lbm-°F at 32 – 212°F, measuring the heat energy needed to raise its temperature, vital for thermal management applications.

Summary of Key Properties

  • Ultimate Tensile Strength: 75 ksi minimum
  • Yield Strength: 30 ksi minimum
  • Elongation: 40% minimum in 2 inches
  • Hardness: Rockwell B: 95 max; Brinell: 217 max
  • Density: 0.285 lb/in³
  • Thermal Conductivity: 8.7 Btu/ft hr°F
  • Electrical Resistivity: 33.5 x 10^-6 Ω-inch
  • Coefficient of Thermal Expansion: 9.2 to 10.8 x 10^-6 in/in-°F
  • Specific Heat: 0.11 Btu/lbm-°F at 32 – 212°F

These physical and mechanical properties make 317L stainless steel a versatile and reliable material for a wide range of industrial applications, particularly those requiring high strength, durability, and resistance to extreme conditions.

Corrosion Resistance

Exceptional Corrosion Resistance of 317L Stainless Steel

317L stainless steel is highly regarded for its exceptional corrosion resistance, making it a popular choice in industries facing harsh environments. Its high chromium content, along with molybdenum and nickel, enhances its ability to resist corrosion from aggressive chemicals.

Resistance to Specific Acids

The alloy is particularly effective against a range of acids, including:

  • Sulfuric Acid: 317L can handle sulfuric acid concentrations up to 5% at temperatures around 120°F (49°C), and it can withstand higher concentrations at lower temperatures.
  • Phosphoric Acid: This stainless steel grade shows good resistance to phosphoric acid, making it suitable for applications in the food and pharmaceutical industries.
  • Chloride Environments: The molybdenum content improves resistance to pitting and crevice corrosion, particularly in environments with chlorides, which are known to cause localized corrosion in stainless steels.

Pitting and Crevice Corrosion Resistance

The higher molybdenum levels in 317L contribute to its superior resistance to pitting and crevice corrosion, especially in chloride-laden environments. This capability is quantified by its Pitting Resistance Equivalent Number (PREN), which is significantly higher than that of 304 and 316 stainless steels. The PREN value indicates the alloy’s ability to withstand localized corrosion, ensuring longevity in corrosive applications.

Intergranular Corrosion

The low carbon content in 317L reduces the risk of intergranular corrosion, which can occur when carbon levels are high, especially during welding. This feature is particularly beneficial during welding, as it reduces the susceptibility of the material to sensitization—a process that can lead to corrosion along the grain boundaries.

Conclusion

These properties make 317L an ideal choice for demanding applications in chemical processing, marine environments, and power generation systems. Its ability to maintain structural integrity while resisting corrosion ensures reliable performance in aggressive conditions.

Applications

The Versatility of 317L Stainless Steel in Industrial Applications

317L stainless steel stands out in various industries due to its exceptional properties, particularly its superior corrosion resistance, high strength, and durability. These qualities make it an indispensable material for demanding applications across multiple sectors.

Chemical Processing and Power Generation

In both the chemical processing and power generation industries, 317L stainless steel is highly valued for its resistance to corrosive chemicals and environments. It is used to construct reactors, storage tanks, and piping systems that handle sulfuric acid, phosphoric acid, and chloride-rich environments. Similarly, in flue gas desulfurization (FGD) systems in power plants, 317L’s resilience against acidic and chloride conditions ensures the longevity and efficiency of the equipment.

Food Processing Equipment

The food processing industry benefits greatly from 317L stainless steel’s excellent corrosion resistance and low carbon content. These properties prevent contamination by ensuring the equipment remains free from corrosion, which is crucial for maintaining hygiene. Consequently, 317L is used in food processing machinery, storage tanks, and conveyor systems, where cleanliness is paramount.

Marine Applications

Marine environments are highly corrosive due to the presence of saltwater. 317L stainless steel is ideal for these conditions as it resists pitting and crevice corrosion, which occur when small pits or crevices form and lead to material degradation. This makes 317L a preferred choice for shipbuilding components, offshore oil rigs, and coastal structures, where durability against seawater exposure is essential.

Medical Equipment

In the medical field, the biocompatibility of 317L stainless steel is crucial. It can withstand frequent sterilization and exposure to bodily fluids without degrading, making it safe for use in surgical instruments, implants, and hospital equipment. Its resistance to corrosion ensures that it does not react adversely with human tissues, making it a reliable material for medical applications.

Oil and Gas Industry

The oil and gas industry demands materials that can endure high pressures and temperatures, as well as exposure to corrosive substances. 317L stainless steel is employed in components such as pipelines, valves, and heat exchangers due to its robustness. Its ability to maintain structural integrity under extreme conditions is vital for the safety and efficiency of oil and gas operations.

