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Can You Silver Solder Stainless Steel to Mild Steel?

In the world of metalworking, joining dissimilar metals like stainless steel and mild steel can be a daunting challenge, sparking curiosity and innovation. Silver soldering, with its unique ability to create strong, reliable bonds, offers a promising solution. But how exactly can you achieve this alchemical feat? This article dives into the intricacies of silver soldering, exploring the techniques that make it possible to fuse these two metals seamlessly. We’ll guide you through selecting the right materials, from flux to solder, and provide a step-by-step tutorial to ensure a sturdy bond. Are you ready to unlock the secrets of silver soldering and enhance your metalworking skills? Let’s embark on this transformative journey.

Silver Soldering Techniques

Introduction to Silver Soldering

Silver soldering, or brazing, joins metals using a filler metal that melts above 450°C (842°F) but below the base metals’ melting points. This technique is renowned for creating strong, leak-proof joints, ideal for applications in plumbing, electronics, and metalworking.

Key Techniques for Silver Soldering

Surface Preparation

Clean the metal surfaces thoroughly with abrasives like sandpaper or emery cloth, then rinse with a solvent to remove contaminants such as oil, grease, or oxide layers. Proper surface preparation is crucial to ensure a successful silver soldering process.

Choosing the Right Solder and Flux

Selecting the appropriate silver solder and flux is essential for achieving a strong bond. High-silver content solders, typically containing around 56% silver, are recommended for their excellent flow characteristics and strong bonding capabilities. The flux used should be compatible with both the solder and the metals being joined to prevent oxidation during heating and ensure the solder flows into the joint properly.

Heating and Solder Application

Heat the workpieces evenly with a torch (e.g., oxyacetylene or propane) until they reach a dull red color. Do not heat the solder directly; instead, allow the metals to reach the right temperature so the solder can flow into the joint.

Advanced Silver Soldering Techniques

Pre-tinning and Gap Control

Pre-tinning, or applying a thin layer of solder to the metal surfaces before joining, improves solder flow and bond strength. Additionally, maintain a gap of 0.001 to 0.005 inches (0.025 to 0.127 mm) between pieces to allow capillary action to draw the solder into the joint.

Joint Design

Designing the joint properly can significantly affect the strength and durability of the bond. Lap joints are preferred over butt joints as they provide a larger surface area for the solder to bond, leading to improved mechanical strength.

Practical Applications of Silver Soldering

Silver soldering is essential in many industries for its ability to join dissimilar metals and create strong, corrosion-resistant joints. It’s commonly used in automotive and aerospace components, plumbing systems, and electrical connections.

By mastering these techniques, metalworkers can achieve high-quality, reliable joints that stand up to demanding applications.

Compatible Metals

Metals Compatible with Silver Soldering

Silver soldering is a versatile technique used to join various metals, making it essential in both industrial and DIY projects. Below is an overview of metals compatible with silver soldering and their key characteristics.

Stainless Steel and Mild Steel

Stainless steel and mild steel are widely used in construction and manufacturing due to their durability. Silver soldering these metals provides strong, leak-proof joints ideal for a range of applications.

Copper

Copper is prized for its excellent conductivity, making it a top choice for electrical wiring and plumbing pipes. Silver soldering copper ensures the joints are strong and efficient, perfect for keeping your electrical systems running smoothly.

Brass

Brass, an alloy of copper and zinc, is often used in decorative items, musical instruments, and plumbing fixtures. Silver soldering brass can produce aesthetically pleasing and structurally sound joints.

Bronze

Bronze, primarily an alloy of copper and tin, is known for its strength and corrosion resistance. Silver soldering bronze is useful in applications requiring durable joints, such as in marine hardware and sculptures.

Cast Iron

Cast iron, with its high carbon content, is used in heavy-duty applications like engine blocks and machinery. Silver soldering cast iron requires careful surface preparation but can achieve strong bonds suitable for repairs and fabrication.

Galvanized Iron

Galvanized iron is coated with zinc to prevent rust. When silver soldering, it’s important to remove the zinc coating where the joint will be made to ensure a strong connection.

High-Strength Alloys

High-strength alloys such as chrome-moly, carbon-moly, and manganese steel are used in demanding applications like automotive and heavy machinery. Silver soldering these metals produces robust joints capable of withstanding significant stress and wear.

