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439 Stainless Steel (UNS S43035): Composition, Properties, and Uses

In the world of engineering materials, the choice of stainless steel can make or break a project’s success. Among the myriad options, 439 stainless steel emerges as a versatile contender, known for its unique blend of properties that cater to both durability and performance. This ferritic stainless steel, identified by its UNS S43035 designation, is a favorite in industries ranging from automotive to home appliances. Its secret lies in its carefully balanced composition, where elements like chromium and titanium work in harmony to deliver impressive corrosion and heat resistance. But what truly sets 439 stainless steel apart from its peers, such as Types 304 and 409? And how does it find its way into applications as diverse as exhaust systems and architectural designs? Join us as we delve into the fascinating world of 439 stainless steel, uncovering its composition, properties, and myriad uses.

Introduction to 439 Stainless Steel

Composition

The unique properties of 439 Stainless Steel stem from its carefully balanced chemical composition. Here is a breakdown of its key elements:

Element Content Role
Carbon Maximum 0.03% Minimizes carbide precipitation
Manganese Maximum 1.00% Improves hardness and strength
Silicon Maximum 1.00% Enhances oxidation resistance
Phosphorous Maximum 0.040% Affects strength and machinability
Sulfur Maximum 0.030% Improves machinability
Chromium 17% to 19% Prevents rust and enhances corrosion resistance
Nickel Maximum 0.50% Adds toughness and resistance to acids
Titanium Minimum 0.20 + 4x(C+N) to maximum 0.75% Stabilizes against carbide formation
Aluminum Up to 0.15% Improves oxidation resistance

Key Characteristics

Corrosion Resistance

Ever noticed how some materials withstand harsh environments better than others? 439 Stainless Steel offers excellent corrosion resistance, especially in acidic, alkaline, and saline conditions. Its high chromium content forms a stable oxide layer, protecting it from corrosion.

Heat Resistance

Ever wondered why your car’s exhaust system doesn’t rust quickly? It’s because of the heat resistance of 439 Stainless Steel. This alloy performs exceptionally well at high temperatures, making it suitable for automotive exhaust systems and heat exchangers. It withstands thermal cycling without significant degradation.

Mechanical Properties and Formability

439 Stainless Steel boasts a combination of good hardness, strength, and toughness. While it cannot be heat-treated for hardening, it can be work-hardened to increase its tensile strength. Additionally, the material is highly formable, allowing it to be easily shaped through processes such as roll forming and bending. For instance, it can achieve Olsen Cup heights of 0.490 inches and flat bends of 180 degrees with material up to 0.080 inches thick, highlighting its versatility in manufacturing.

Weldability

439 Stainless Steel can be welded using common fusion and resistance techniques, similar to Type 409 stainless steel. This makes it a practical choice for manufacturing processes that require reliable and strong welds.

Applications

Thanks to its robust characteristics, 439 Stainless Steel is employed across various industries, including automotive and home appliances. Its superior properties make it ideal for several key applications:

  • Automotive Exhaust Systems: Perfect for tubular manifolds and other components due to its heat and corrosion resistance.
  • Heat Exchangers: Suitable for thermal transfer applications because of its high thermal conductivity and temperature stability.
  • Home Appliances: Used in the construction of refrigerators, washing machines, and ovens due to its durability and resistance to corrosion.
  • Architectural Decoration: Popular in architectural applications for its aesthetic appeal and corrosion resistance.
  • Food Service Equipment: Commonly used in kitchen appliances and equipment for its resistance to high temperatures and corrosive environments.

439 Stainless Steel stands out as a versatile and reliable material, combining excellent mechanical and chemical properties to meet the demands of various industrial and consumer applications.

Chemical Composition and Elemental Content

Chemical Composition of 439 Stainless Steel

439 stainless steel is a type of stainless steel strengthened with titanium. Its carefully balanced composition enhances both its mechanical properties and resistance to corrosion, making it suitable for various industrial applications.

