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631 Stainless Steel (UNS S17700): Composition, Properties, and Uses

Imagine a material that combines exceptional strength, impressive corrosion resistance, and remarkable versatility, making it indispensable across numerous industries. This is the allure of 631 stainless steel, also known as UNS S17700. As engineering challenges evolve and demands for durable, high-performance materials increase, understanding the intricacies of this specialized alloy becomes crucial. From its unique chemical composition to its robust mechanical properties, this article delves into every facet of 631 stainless steel. Why is it a favorite in aerospace and chemical processing? How do its treatment processes enhance its capabilities? Join us as we uncover the secrets behind this engineering marvel and explore its myriad applications.

Introduction to 631 Stainless Steel

Overview of 631 Stainless Steel

631 Stainless Steel, also known as 17-7PH or UNS S17700, is a versatile alloy prized for its high strength, excellent corrosion resistance, and exceptional formability. This alloy is a popular choice in various industrial applications due to its reliable performance and adaptability.

Chemical Composition

The chemical composition of 631 Stainless Steel is carefully balanced to achieve its remarkable properties. The primary elements include:

  • Nickel: 6.50-7.75%
  • Chromium: 16.00-18.00%
  • Aluminum: 0.75-1.50%
  • Carbon: ≤0.09%
  • Silicon: ≤1.00%
  • Manganese: ≤1.00%
  • Phosphorus: ≤0.040%
  • Sulfur: ≤0.030%
  • Iron: Balance

Key Properties

Mechanical Properties

631 Stainless Steel offers a unique combination of high strength, hardness, and formability, which can be tailored through various heat treatments to enhance its tensile and yield strength. These processes improve its overall durability, making it suitable for demanding applications.

  • Tensile Strength: Ranges from 980 MPa to over 1300 MPa, depending on the temper condition.
  • Yield Strength: Around 725 MPa.
  • Elongation: Approximately 15% in a 50mm gauge length.

Corrosion Resistance

While 631 Stainless Steel is more corrosion-resistant than general hardenable steels like 410 and 420, specific heat treatments can make its resistance comparable to 304 stainless steel. This makes it a reliable choice for environments where corrosion resistance is crucial.

Thermal Properties

  • Melting Point: Between 1405°C and 1440°C.
  • Coefficient of Thermal Expansion: Approximately 15.9 x 10^-6/K at 0-100°C.

Magnetic and Electrical Properties

631 Stainless Steel is non-magnetic in its annealed state but becomes magnetic after heat treatments that transform it into martensite. Its electrical resistivity is around 0.780 μΩ·m at 20°C.

Applications

Due to its robust properties, 631 Stainless Steel is used in:

  • Springs and Spring Components: Utilized for high strength and elasticity.
  • Aerospace Components: Essential for parts requiring durability and fatigue resistance.
  • Medical Equipment: Preferred for surgical instruments due to its biocompatibility and corrosion resistance.
  • Heat Exchangers: Employed for thermal stability and corrosion resistance.
  • Industrial Hardware: Used in washers, clips, blades, and other durable industrial components.

Overall, 631 Stainless Steel’s versatility and performance make it a vital material in demanding applications, ensuring reliability and longevity in challenging environments.

Chemical Composition of 631 Stainless Steel

Chemical Composition and Properties of 631 Stainless Steel

631 stainless steel, commonly known as 17-7 PH, is a precision-engineered alloy known for its exceptional properties. The chemical composition of this alloy is meticulously designed to deliver high strength, excellent corrosion resistance, and good formability.

Major Elements

The alloy primarily consists of the following major elements:

  • Carbon (C): ≤0.09%
  • Manganese (Mn): ≤1.00%
  • Phosphorus (P): ≤0.040%
  • Sulfur (S): ≤0.030%
  • Silicon (Si): ≤1.00%
  • Chromium (Cr): 16.00 – 18.00%
  • Nickel (Ni): 6.50 – 7.75%
  • Aluminum (Al): 0.75 – 1.50%

The remainder of the composition is primarily iron, making up approximately 70.5 to 76.8% by weight. This high iron content provides a robust base structure, contributing to the alloy’s remarkable strength and durability.