Cast Steel

Cast steel, known for its versatility and strength, is used in various structural and industrial applications. Silver soldering cast steel can create durable joints suitable for heavy-duty use.

Carbon Steel

Carbon steel, with higher carbon content than mild steel, offers increased hardness and strength. Silver soldering carbon steel is effective for creating strong, durable joints in applications requiring enhanced mechanical properties.

Inconel

Inconel, a family of nickel-chromium-based superalloys, is used in high-temperature and corrosive environments. Silver soldering Inconel requires specialized techniques but results in highly resilient joints suitable for extreme conditions.

Spring Steel

Spring steel, known for its elasticity and high yield strength, is used in springs and high-stress components. Silver soldering spring steel can produce flexible yet strong joints that maintain the metal’s desirable properties.

German Steel

German steel, often referring to high-quality stainless or tool steels, is used in precision instruments and high-performance applications. Silver soldering German steel results in strong, reliable joints suitable for demanding uses.

Silicone Bronze

Silicone bronze, an alloy of copper with silicon and other elements, is used for its strength and corrosion resistance. Silver soldering silicone bronze is ideal for creating durable, aesthetically pleasing joints in artistic and structural applications.

Cadmium-Coated Steel

Cadmium-coated steel, used for its corrosion resistance and lubricity, requires careful handling due to cadmium’s toxicity. Silver soldering cadmium-coated steel involves removing the coating in the soldering area to ensure a strong bond.

Cupronickel

Cupronickel, an alloy of copper and nickel, is used in marine environments and coinage due to its corrosion resistance. Silver soldering cupronickel can create resilient joints suitable for harsh environments.

By understanding the compatibility of these metals with silver soldering, metalworkers can achieve strong, reliable joints for a variety of applications.

Tools and Materials

Materials

Silver Solder

Choosing the correct silver solder is essential for a strong bond. SSF-6, a 56% silver alloy, is highly recommended for joining stainless steel to mild steel. This alloy is versatile, offering excellent bonding capabilities with various metals, including copper, brass, and bronze. Its high silver content ensures robust and durable joints.

Flux

Flux is crucial in silver soldering as it removes oxidation from metals, allowing the solder to flow smoothly into the joint. For stainless steel to mild steel applications, a flux-coated silver solder rod like SSF-6 is ideal. This flux coating is potent enough to bond even burnt stainless steel and eliminates the need for pre-cleaning in some cases.

Base Metals

Both stainless steel and mild steel must be clean and free of oxidation before soldering. Using a Dremel tool or wire brush to clean the surfaces ensures optimal bonding. This step is essential for achieving a strong and reliable joint.

Tools

Heating Source

Heating sources like propane, oxyacetylene, MAPP gas, and natural gas torches can be used, depending on the heat control required. The selection depends on the specific application and the level of heat control needed. Each type offers different advantages in terms of heat distribution and control.

Cleaning Tools

Cleaning tools such as a Dremel tool or wire brush are indispensable for preparing the metal surfaces before soldering. These tools effectively remove oxidation and debris, ensuring that the solder bonds well with the metals.

Clamps

Clamping the parts together during the soldering process helps maintain joint integrity. Proper clamping ensures that the pieces stay aligned and that the solder flows evenly into the joint, resulting in a stronger bond.

Techniques

Preparing the Joint

Thoroughly clean the metal surfaces to ensure proper bonding. If the silver solder is not adhering, it may indicate insufficient cleaning or inadequate heating.

Heating the Metals

Heat both sides of the joint evenly until the metal turns a dull red color, signaling readiness for the solder application. Even heating is crucial for the solder to flow properly and create a strong bond.

Applying the Solder

Melt a small amount of flux onto the joint, then use the torch to spread it evenly. Add the silver solder rod, moving the torch continuously to avoid overheating the metals. This technique ensures a uniform and strong joint.

Post-Soldering Cleanup

After soldering, clean any excess flux with water and a wire brush. Thorough cleaning prevents residue from compromising the joint’s strength and appearance.

Considerations

Corrosion Resistance

Silver soldering stainless steel can affect its corrosion resistance. Using a cadmium-free silver solder like SSF-6 mitigates this risk, making it suitable for applications where corrosion resistance is crucial.