Major Elements

Iron (Fe):
Iron forms the bulk of 439 stainless steel, accounting for approximately 77.1% to 82.8% of its composition. It serves as the foundational element, providing structure and strength.

Chromium (Cr):
With a content of 17% to 19%, chromium is vital for corrosion resistance. It creates a protective layer that prevents rust, which is essential for maintaining the steel’s durability in corrosive environments.

Titanium (Ti):
Present in amounts ranging from 0.2% to 1.1%, titanium plays a crucial role in preventing the formation of chromium carbides during welding. This is particularly important in harsh environments like marine settings, where maintaining rust resistance is critical.

Minor Elements

Carbon (C):
Kept between 0 to 0.030%, carbon is minimized to reduce carbide formation, which can decrease corrosion resistance.

Manganese (Mn):
Up to 1.0% manganese is included to enhance the hardness and strength of the steel without significantly affecting its ductility.

Silicon (Si):
Silicon, also up to 1.0%, improves oxidation resistance, especially at high temperatures, and contributes to the alloy’s strength.

Nickel (Ni):
Present in small amounts up to 0.5%, nickel adds toughness and improves resistance to certain acids.

Aluminum (Al):
Aluminum content is up to 0.15%. It enhances oxidation resistance and aids in deoxidizing the alloy during production.

Phosphorus (P) and Sulfur (S):
Both phosphorus and sulfur are kept low, with phosphorus at a maximum of 0.040% and sulfur at 0.030%, to avoid brittleness and maintain corrosion resistance.

Nitrogen (N):
Limited to 0.030%, nitrogen helps stabilize the steel’s structure, benefiting its mechanical properties.

Summary

The composition of 439 stainless steel provides high corrosion resistance, excellent mechanical properties, and ensures good formability and weldability. Each element is carefully selected to contribute to the alloy’s overall performance, making it ideal for demanding applications like automotive exhaust systems, heat exchangers, and household appliances.

Properties of 439 Stainless Steel

Corrosion Resistance

439 stainless steel is highly resistant to corrosion, especially in mildly corrosive environments like fresh water and certain acids. This exceptional resistance is attributed to its high chromium content, ranging from 17% to 19%, which forms a stable oxide layer on the surface, protecting the steel from rust and other forms of corrosion. This makes 439 stainless steel ideal for applications where long-term exposure to moisture and various chemicals is expected.

Performance Under Stress and High Temperatures

439 stainless steel demonstrates impressive performance under stress and high temperatures, making it suitable for demanding applications.

Heat Resistance

439 stainless steel maintains stable performance in continuous service environments up to 1700°F (927°C). This ability to withstand high temperatures is crucial for applications such as automotive exhaust systems and heat exchangers, where the material must endure significant thermal cycling without degrading. The inclusion of aluminum and titanium enhances its resistance to oxidation at elevated temperatures.

Mechanical Properties

Key mechanical properties of 439 stainless steel include:

  • Yield Strength: Minimum of 30 KSI (0.2% offset)
  • Tensile Strength: Minimum of 60 KSI
  • Elongation: Minimum of 22% (2-inch gauge length)
  • Density: 0.278 lb./in³ at room temperature
  • Modulus of Elasticity: 29.0 x 10⁶ psi in tension
  • Thermal Conductivity: 168.0 BTU/hr/ft²/ft at 212°F (100°C)
  • Mean Coefficient of Thermal Expansion: 5.6 x 10⁻⁶ per °F between 32°F and 212°F (0°C and 100°C)

These properties ensure that 439 stainless steel can handle mechanical stress and deformation while maintaining its structural integrity.

Formability

439 stainless steel is known for its excellent formability, making it suitable for various manufacturing processes. It can achieve Olsen Cup heights of 0.490 inches, and flat bends of 180 degrees are possible with material up to 0.080 inches thick. The capability to undergo significant deformation without failure makes it an excellent choice for applications requiring intricate shapes and detailed forming.