Industry Standards

This steel meets several industry standards, including ASTM A693, AMS 5528, ASME SA 693, UNS S17700, EN 1.4568, and SUS 631.

Importance of Each Element

  • Chromium (Cr): Enhances corrosion resistance.
  • Nickel (Ni): Boosts toughness and stability.
  • Aluminum (Al): Essential for precipitation hardening, increasing strength and hardness.
  • Carbon (C): Kept low to reduce carbide precipitation, maintaining ductility.
  • Silicon (Si) and Manganese (Mn): Improve strength and toughness.
  • Phosphorus (P) and Sulfur (S): Controlled to low levels to avoid brittleness and enhance weldability.

Summary

In summary, the balanced chemical composition of 631 stainless steel ensures high strength, excellent corrosion resistance, and good formability, making it suitable for demanding applications. By adhering to strict industry standards, this alloy maintains its performance across various challenging environments.

Mechanical Properties of 631 Stainless Steel

Tensile Strength and Yield Strength

The tensile and yield strengths of 631 Stainless Steel vary significantly based on its heat treatment condition.

Annealed Condition (Condition A)

  • Tensile Strength: > 1035 MPa
  • Yield Strength: > 380 MPa
  • Elongation: > 20%
  • Hardness: < 92 HRB

Heat-Treated Conditions

  • Condition TH 1050:
  • Tensile strength exceeds 1170 MPa, yield strength is over 965 MPa, elongation is more than 6%, and hardness is greater than 38 HRC (or 352 HB).
  • Condition RH 950:
  • Tensile strength exceeds 1280 MPa, yield strength is over 1030 MPa, elongation is more than 6%, and hardness is greater than 41 HRC (or 388 HB).
  • Condition CH 900:
  • Tensile strength exceeds 1655 MPa, yield strength is over 1580 MPa, elongation is more than 1%, and hardness is greater than 46 HRC.

Hardness

The hardness of 631 Stainless Steel varies significantly with heat treatment. In its annealed condition, the hardness is typically less than 92 HRB. However, upon heat treatment, the hardness can increase significantly, reaching up to 46 HRC in Condition CH 900.

Elastic Modulus

The elastic modulus of 631 Stainless Steel is approximately 200 GPa (28 million psi). This high modulus indicates the material’s ability to withstand deformation under stress, contributing to its high strength and rigidity.

Fatigue Strength

The fatigue strength of 631 Stainless Steel ranges from 290 to 560 MPa (42,000 to 81,000 psi). This property is crucial for applications involving cyclic loading, such as in aerospace and mechanical components.

Shear Modulus and Shear Strength

The shear modulus is 76 GPa (11 million psi) and the shear strength ranges from 740 to 940 MPa (110,000 to 140,000 psi).

Poisson’s Ratio

The Poisson’s ratio for 631 Stainless Steel is 0.28. This ratio describes the material’s ability to deform in directions perpendicular to the direction of the applied force, an important factor in understanding the material’s overall deformation characteristics.

Impact of Heat Treatment

Heat treatment is essential for improving the mechanical properties of 631 Stainless Steel. This process transforms its semi-austenitic structure into a martensitic structure, significantly boosting its hardness and strength. Controlled heating and cooling processes not only enhance hardness but also improve wear resistance and durability.

Summary of Mechanical Properties

631 Stainless Steel’s mechanical properties make it a versatile and reliable material for high-strength applications. Its ability to be tailored through heat treatment processes allows it to meet the specific demands of various industries, ensuring high performance and longevity in challenging environments.

Corrosion Resistance and Environmental Factors

General Corrosion Resistance

631 stainless steel, or 17-7 PH, is well-known for its strong corrosion resistance across various environments. The alloy’s composition, which includes chromium, nickel, and aluminum, significantly contributes to its ability to withstand corrosion. Its resistance is comparable to 304 stainless steel and superior to the 400 series, making it suitable for applications requiring moderate corrosion resistance.