Strength of the Bond

The bond created by SSF-6 silver solder is exceptionally strong, with a tensile strength of up to 70,000 psi, surpassing many MIG welding wires. This strength ensures the joint can withstand significant stress and wear.

By selecting the appropriate materials and tools, and employing proper techniques, you can achieve a strong and reliable bond when silver soldering stainless steel to mild steel.

Choosing the Right Solder and Flux for Silver Soldering

Importance of Choosing the Right Solder

Choosing the right solder is essential for creating a strong, lasting bond in silver soldering. The solder must have a high silver content to ensure excellent flow characteristics and robust bonding capabilities.

SSF-6 Silver Solder

  • Composition: SSF-6, with its 56% silver content, offers superior bond strength.
  • Versatility: This solder can join metals like stainless steel, mild steel, copper, brass, and bronze.
  • Strength: It provides a bond strength of over 70,000 PSI, making it suitable for high-stress applications.
  • Application: SSF-6 can be applied using various heat sources such as a propane torch, oxyacetylene, MAPP gas, or a natural gas torch.

Selecting the Appropriate Flux

Flux plays a crucial role in silver soldering by removing oxides, promoting wetting, and ensuring smooth solder flow into the joint.

Types of Flux

  • General-Purpose Flux: Suitable for most silver soldering applications, general-purpose fluxes like Lucas-Milhaupt’s Handy Flux® are effective. These fluxes typically contain potassium salts, fluorides, and borates.
  • Proprietary Flux Coating: The SSF-6 silver solder comes with a proprietary flux coating that simplifies the soldering process. This flux is strong enough to wet burnt stainless steel and does not require pre-cleaning.

Application Considerations

  • Compatibility: To work effectively, the flux must be compatible with both the base metals and the filler metal, ensuring it removes oxides and promotes proper solder flow.
  • Heat Control: The flux should accommodate the specific conditions of the brazing process. For example, in fast-heat processes or when brazing small parts, use fluxes that minimize boiling off.
  • Automation: In manufacturing settings, the flux should be capable of being sprayed or deposited without separation to facilitate automation.

Steps for Using Solder and Flux

  1. Pre-Cleaning: Ensure the surfaces of both metals are clean to prevent contaminants from interfering with the bond.
  2. Flux Application: Apply the flux according to the type being used. For SSF-6, the proprietary flux coating simplifies the process.
  3. Heat Control: Carefully monitor the heat to avoid damaging the metal or flux, and use the right torch tip for precise application.

By carefully selecting the right solder and flux and following proper application techniques, you can achieve strong and reliable bonds in your silver soldering projects.

Step-by-Step Guide to Silver Soldering Stainless Steel to Mild Steel

Preparation

Cleaning the Surfaces

Start by cleaning the stainless steel and mild steel surfaces thoroughly. Use a wire brush, abrasive pad, or degreaser to remove any dirt, rust, or oil. This step is crucial to ensure that the flux and solder adhere properly, creating a strong bond.

Pre-Heating the Metals

Use an appropriate torch, like oxyacetylene, propane, or MAPP gas, to heat the metals. Watch for the metal to turn a dull red, which signals it’s ready for soldering. Be careful not to overheat, as this can cause oxidation and prevent the solder from flowing properly.

Applying the Silver Solder

Flux and Solder Application

Choose a high-silver-content solder, such as SSF-6, which comes with a special flux coating. When the metals are hot enough, apply the solder. The flux will melt and spread over the joint, preventing oxidation and helping the solder bond. Make sure the solder flows evenly to create a strong, durable joint.

Finalizing the Joint

Cooling Process

Let the joint cool down naturally. Do not use rapid cooling methods like quenching, as these can stress the metal and cause cracks or brittleness. Gradual cooling preserves the bond’s strength.

Cleaning the Joint

After the joint has cooled, clean off any excess flux residue using water and a wire brush. This step not only improves the appearance but also ensures the longevity of the joint by removing potentially corrosive residues.

Tips for Success

  • Proper Heat Control: Select the right torch tip and carefully monitor the heat to avoid overheating.
  • Appropriate Flux: Use a high-temperature flux, especially for stainless steel, to ensure a strong bond.
  • Joint Design: Opt for lap joints instead of butt joints for a larger bonding area and stronger joint.