Weldability

439 stainless steel is easily weldable using standard techniques. The presence of titanium helps stabilize the alloy during welding, preventing issues such as intergranular corrosion and enhancing the overall quality of the welded joints. This makes it a practical choice for applications requiring strong and reliable welds.

Uses and Applications of 439 Stainless Steel

Automotive Industry

439 stainless steel is widely used in the automotive industry, particularly for exhaust system components. Its excellent resistance to corrosion and high temperatures makes it an ideal choice for exhaust manifolds, catalytic converters, and mufflers. The material’s ability to withstand thermal cycling without significant degradation ensures long-lasting performance in demanding automotive environments.

Heat Exchangers

The superior thermal conductivity and heat resistance of 439 stainless steel make it highly suitable for heat exchangers. These properties enable efficient heat transfer while maintaining structural integrity under high-temperature conditions, making 439 stainless steel a preferred material in applications where efficient thermal management is critical.

Home Appliances

439 stainless steel is extensively used in the manufacturing of home appliances. Its corrosion resistance and durability make it an excellent choice for parts exposed to moisture and varying temperatures, such as internal structures and casings of refrigerators, washing machines, and ovens. The material’s aesthetic appeal also adds value to its use in visible parts of household appliances.

Architectural Uses

In architectural applications, 439 stainless steel is valued for both its functional and aesthetic qualities. Its corrosion resistance and durability make it suitable for exterior cladding, roofing, and other decorative elements. The material’s ability to maintain its appearance over time, even in harsh conditions, makes it popular for modern designs.

Food Service Equipment

The food service industry benefits from the use of 439 stainless steel due to its resistance to high temperatures and corrosive environments. It is ideal for kitchen appliances, countertops, and food processing equipment. The material’s ability to maintain hygiene standards and resist corrosion from food acids and cleaning agents is crucial in this sector.

Other Industrial Applications

439 stainless steel finds use in various other industrial applications where corrosion resistance and high-temperature stability are essential. This includes chemical processing equipment, pressure vessels, and piping systems. Its balanced properties make it a versatile material suitable for a wide range of demanding industrial environments.

Comparison with Other Stainless Steel Types

Comparison with Type 304 Stainless Steel

Type 439 and Type 304 stainless steels are both known for their corrosion resistance. However, they are suited for different applications due to their unique properties.

Corrosion Resistance

Type 439 is particularly resistant to stress corrosion cracking, making it ideal for environments with high chloride exposure, such as coastal or industrial settings. This gives it an edge over Type 304 in such challenging conditions.

Thermal Properties

Type 439’s lower thermal expansion and higher thermal conductivity make it more stable at high temperatures, which is beneficial for automotive exhaust systems and heat exchangers. This stability is a significant advantage where dimensional accuracy is crucial.

Mechanical Properties

While Type 439 and Type 304 have similar tensile and yield strengths, Type 439 maintains its mechanical properties at elevated temperatures, making it suitable for high-temperature applications. In contrast, Type 304 may require annealing after welding to prevent intergranular corrosion, which can be an additional step in the manufacturing process.

Comparison with Type 409 Stainless Steel

Type 439 outperforms Type 409 in corrosion and oxidation resistance due to its higher chromium content, which forms a stronger protective oxide layer. This makes Type 439 ideal for more demanding environments, despite its higher cost. The long-term benefits of reduced maintenance and extended service life often justify the investment.

Mechanical Strength

Type 439 also provides higher tensile and yield strengths compared to Type 409, making it a superior choice for applications that demand enhanced mechanical performance. This makes it particularly valuable in automotive components where strength and durability are paramount.

