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CN7M vs. Alloy 20 Stainless Steels: Differences Explained

When it comes to selecting the right stainless steel for industrial applications, the choice between CN7M and Alloy 20 can be pivotal. Both of these high-performance materials are renowned for their exceptional resistance to corrosion and their robust mechanical properties, yet they cater to different needs and environments. Understanding the nuances between CN7M, a cast austenitic alloy, and Alloy 20, a nickel-iron-chromium alloy with added copper and molybdenum, is crucial for engineers, maintenance technicians, and researchers alike.

In this comprehensive comparison, we will delve into the specific properties that set these two alloys apart. From their chemical composition and corrosion resistance to their performance in high-temperature settings and susceptibility to stress-corrosion cracking, every aspect will be meticulously analyzed. Additionally, we will explore their typical industrial applications, providing insights into why one might be favored over the other in certain scenarios. Whether you’re involved in chemical processing, industrial valve manufacturing, or equipment maintenance, this article aims to equip you with the knowledge needed to make an informed decision. So, let’s embark on this detailed exploration of CN7M and Alloy 20 stainless steels and uncover which one stands out for your specific requirements.

Introduction

Overview of CN7M and Alloy 20 Stainless Steels

CN7M and Alloy 20 are high-performance stainless steel alloys widely used in industrial applications for their excellent corrosion resistance and durability. These alloys are essential in environments with aggressive chemicals, high temperatures, and mechanical stress. Understanding the unique properties and differences between CN7M and Alloy 20 helps in selecting the right material for specific industrial needs.

Importance of Understanding the Differences

Choosing the appropriate stainless steel alloy involves considering factors like chemical composition, corrosion resistance, heat tolerance, and resistance to stress-corrosion cracking. While CN7M and Alloy 20 share some similarities, their distinct properties make them suitable for different environments and applications.

Key factors include:

  • Chemical Composition: Elements like nickel, chromium, molybdenum, and copper determine the alloys’ strengths and weaknesses.
  • Corrosion Resistance: Ability to withstand acidic, alkaline, and chloride environments.
  • Heat Resistance: Tolerance to high temperatures and thermal stress.
  • Stress-Corrosion Cracking Resistance: Susceptibility to cracking under stress in corrosive environments.

Understanding these differences ensures the selected alloy will perform optimally, enhancing safety, efficiency, and longevity of industrial equipment.

Properties of CN7M and Alloy 20

Chemical Composition and Properties of CN7M and Alloy 20

Understanding the chemical composition of CN7M and Alloy 20 is essential to grasp their specific properties and suitability for various applications. Both alloys are nickel-chromium-molybdenum stainless steels, with slight variations due to their different forms—cast for CN7M and wrought for Alloy 20.

Nickel Content

Nickel is a significant component in both CN7M and Alloy 20, contributing to their excellent corrosion resistance and mechanical properties. The nickel content in CN7M ranges from 32.5% to 35%, while in Alloy 20, it ranges from 32% to 38%.

Chromium Content

Chromium provides corrosion resistance by forming a protective oxide layer on the surface of the metal. Both CN7M and Alloy 20 contain 19% to 21% chromium.

Molybdenum Content

Molybdenum improves resistance to pitting and crevice corrosion, especially in chloride environments. Both alloys contain 2% to 3% molybdenum, which is crucial for performance in aggressive chemical settings.

Copper Content

Copper enhances resistance to sulfuric acid and other reducing environments. CN7M and Alloy 20 have 3% to 4% copper, making them ideal for applications involving sulfuric acid.

Corrosion Resistance

CN7M and Alloy 20 are renowned for their superior corrosion resistance, making them ideal for use in harsh environments.

Acidic Environments

Both alloys exhibit excellent resistance to sulfuric acid due to their high copper content and also perform well in other acidic environments like phosphoric and nitric acids, making them suitable for chemical processing industries.

Alkaline Environments

These alloys maintain their integrity in alkaline environments, ensuring long-lasting performance and reducing the need for frequent maintenance.

Chloride Environments

CN7M and Alloy 20 resist pitting and chloride ion corrosion, making them suitable for marine and coastal applications. They perform better than 304 stainless steel and are comparable to 316L stainless steel in these environments.