By following these steps, you can achieve a strong, reliable, and aesthetically pleasing silver soldered joint between stainless steel and mild steel.

Common Challenges and Troubleshooting Tips

Cleaning and Preparation

For successful silver soldering, it’s crucial to ensure both stainless steel and mild steel surfaces are impeccably clean. Avoid methanol or alcohol; instead, use acetone, brake cleaner, or a mix of emery paper and warm soapy water with a stiff brush to remove grease, oil, and oxidation, ensuring proper solder adhesion. Wire brushing the surfaces before applying flux can further help in removing any remaining contaminants and oxidation layers, improving the bonding surface.

Heat and Flux

Stainless steel and mild steel are poor conductors of heat compared to metals like copper or brass. This can cause the contact point to cool quickly, preventing the solder from melting and flowing properly. To address this, apply heat quickly and evenly across the joint.

Using a high-temperature flux is essential. Standard fluxes are often insufficient for steel; instead, use products like HT5 or Harris Stay Clean. These fluxes are designed to handle the higher temperatures required for steel, ensuring the solder flows smoothly and bonds effectively.

When applying the solder, place it close to the joint and heat the area gently. This technique allows the solder to melt and flow into the joint, creating a strong bond.

Temperature Control

Silver solder melts at temperatures close to where stainless steel can oxidize (blueing). Carefully control the heat to avoid overheating and ensure the solder adheres properly. If blueing occurs, clean the area thoroughly before attempting to solder again.

Using an oxygen-fueled torch, such as oxy/acetylene, oxy/propane, or oxy/MAPP, can help achieve the necessary temperature quickly and minimize the risk of oxide formation. These torches provide precise heat control, essential for maintaining the integrity of the joint.

Material Compatibility

Stainless and mild steel have different thermal properties. Handle stainless steel carefully to avoid oxidation and blueing. Identifying the specific type of steel you are working with is crucial, as some leaded free-cutting steels can be problematic for silver soldering.

Ensure you select compatible materials and adjust your technique accordingly to accommodate these differences.

Technique and Patience

Patience is crucial. Heat the parts gradually, especially larger ones, and use the solder to check if the metal is hot enough, rather than directly applying the flame. Flattening the solder with a hammer before application can reduce the amount of heat needed and the risk of overheating the joint. This technique allows for more controlled heating and a better bond.

Common Issues

  • Solder Forms Balls: If the solder forms balls and does not adhere, the surfaces may not be clean enough, or the flux may have been destroyed by excessive heat. Ensure proper cleaning and use high-quality flux.
  • Solder Rolls Off: This issue indicates the metal is not hot enough or there is oxidation on the surface. Check for blueing on stainless steel and clean it off before proceeding.
  • Inconsistent Bonding: Uneven heating or insufficient flux can result in inconsistent bonding. Ensure you apply heat evenly and use adequate flux to promote smooth solder flow.

By addressing these challenges with the right cleaning methods, flux, temperature control, and technique, you can successfully silver solder stainless steel to mild steel.

Safety Precautions and Best Practices

Personal Protective Equipment (PPE)

When silver soldering, it is essential to wear appropriate personal protective equipment to safeguard against potential hazards.

  • Protective Clothing and Gloves: Wear long sleeve shirts, pants made of natural fibers, closed-toe shoes, and heat-resistant gloves to protect against burns and hot surfaces.
  • Eye Protection: Safety glasses, goggles, or a face shield should be worn to guard against hot solder and flux fumes.

Ventilation and Fume Control

Proper ventilation is crucial to minimize exposure to hazardous fumes generated during the soldering process.

  • Work Area Ventilation: Conduct soldering in a well-ventilated area. Use fans or fume extractors to blow fumes away from the breathing zone.
  • Toxic Fumes Awareness: Heating stainless steel can produce toxic fumes, like hexavalent chromium. Ensure good ventilation to avoid inhaling these fumes.

Electrical Safety

Soldering involves the use of electrical equipment, requiring adherence to specific safety protocols.

  • Grounding and GFCI Protection: Use a soldering iron with a grounding prong and ensure your work area has a ground fault circuit interrupter (GFCI) to reduce the risk of electrical shocks.

Fire Prevention

Preventing fires is a critical aspect of maintaining a safe soldering environment.