Standards and Specifications

ASTM Standards for 439 Stainless Steel

Overview of ASTM Standards

ASTM standards ensure that 439 stainless steel meets rigorous quality and performance criteria, making it suitable for various demanding applications. Here is a summary of key ASTM standards relevant to 439 stainless steel:

ASTM A240

ASTM A240 specifies the requirements for chromium and chromium-nickel stainless steel, including 439 stainless steel, used in pressure vessels and general applications. This standard ensures the material’s:

  • Material Makeup: Proper chemical composition.
  • Strength and Durability: Adequate mechanical properties.

Compliance with ASTM A240 guarantees that 439 stainless steel can perform reliably in various environments.

ASTM A268

ASTM A268 covers seamless and welded ferritic and martensitic stainless steel tubes, including 439 stainless steel. This specification is crucial for high-temperature and corrosive environments, such as automotive exhaust systems and heat exchangers. Key requirements include:

  • Oxidation and Corrosion Resistance: Ensures durability in harsh conditions.
  • Strength: Suitable for high-temperature applications.

Adherence to ASTM A268 ensures that tubes made from 439 stainless steel are robust and reliable.

ASTM A554

ASTM A554 specifies requirements for welded stainless steel mechanical tubing, including 439 stainless steel. This standard is important for applications where both appearance and mechanical properties are essential, such as in architectural and structural uses. Key aspects include:

  • Surface Finish: Ensures aesthetic quality.
  • Dimensional Accuracy: Meets precise measurement standards.
  • Strength and Durability: Suitable for structural applications.

Compliance with ASTM A554 ensures that the tubing meets the necessary quality for both functional and decorative purposes.

Importance of Standards Compliance

Adhering to these ASTM standards is critical for manufacturers and engineers. It ensures that 439 stainless steel performs reliably in its intended applications by meeting stringent criteria for material makeup, strength, and quality. This adherence provides confidence in the material’s performance and suitability for various industrial and consumer applications.

Certification and Quality Assurance

Manufacturers must provide certification that their products comply with the relevant ASTM standards. This certification is essential for quality assurance and traceability. By adhering to these rigorous standards, manufacturers guarantee that 439 stainless steel will meet the highest expectations for performance, safety, and reliability in critical applications.

Practical Examples

Direct Fired Hot Water Tanks

439 stainless steel is ideal for direct fired hot water tanks due to its exceptional weldability and resistance to stress corrosion cracking. These qualities allow it to withstand constant exposure to water and heat, ensuring a long service life and reliable performance with minimal risk of leaks or failures.

Automotive Exhaust Systems

In automotive exhaust systems, 439 stainless steel excels due to its high resistance to oxidation and corrosion, especially in chloride-containing environments. This makes it suitable for components like tubular manifolds and catalytic converter shells, which endure the high temperatures and harsh conditions of exhaust gases, providing durability and reducing the need for frequent replacements.

Residential Furnace Heat Exchangers

439 stainless steel is a popular choice for residential furnace heat exchangers because of its excellent oxidation and corrosion resistance. These properties ensure that the material maintains structural integrity and performance under high-temperature conditions, promoting efficient heat transfer and long-term reliability. Additionally, its low thermal expansion enhances the safety and efficiency of the furnace system.

Shell and Tube Heat Exchangers

In industrial settings, 439 stainless steel is often used in shell and tube heat exchangers. Its high thermal conductivity and low thermal expansion facilitate efficient heat transfer and eliminate the need for expansion joints. This simplification not only enhances the design but also extends the durability and longevity of the heat exchangers.

Food Service Equipment

In the food service industry, the ease of cleaning 439 stainless steel is a significant advantage, ensuring high hygiene standards. Its resistance to high temperatures and corrosive environments, coupled with its durability, makes it perfect for kitchen appliances and countertops, allowing them to withstand the rigors of daily use without compromising performance or safety.

Power Generation Components

439 stainless steel is employed in power generation for components that require both thermal and corrosion resistance. Its reliability under high temperatures and in corrosive environments makes it suitable for parts such as heat exchangers and piping systems, ensuring the longevity and efficiency of these critical components and contributing to the overall reliability of power generation systems.