Heat Resistance

The temperature tolerance and heat treatment requirements of CN7M and Alloy 20 are critical for their performance in high-temperature applications.

Temperature Tolerance

Both alloys have a melting point range of 2525°F to 2630°F, making them suitable for high-temperature environments. Their thermal stability ensures they maintain mechanical properties and corrosion resistance even at elevated temperatures.

Heat Treatment

Heat treatment, specifically solution annealing, is necessary to restore the optimal properties of these alloys after exposure to high temperatures. This process involves heating the material to a specific temperature and cooling it rapidly to prevent sensitization and maintain corrosion resistance.

Stress-Corrosion Cracking Resistance

Stress-corrosion cracking (SCC) is a critical factor in selecting materials for corrosive environments. Both CN7M and Alloy 20 show excellent resistance to SCC, particularly in chloride environments.

Comparison of CN7M and Alloy 20

While both alloys resist SCC well, Alloy 20’s wrought form may perform slightly better in specific scenarios due to its manufacturing process. However, CN7M, being the cast version, offers similar benefits and is chosen based on application requirements.

Industrial Applications

Use in Chemical Processing

CN7M and Alloy 20 are popular in chemical processing due to their excellent resistance to corrosive environments. These alloys are particularly effective in processes involving sulfuric acid, phosphoric acid, and other aggressive chemicals.

Specific Examples and Case Studies

Heat Exchanger Parts: CN7M is used in heat exchangers where both high temperature and corrosive conditions are present. Its resistance to sulfuric acid and chloride environments makes it ideal for these applications.

Pump Components: CN7M’s excellent resistance to corrosion and mechanical wear makes it suitable for pump components in chemical plants, ensuring long-term reliability.

Valve Components: In chemical processing, valves need to withstand harsh conditions. CN7M ensures valves maintain their integrity and functionality due to its robustness and corrosion resistance.

Storage Tanks and Process Vessels: Alloy 20 is often used for storage tanks and process vessels in chemical plants, particularly where sulfuric acid is involved. Its superior resistance to pitting and stress-corrosion cracking extends the lifespan of these components.

Pickling Racks: Alloy 20 is ideal for pickling racks in the steel industry, where materials are treated with acid solutions. Its resistance to acid attack ensures durability and low maintenance.

Flue-Gas Scrubbers: Alloy 20 is used in flue-gas desulfurization units to remove sulfur dioxide from exhaust gases. Its resistance to sulfuric acid makes it perfect for these applications.

Use in Industrial Valves and Pumps

The reliability and performance of industrial valves and pumps are crucial in maintaining operational efficiency and safety in various industries. CN7M and Alloy 20 are favored materials for these components due to their exceptional properties.

Advantages of Each Alloy in These Applications

CN7M:

  • Durability: CN7M’s high nickel and chromium content provide excellent resistance to corrosion and mechanical stress, making it suitable for valve and pump components in aggressive environments.
  • Versatility: CN7M performs well in both acidic and chloride environments, making it a versatile material for various industrial applications, including chemical processing and water treatment.

Alloy 20:

  • Corrosion Resistance: Alloy 20 offers superior resistance to pitting, crevice corrosion, and stress-corrosion cracking, making it highly reliable for valve and pump applications in harsh environments.
  • Ease of Fabrication: The wrought nature of Alloy 20 allows for easier fabrication and welding, ensuring high-quality construction of valves and pumps. Its stability during welding maintains its corrosion-resistant properties.

Broader Industrial Applications

Beyond chemical processing and valve/pump manufacturing, CN7M and Alloy 20 are used in a variety of other industrial applications due to their robust properties.

Heat Exchanger Rolls: CN7M is used in heat exchanger rolls where thermal and chemical stability are required, ensuring long-lasting performance.

Centrifuge Parts: In the pharmaceutical and chemical industries, centrifuge parts made of CN7M can withstand corrosive substances and high rotational speeds without compromising integrity.

Food and Beverage Equipment: Alloy 20’s resistance to organic and inorganic acids makes it suitable for food processing equipment, ensuring hygiene and longevity.

Waste Treatment Facilities: Alloy 20’s ability to resist various chemical attacks makes it ideal for components in waste treatment plants, where exposure to corrosive substances is common.