Pulp and Paper Processing

The pulp and paper industry involves processes that expose materials to harsh chemicals and high temperatures. 317L stainless steel’s resistance to corrosive environments, such as those containing sulfur compounds, makes it ideal for equipment used in pulp digesters, bleaching plants, and recovery boilers. Its durability ensures consistent performance and reduces the need for frequent maintenance and replacements.

Textile Industry

The textile industry often uses dyes and chemicals that can be highly corrosive. For example, acid dyes can cause significant wear on equipment. 317L stainless steel’s excellent resistance to these chemicals makes it suitable for textile processing equipment, including dyeing machines and rollers, ensuring the longevity and reliability of the machinery.

Pharmaceutical Manufacturing

In pharmaceutical manufacturing, maintaining a contamination-free environment is critical. 317L stainless steel’s corrosion resistance and ease of cleaning ensure that reactors, mixing vessels, and storage tanks remain free from contaminants. Its ability to withstand repeated sterilization processes without degrading ensures the purity and safety of pharmaceutical products.

Conclusion

The versatility and superior properties of 317L stainless steel make it an indispensable material across a wide range of industries. Its exceptional corrosion resistance, high strength, and ability to withstand extreme conditions ensure reliable performance and longevity, making it a preferred choice for demanding applications.

Welding Characteristics

Composition and Properties Relevant to Welding

317L stainless steel has low carbon content, which is essential for preventing sensitization during welding. This characteristic helps maintain corrosion resistance at the grain boundaries and reduces the risk of intergranular stress corrosion cracking, making the alloy suitable for welded applications in aggressive environments. The high molybdenum and chromium content further enhances its overall corrosion resistance.

Welding Processes and Techniques

317L can be welded using various welding methods. Common welding techniques include:

  • Shielded Metal Arc Welding (SMAW)
  • Gas Metal Arc Welding (GMAW)
  • Gas Tungsten Arc Welding (GTAW)

These techniques provide flexibility in fabrication and allow for effective joining of components made from 317L stainless steel.

Filler Metals

For optimal welding results, it is recommended to use the following filler metals:

  • AWS E317L/ER317L: A low-carbon filler metal that matches the base material’s composition.
  • Nickel-base filler metals: Ensure sufficient chromium and molybdenum content to maintain corrosion resistance.

Using appropriate filler materials is essential to maintain the integrity and performance of the welded joint.

Post-Weld Treatment

One advantage of welding 317L stainless steel is that it does not require post-weld heat treatment, simplifying the process and minimizing the risk of distortion and other heat-related issues.

Fabrication Considerations

Cold Working

While 317L can harden through cold working, it does not harden through heat treatment, making it suitable for applications that involve cold forming.

Hot Forming

If hot forming is necessary, it is recommended to work within temperatures between 1652°F (900°C) and 2102°F (1150°C). If the final forming temperature is below 1742°F (950°C), a solution anneal at temperatures between 1976°F to 2156°F (1080°C to 1180°C) followed by rapid quenching is advised to restore corrosion resistance and mechanical properties.

Uses in Welded Applications

The excellent welding characteristics of 317L stainless steel make it a favored choice in various industries, including:

  • Chemical and Petrochemical Processing: Its resistance to corrosive environments, particularly those containing sulfurous media and chlorides, makes it highly suitable for constructing reactors, storage tanks, and piping systems.
  • Power Generation: 317L is utilized in flue gas desulfurization systems and condensers in both fossil and nuclear power generation plants, where durability and corrosion resistance are paramount.
  • Food and Beverage Processing: The alloy’s ease of welding and resistance to corrosion render it ideal for food processing equipment, ensuring hygiene and safety in food applications.
  • Pulp and Paper Processing: Its ability to withstand harsh environments makes 317L a reliable option for equipment in the pulp and paper industry, where exposure to corrosive substances is common.

These qualities make 317L stainless steel a top choice for critical applications across various industries.

Heat Resistance

High Temperature Strength

317L stainless steel offers exceptional high-temperature strength, making it ideal for applications involving prolonged exposure to heat. This strength is crucial in situations where materials face extended high temperatures, thanks to its higher creep strength, rupture resistance, and tensile strength at elevated temperatures.

Oxidation Resistance

The alloy resists scaling in typical atmospheric conditions at temperatures up to 1600-1650°F (871-899°C). Its high chromium content forms a protective oxide layer that prevents further oxidation and material degradation.

Thermal Stability

The low carbon content of 317L stainless steel enhances its thermal stability. This is vital for maintaining corrosion resistance, particularly between 800-1500°F (427-816°C). This quality enables it to endure thermal cycling and remain intact in high-temperature conditions.

Physical Properties Relevant to Heat

Density

The density of 317L stainless steel is approximately 0.285 lb/in³ (7.89 g/cm³). This is important for weight-sensitive applications like aerospace and automotive industries.

Thermal Conductivity

Its moderate thermal conductivity ensures efficient heat dissipation, making it ideal for heat exchangers and thermal management systems.

Specific Heat

This measures the heat energy needed to raise the material’s temperature, which is crucial for applications with thermal cycling.