Environmental Considerations

In atmospheric environments, 631 stainless steel resists rust and maintains its integrity over time. However, in harsher conditions like saltwater spray or industrial pollutants, it may develop superficial rust, which stabilizes after six months. In environments containing hydrogen sulfide, it can be prone to stress corrosion cracking, underscoring the need to consider specific environmental factors.

Resistance to High Temperatures

631 stainless steel maintains its strength and shape even under high temperatures, making it ideal for high-temperature applications such as aerospace and heat exchangers.

Properties Influencing Corrosion Resistance

The precipitation hardening process enhances the alloy’s mechanical properties without significantly affecting its corrosion resistance. Whether in its annealed austenitic state or heat-treated martensitic state, 631 stainless steel remains durable and resistant to corrosion.

Applications Based on Corrosion Resistance

Thanks to its combination of high strength and corrosion resistance, 631 stainless steel is ideal for aerospace parts like springs and fasteners, chemical processing equipment, oil refining gear, and food processing machinery. Its robustness also makes it suitable for general industrial components.

Conclusion

Overall, the corrosion resistance of 631 stainless steel, combined with its mechanical properties, makes it a versatile and reliable material for a variety of demanding applications. Its performance in different environments ensures its suitability for industries where both mechanical strength and resistance to corrosion are crucial.

Fabrication and Machinability

Machinability

631 stainless steel, also known as 17-7 PH, is particularly machinable in its annealed state. For successful machining, consider the following:

  • Tool Selection, Cutting Speeds, and Feeds, and Coolant Use: Use high-speed steel or carbide tools to handle the material’s hardness and ensure precise cuts. Employ moderate cutting speeds and feeds to avoid excessive tool wear and achieve smooth finishes. Adequate cooling is essential to prevent overheating and maintain tool life, so use water-based coolants or cutting oils.

Weldability

631 stainless steel is known for its good weldability, allowing it to be easily joined using common methods such as TIG (Tungsten Inert Gas) welding for precise control, MIG (Metal Inert Gas) welding for thicker sections, and spot welding for thin sheets. Heat treatments before and after welding help maintain strength and prevent cracking.

Formability

In its annealed state, 631 stainless steel is highly formable and can be shaped into various forms:

  • Sheets and Plates: Easily cut, bent, and formed into complex shapes.
  • Bars and Rods: Can be drawn and formed into round, flat, square, and hexagonal profiles.
  • Tubes and Pipes: Suitable for applications requiring hollow sections with high strength and corrosion resistance.

Heat Treatment

Typical heat treatment processes for 631 stainless steel are:

  • Condition A: Annealed state, providing good formability and machinability.
  • Condition TH 1050: Heating to 1050°F (565°C) for a balance of strength and ductility.
  • Condition RH 950: Heating to 950°F (510°C) for higher strength and hardness.

Cold Working

Cold working deforms the material at room temperature, increasing its strength and hardness. Processes such as cold rolling and drawing are commonly used to enhance these properties.

Fabrication Considerations

When fabricating components from 631 stainless steel, consider the following:

  • Precision and Tolerances: The material’s high strength and hardness can impact machining precision and tolerance control.
  • Surface Finish: Achieving a smooth surface finish may require additional polishing or grinding steps.
  • Dimensional Stability: Post-fabrication heat treatments may be necessary to relieve internal stresses and ensure dimensional stability.

By understanding and applying these principles, engineers and manufacturers can effectively utilize 631 stainless steel in various high-performance applications.

Heat Treatment and Hardening of 631 Stainless Steel

Heat Treatment Processes

Heat treatment is essential for improving 631 stainless steel (17-7 PH), helping to achieve the right balance of strength, hardness, and ductility.

Conditioning (Solution Treatment)

The first step in the heat treatment process is conditioning, where the material is heated to form austenite. This is typically done at a temperature of around 1040°C (1900°F). This step ensures a uniform austenitic structure, crucial for effective hardening.