  • Nonflammable Surface and Safe Handling: Work on a nonflammable surface and keep flammable items away. Always place the hot soldering iron in its stand when not in use.

Cleaning and Preparation

Proper preparation of metal surfaces is vital for achieving a successful solder joint.

  • Surface Cleaning: Ensure all metal surfaces are thoroughly cleaned. Use sandpaper or a file to remove any oil, rust, or contaminants before applying flux and solder.
  • Joint Fit: Ensure the joint faces fit tightly. Proper fit is crucial for the capillary action that allows the silver solder to flow into the joint.

Flux Application

Applying flux correctly is essential to prevent oxidation and ensure the solder flows properly.

  • Flux Coating: Apply soldering flux to each metal surface at the joint. This helps in preventing oxidation during the heating process.

Heating and Temperature Control

Controlling heat is crucial to avoid damaging the metals and ensuring a strong bond.

  • Heat Source: Use an Oxygen + Fuel Torch to heat the joint area quickly. This minimizes the risk of oxides forming and avoids burning the chrome in stainless steel, which can prevent bonding.
  • Temperature Monitoring: Be cautious of the high temperatures required for silver soldering, especially with stainless steel. Ensure the temperature is high enough to melt the solder but not so high as to burn the chrome.

Solder Selection

Choosing the right solder is key to forming a strong and durable joint.

  • High-Silver Content: Select a silver solder with a high silver content (at least 40%, ideally 55%) for stainless steel to ensure a strong bond without overheating the metal.

By adhering to these safety precautions and best practices, you can effectively silver solder stainless steel to mild steel while minimizing risks and ensuring strong, durable joints.

Comparison of Different Silver Soldering Products

Silver Solder Alloys

SSF-6 Silver Solder

SSF-6 is a 56% silver alloy known for its versatility and strong bonding capabilities. It is ideal for soldering a wide range of metals, including stainless steel, mild steel, copper, brass, and bronze. The flux-coated brazing rod form of SSF-6 simplifies the soldering process by eliminating the need for a separate flux application. This product is particularly noted for its high flow and strong bond strength, reaching up to 70,000 psi, making it suitable for high-stress applications.

General Silver Solder Types

Silver solders are available in various compositions, affecting their melting and flow characteristics:

  • Easy Solder (56% Silver): Melts and flows at lower temperatures, making it suitable for fine work and delicate components.
  • Soft Solder (65% Silver): Provides a good mix of low melting point and strong bond.
  • Medium Solder (70% Silver): Offers a stronger bond but requires higher temperatures.
  • Hard Solder (75% Silver): Provides the highest bond strength but needs precise heat control due to its high melting point.

Fluxes

White Flux

White flux is commonly used for brazing metals like copper, brass, steel, and stainless steel. It operates within an active temperature range of 1050° – 1600°F (565° – 870°C) and conforms to AWS A5.31 class FB3-A standards. While effective for general purposes, it may not be as efficient for metals that form difficult oxides, such as stainless steel.

Black Flux

Black flux is designed for soldering metals that form challenging oxides, such as stainless steel, nickel alloys, and tungsten carbide. It includes powdered boron, which helps absorb oxides and ensures effective wetting of the filler metal. Black flux is particularly useful for achieving strong bonds in applications involving stainless steel.

Application Techniques

Silver soldering offers practical benefits for both everyday repairs and industrial settings, providing strong and durable joints across various metals. Here’s how to apply silver solder effectively:

  1. Clean the Surfaces: Clean both stainless steel and mild steel surfaces thoroughly. Use a wire brush or abrasive pad to remove any dirt, rust, or grease, followed by a solvent rinse to eliminate any residual contaminants.
  2. Heat the Metal: Apply broad heating to the metal rather than direct heating. This method helps to gradually bring the steel to the appropriate working temperature, promoting a uniform bond and preventing localized overheating.
  3. Use Flux-Coated Rods or Paste: Products like SSF-6 flux-coated rods or SSQ-6 silver solder paste simplify the soldering process. These products combine the flux and solder, ensuring effective wetting of the metal surfaces, even on burnt or oxidized stainless steel.

Specific Products for Stainless Steel to Mild Steel

SSF-6 Silver Solder

SSF-6 is highly recommended for soldering stainless steel to various metals, including mild steel. It is cadmium-free, making it safe for use in food and restaurant industries. Its flux coating is effective on burnt stainless steel, eliminating the need for pre-cleaning and ensuring a strong bond.