Melting Range

The high melting point keeps the alloy stable and maintains its mechanical properties at high temperatures, with a range between 2540 – 2630°F (1390 – 1440°C).

Uses Related to Heat Resistance

Flue Gas Desulfurization Systems

Fossil fuel power plants use 317L stainless steel in flue gas desulfurization (FGD) systems for its resistance to sulfuric acid and other corrosive substances. These high-temperature systems benefit from the alloy’s heat resistance, ensuring durability and reliability.

Power Generation

In power generation, especially in condensers for fossil and nuclear power stations, 317L stainless steel’s heat resistance and oxidation resistance are crucial.

Chemical and Petrochemical Processing

Equipment that handles hot organic acids, fatty acids, and other chemicals benefits from 317L stainless steel’s heat and corrosion resistance. This suitability extends to reactors, heat exchangers, and storage tanks in the chemical and petrochemical industries.

Food Processing

Food processing equipment must endure acidic and high-temperature conditions. 317L stainless steel’s heat and corrosion resistance ensures machinery stays hygienic and durable, making it ideal for food processing equipment.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What are the key elements in 317L stainless steel?

The key elements in 317L stainless steel are Chromium (18.00 – 20.00%), Nickel (11.00 – 15.00%), and Molybdenum (3.00 – 4.00%). Other important elements include Carbon (0.030% maximum), Manganese (2.00% maximum), Silicon (0.75% maximum), Phosphorus (0.04% maximum), Sulfur (0.030% maximum), and Nitrogen (0.10% maximum). The balance is primarily Iron. These elements collectively contribute to the alloy’s superior corrosion resistance, mechanical strength, and suitability for various industrial applications.

How does 317L stainless steel compare to 316L in terms of corrosion resistance?

317L stainless steel offers superior corrosion resistance compared to 316L, particularly in acidic and chloride-rich environments. The higher molybdenum content in 317L (3-4% compared to 2-3% in 316L) significantly enhances its resistance to pitting and crevice corrosion. This makes 317L more suitable for applications involving strong acids, chlorides, and other corrosive substances, such as chemical processing plants and marine environments. Additionally, 317L maintains its corrosion resistance and strength at elevated temperatures better than 316L, making it ideal for high-temperature applications. Overall, 317L is a preferred choice for environments requiring enhanced corrosion protection.

Can 317L stainless steel be welded easily?

Yes, 317L stainless steel can be welded easily. It is compatible with a wide range of conventional welding processes, including shielded metal arc welding (SMAW), gas metal arc welding (GMAW), and gas tungsten arc welding (GTAW), among others. The low carbon content of 317L prevents intergranular corrosion due to chromium carbide precipitation, allowing it to be used in the as-welded condition without requiring post-weld heat treatment. For optimal welding results, filler metals with a molybdenum content equal to or higher than that of 317L, such as AWS E317L/ER317L, are recommended. Overall, 317L’s combination of properties makes it relatively easy to weld and suitable for various industrial applications.

What are the common applications of 317L stainless steel?

317L stainless steel is commonly used in various applications due to its enhanced corrosion resistance and beneficial properties. It is extensively employed in chemical and petrochemical processing equipment, particularly where resistance to acids like sulfurous, acetic, and citric acids is required. In the power generation industry, it is used in condensers and flue gas desulfurization systems. The food processing industry utilizes 317L for equipment that must withstand hot organic and fatty acids. Additionally, it is used in marine environments, such as offshore platforms and underwater equipment, due to its seawater resistance. Other applications include the paper and pulp industry, textile equipment, oil and gas industry, and high-temperature environments like industrial scrubbing systems.

How resistant is 317L stainless steel to sulfuric acid and chlorides?

317L stainless steel exhibits excellent resistance to sulfuric acid and chlorides due to its high molybdenum content, which enhances its corrosion resistance in these environments. Specifically, it is more resistant to sulfuric acid compared to other austenitic stainless steels like 304 and 316, owing to its composition. Additionally, 317L’s increased molybdenum content provides superior protection against chloride-induced pitting and crevice corrosion, with a Pitting Resistance Equivalent Number (PREN) of 29.7, which is higher than that of 304 and 316 grades. This makes 317L an ideal choice for applications involving these corrosive agents, such as in chemical processing and flue gas desulfurization systems.

How does 317L stainless steel perform at elevated temperatures?

317L stainless steel performs exceptionally well at elevated temperatures due to its unique composition. It offers higher creep, stress-to-rupture, and tensile strength compared to other austenitic stainless steels like 304 and 316. This alloy maintains mechanical integrity and resists sensitization and intergranular corrosion because of its low carbon content, which prevents chromium carbide precipitation. Additionally, its high molybdenum content provides excellent corrosion resistance against sulfuric acid and other aggressive environments. These properties make 317L stainless steel suitable for high-temperature applications such as flue gas desulfurization, chemical processing, and power generation.

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