Cooling

After conditioning, the material is rapidly cooled, usually by quenching. This rapid cooling transforms the austenite into martensite, a highly desirable phase that provides a foundation for further hardening. Quenching is typically done in air or oil, depending on the specific requirements of the application.

Precipitation Hardening

Precipitation hardening is the process where the martensitic structure is aged at specific temperatures to precipitate out strengthening phases. This step significantly enhances the mechanical properties of the steel.

Aging at 565°C (Condition TH 1050)

Aging the material at 565°C (1050°F) balances high strength with good ductility. The typical mechanical properties achieved in this condition include a tensile strength of around 1140 MPa (165,000 psi) and a yield strength of approximately 960 MPa (139,000 psi).

Aging at 510°C (Condition RH 950)

For applications requiring higher strength and hardness, the material is aged at 510°C (950°F). This condition, known as RH 950, results in increased mechanical properties, with tensile strengths exceeding 1280 MPa (185,000 psi) and yield strengths over 1030 MPa (150,000 psi).

Sub-Zero Treatment

Sub-zero treatment, often using liquid nitrogen, can further enhance 631 stainless steel by cooling it below room temperature. This can improve the stability of the martensitic structure and enhance wear resistance.

Cold Working

Cold working is another method to improve the mechanical properties of 631 stainless steel. This process involves deforming the material at room temperature, which increases its strength and hardness. Common cold working techniques include rolling, drawing, and bending.

Key Considerations

  • Temperature Control: Precise temperature control is essential during heat treatment to ensure the desired properties are achieved. Any deviation can lead to poor performance.
  • Time at Temperature: The duration of each heat treatment stage must be carefully controlled. Insufficient time can lead to incomplete transformations, while excessive time can cause grain growth and reduced toughness.
  • Cooling Rate: The cooling rate during quenching must be rapid enough to form martensite but controlled to prevent cracking or distortion.

Conclusion

Heat treatment and hardening processes are crucial for maximizing the performance of 631 stainless steel. By carefully controlling the conditioning, cooling, and aging stages, manufacturers can tailor the material’s properties to meet specific application requirements, ensuring high strength, hardness, and durability.

Uses and Applications of 631 Stainless Steel

Aerospace Industry

In the aerospace industry, 631 stainless steel is prized for its outstanding strength, resistance to corrosion, and ability to withstand fatigue. This alloy is used in critical components such as:

  • Springs and Fasteners: Essential for maintaining structural integrity and performance under high stress and cyclic loading conditions.
  • Aircraft Structural Parts: Utilized in areas requiring high strength and low weight.
  • Engine Components: Suitable for parts exposed to high temperatures and corrosive environments.

Chemical Processing

The chemical processing industry benefits from 631 stainless steel’s robust properties, making it ideal for equipment such as reactors and vessels, which must withstand corrosive chemicals and high temperatures. Additional applications include:

  • Heat Exchangers: Ensures efficient heat transfer while resisting corrosion.
  • Pumps and Valves: Maintains performance and longevity in aggressive environments.

Spring Applications

Due to its strong and durable nature, 631 stainless steel is commonly used to make springs:

  • Spring Wires: Provides high strength and durability for demanding applications.
  • Flat Springs: Offers reliable performance in precision instruments and mechanical devices.
  • Compression and Tension Springs: Suitable for applications requiring high fatigue resistance and elasticity.

Medical Equipment

In the medical field, 631 stainless steel is favored for its biocompatibility, corrosion resistance, and strength. For example, it ensures sharpness and durability in surgical instruments, provides strength and compatibility in orthopedic implants, and maintains precision and hygiene in dental tools.

General Engineering

General engineering applications leverage 631 stainless steel’s versatile properties for various components:

  • Industrial Hardware: Used in washers, clips, and other durable parts.
  • Blades and Cutters: Ensures sharpness and wear resistance in industrial settings.
  • Machinery Components: Offers strength and reliability in high-stress environments.