SSQ-6 Silver Solder Paste

SSQ-6 is a paste version of SSF-6, designed for easy application on cold metals. It is particularly useful for joining mild steel to copper or other metals and extends its versatility to stainless steel. The paste form allows for precise application, especially in tight or intricate joints, ensuring a strong and durable bond.

Conclusion

When silver soldering stainless steel to mild steel, choosing the right products is essential for achieving strong, reliable joints. SSF-6 and SSQ-6 silver solder products, combined with appropriate fluxes, offer high bond strength, ease of use, and compatibility with a wide range of metals. By following proper cleaning and heating techniques and using flux-coated rods or paste, you can ensure successful and durable bonds in various applications.

Frequently Asked Questions

Below are answers to some frequently asked questions:

How do you silver solder stainless steel to mild steel?

To silver solder stainless steel to mild steel, first clean both metal surfaces thoroughly to remove contaminants. Use a suitable heat source like an oxyacetylene torch to heat the metals evenly until they reach a dull red color. Apply a high-strength silver solder, such as SSF-6, which comes with a flux coating that helps the solder flow smoothly and bond effectively. The flux coating will melt as you heat the metal, allowing the solder to flow across the joint. Monitor the heat carefully to avoid overheating and ensure a strong, durable bond by following these steps and using the right materials.

What tools and materials are needed for silver soldering stainless steel and mild steel?

To silver solder stainless steel to mild steel, you need an oxyacetylene or propane torch with the correct tip, cleaning tools like a wire brush or abrasive pad, high-quality silver solder (e.g., 56% silver content), high-temperature flux (such as black flux rated around 1000°C), and soldering accessories like tweezers and a soldering block. Proper heat control and thorough cleaning of the metal surfaces are crucial for a strong bond. Ensure the stainless steel can withstand brazing temperatures without losing corrosion resistance, and always follow safety guidelines during the process.

What are the key factors for successful silver soldering of stainless steel?

To successfully silver solder stainless steel, key factors include selecting the right flux and solder, ensuring proper heat application, and thorough surface preparation. Use a strong flux specifically for stainless steel and a high silver content solder like SSF-6. Apply heat broadly with a torch, preheat parts to remove oils, and clean surfaces to a shiny finish for optimal adhesion. Proper technique, such as heating from beneath, enhances bonding. Additionally, ensure compatibility when joining dissimilar metals like mild steel, and prioritize safety by using cadmium-free solders for food-related applications.

What are the common challenges faced during silver soldering, and how can they be resolved?

Common challenges faced during silver soldering stainless steel to mild steel include ensuring clean surfaces, maintaining the correct gap for solder flow, preventing flux evaporation, and controlling heat application. To resolve these, thoroughly clean the surfaces, create a gap of about 0.05mm – 0.1mm, apply flux properly, and heat the metals evenly and slowly. Additionally, using high-quality silver solder and the right flux, ensuring material compatibility, and proper solder placement are crucial. Post-soldering cleaning is also essential for removing flux residue and achieving a professional finish. These steps help ensure strong and reliable joints.

How do you choose the right solder and flux for silver soldering?

To choose the right solder and flux for silver soldering stainless steel to mild steel, consider the base metals’ oxide formation, requiring aggressive fluxes like No. 71 Stainless Steel Soldering Flux for stainless steel. Select a silver-containing solder, such as SSF-6, for strong bonding. Ensure the flux can handle high temperatures and is suitable for your brazing method. Proper surface preparation, including cleaning and pre-heating, is essential for effective solder flow. These considerations will help achieve a reliable joint by managing oxide removal and enhancing solder adhesion between the metals.

What safety precautions should be taken when silver soldering stainless steel to mild steel?

When silver soldering stainless steel to mild steel, ensure safety by wearing protective gear like safety glasses, gloves, and a face mask, and maintain good ventilation to avoid inhaling fumes. Use an appropriate flux to remove chrome oxide and prevent overheating to avoid damaging the metals. Monitor temperature closely to prevent oxidation and ensure a clean bond. Always follow AWS Safety & Health Guidelines and thoroughly clean the joint post-soldering to remove any flux residues. These precautions will help achieve a safe and effective soldering process.

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