Nuclear Applications

In nuclear applications, 439 stainless steel is valued for its low cobalt content, which enhances safety. Its excellent corrosion resistance and mechanical properties ensure reliable performance even in harsh environments. This stability and durability under extreme conditions are crucial for maintaining safety and reliability in the nuclear industry.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the chemical composition of 439 Stainless Steel?

The chemical composition of 439 Stainless Steel (UNS S43035) primarily includes 17.0 to 19.0% Chromium (Cr) and 0.2 to 1.1% Titanium (Ti), with minor elements such as Carbon (C) up to 0.030%, Manganese (Mn) up to 1.00%, Silicon (Si) up to 1.00%, Nickel (Ni) up to 0.50%, Phosphorus (P) up to 0.040%, Sulfur (S) up to 0.030%, and Nitrogen (N) up to 0.030%. The remaining composition is primarily iron, ranging from 77.1 to 82.8%. This composition ensures a fully ferritic structure, enhancing corrosion resistance, weldability, and mechanical properties.

What are the key properties of 439 Stainless Steel?

439 Stainless Steel (UNS S43035) is known for its excellent corrosion resistance, particularly in fresh water, acidic, alkaline, and saline environments. It exhibits good heat resistance, making it suitable for high-temperature applications like automotive exhaust systems and heat exchangers. Mechanically, it has a minimum yield strength of 205 MPa and a tensile strength of 415 MPa, with an elongation of 22%. It also has good formability and is weldable using common techniques. These properties make it versatile for use in automotive, home appliances, and architectural applications, as discussed earlier in the article.

What are the typical applications of 439 Stainless Steel?

439 Stainless Steel, known as UNS S43035, finds typical applications in automotive exhaust systems, residential furnace components, heat exchangers, and nuclear applications. Its excellent corrosion and oxidation resistance, especially in high-temperature environments, make it ideal for exhaust manifolds and furnace heat exchangers. Additionally, its low carbon content and good weldability, without the need for post-weld annealing, enhance its suitability for various industrial uses. The steel’s resistance to chloride stress corrosion cracking also makes it valuable in settings where Type 304 stainless steel might fail.

How does 439 Stainless Steel compare to other stainless steel types like 304 and 409?

Type 439 stainless steel is a titanium-stabilized ferritic alloy offering excellent corrosion resistance, especially against stress corrosion cracking, and good weldability, making it superior to Type 409 in corrosive and high-temperature environments. While Type 304 stainless steel provides higher overall corrosion resistance and mechanical strength due to its higher chromium and nickel content, Type 439 is preferred in applications susceptible to chloride stress corrosion cracking, where Type 304 might be vulnerable. Type 409, on the other hand, is more cost-effective and suitable for applications requiring good oxidation resistance and heat conductivity, such as exhaust systems.

What standards and specifications apply to 439 Stainless Steel?

Standards and specifications applicable to 439 Stainless Steel (UNS S43035) include ASTM A240, which covers chromium and chromium-nickel stainless steel plate, sheet, and strip for pressure vessels and general applications, ASTM A268 for seamless and welded ferritic and martensitic stainless steel tubing for general service, and ASTM A554 for welded stainless steel mechanical tubing. These standards ensure that 439 Stainless Steel meets the required chemical composition, mechanical properties, and fabrication characteristics for its intended uses.

Can 439 Stainless Steel be easily welded and fabricated?

Yes, 439 Stainless Steel can be easily welded and fabricated. It is highly weldable using common fusion and resistance techniques, and maintaining low weld heat input helps avoid brittle weld fractures. The alloy exhibits good formability, allowing for complex forming operations without requiring annealing after welding. Its favorable mechanical properties and resistance to intergranular cracking further enhance its suitability for various fabrication processes, making it a versatile choice for applications like automotive exhaust systems and heat exchangers.

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