Automotive Industry

The automotive industry uses 631 stainless steel for parts that require high strength and resistance to harsh conditions:

  • Exhaust Systems: Withstands high temperatures and corrosive gases.
  • Suspension Springs: Provides durability and performance under dynamic loads.
  • Transmission Components: Ensures longevity and reliability in high-stress applications.

Oil and Gas Industry

In the oil and gas sector, 631 stainless steel is employed for its strength and corrosion resistance in challenging environments:

  • Downhole Tools: Maintains performance in high-pressure and high-temperature conditions.
  • Pipeline Components: Resists corrosion and wear in harsh chemical environments.
  • Offshore Platforms: Provides structural integrity and durability in marine settings.

Conclusion

In summary, the unique blend of strength, corrosion resistance, and flexibility makes 631 stainless steel a versatile material, ideal for a wide array of applications across numerous industries.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What are the benefits of using 631 stainless steel?

The benefits of using 631 stainless steel include its high strength and hardness after heat treatment, excellent fatigue properties, good formability, and reliable corrosion resistance. It maintains its properties well at high temperatures and offers high elasticity and magnetic properties post-heat treatment. These attributes make it ideal for aerospace, industrial hardware, medical equipment, and chemical processing applications, where durability, resilience, and minimal distortion are crucial.

Can 631 stainless steel be used in marine environments?

631 stainless steel can be used in marine environments due to its good corrosion resistance, strength, and oxidation resistance. However, special attention must be given to design and maintenance to prevent localized corrosion such as crevice corrosion and stress corrosion cracking. Proper fabrication, regular cleaning, and avoiding contact with materials that could cause galvanic corrosion are essential to ensure its longevity and performance in such environments.

How does the heat treatment process affect the properties of 631 stainless steel?

The heat treatment process significantly impacts the properties of 631 stainless steel (UNS S17700) by enhancing its mechanical characteristics. Solution treatment (annealing) makes the alloy soft and ductile, suitable for complex machining. Subsequent precipitation hardening (aging) dramatically increases the material’s strength and hardness while retaining good corrosion resistance, ductility, and toughness. Specific aging treatments, such as Condition TH 1050 and RH 950, optimize these properties, resulting in yield strengths up to 190,000 psi and tensile strengths up to 200,000 psi, making 631 stainless steel suitable for high-performance applications.

Is 631 stainless steel suitable for welding?

631 stainless steel, also known as 17-7 PH, is suitable for welding using shielded fusion and resistance welding processes, but oxyacetylene welding is not recommended due to potential carbon pickup. When filler metal is needed, using a consumable of similar composition is advisable. Post-weld annealing treatment may be necessary to restore corrosion resistance. Overall, while 631 stainless steel can be welded effectively, careful management of welding conditions and post-weld treatments is essential to maintain its mechanical and corrosion properties.

What are some common industries that use 631 stainless steel?

631 stainless steel, also known as 17-7 PH, is used in various industries due to its high strength, corrosion resistance, and formability. Common industries include aerospace for components like valve parts and springs, chemical and petrochemical for processing equipment, oil and petroleum refining for pipelines, food industry for processing tools, energy and cryogenic applications for heat exchangers, and general metalworking for high-strength parts such as springs and fittings. Its unique properties make it essential in these critical sectors.

How does 631 stainless steel compare to other stainless steels?

631 stainless steel, also known as 17-7 PH, distinguishes itself from other stainless steels with its high strength and excellent fatigue properties due to its precipitation-hardening capability. Compared to AISI 316L, 631 offers significantly higher mechanical strength and hardness but slightly lower corrosion resistance. When compared to other precipitation-hardening steels like 17-4 PH and 15-5 PH, 631 stainless steel provides superior high-temperature properties and strength, attributable to its higher alloy content. These characteristics make 631 stainless steel ideal for applications in aerospace, petrochemical, and other industries requiring robust, durable materials.

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