By leveraging the unique properties of CN7M and Alloy 20, industries can enhance the performance, reliability, and lifespan of their equipment, leading to improved operational efficiency and reduced maintenance costs.

Comparison of CN7M and Alloy 20

Chemical Composition and Performance

The chemical composition of CN7M and Alloy 20 is crucial for their performance and suitability in various applications.

Nickel Content

Both CN7M and Alloy 20 contain significant amounts of nickel. CN7M typically has 27.5-30.5% nickel, while Alloy 20 has slightly more, at 32.5-35%. Nickel enhances corrosion resistance, especially in reducing environments, and contributes to the overall stability of the alloys.

Chromium Content

Chromium, which provides excellent resistance to oxidation and corrosion, is present in CN7M at 19-22% and in Alloy 20 at 19-21%. The similar chromium content in both alloys helps form a protective oxide layer, ensuring durability in harsh environments.

Molybdenum Content

Molybdenum, essential for resistance to pitting and crevice corrosion, is found in both CN7M and Alloy 20 at 2-3%. This is crucial for their performance in aggressive chemical settings.

Copper Content

Both CN7M and Alloy 20 have 3-4% copper, enhancing their resistance to sulfuric acid and other reducing environments. This similarity ensures both alloys perform well in sulfuric acid applications.

Corrosion Resistance

Both CN7M and Alloy 20 are known for their excellent corrosion resistance, but there are some distinctions.

Acidic Environments

CN7M is robust against a wide range of acids, including sulfuric, phosphoric, and nitric acids, while Alloy 20 excels particularly in sulfuric acid environments. This makes Alloy 20 a preferred choice for applications involving high concentrations of sulfuric acid.

Alkaline Environments

Both alloys perform well in alkaline environments, maintaining structural integrity and minimizing maintenance needs. Their similar composition ensures they resist corrosive attacks in such settings.

Chloride Environments

CN7M and Alloy 20 both resist pitting and crevice corrosion in chloride environments, but Alloy 20’s higher nickel content may offer slightly better performance. This makes Alloy 20 suitable for more demanding applications in chloride-rich environments.

Heat Resistance

Heat resistance is another critical factor where CN7M and Alloy 20 exhibit differences.

Temperature Tolerance

CN7M can withstand temperatures up to 1100°F (593°C) without significant degradation, making it more heat-resistant than Alloy 20, which is better for moderate temperatures. This makes CN7M suitable for applications requiring long-term exposure to high temperatures.

Heat Treatment

Both alloys require solution annealing after high-temperature exposure to restore their optimal properties. This heat treatment process ensures that the alloys maintain their corrosion resistance and mechanical strength.

Stress-Corrosion Cracking Resistance

Stress-corrosion cracking (SCC) is a significant concern in many industrial applications.

Alloy 20’s higher copper content gives it superior resistance to SCC, making it ideal for high-stress applications. CN7M also offers good SCC resistance but may not perform as well under extreme conditions. However, it remains a reliable option for many applications requiring robust resistance to stress and corrosion.

Industrial Applications

The distinct properties of CN7M and Alloy 20 make them suitable for various industrial applications.

Chemical Processing

Both alloys are used in chemical processing industries due to their resistance to aggressive chemicals. CN7M is often used for heat exchanger parts, pump components, and flanges, while Alloy 20 is preferred for storage tanks and process vessels, especially in sulfuric acid environments.

Industrial Valves and Pumps

In manufacturing valves and pumps, CN7M’s heat tolerance and corrosion resistance make it ideal for harsh conditions, while Alloy 20’s superior SCC resistance and ease of fabrication suit high-stress applications.

Decision-Making Criteria

Choose CN7M for high-temperature applications and Alloy 20 for superior sulfuric acid resistance and better SCC resistance. Both alloys offer excellent general corrosion resistance, with specific conditions favoring one over the other. By considering these factors, industries can select the most appropriate alloy to ensure optimal performance, longevity, and cost-efficiency in their applications.

Maintenance and Treatment

Heat Treatment Requirements

CN7M Heat Treatment

  • Solution Annealing: Heat the alloy to 1800°F to 2000°F.
  • Rapid Cooling: Follow with rapid cooling to dissolve precipitates and prevent sensitization.

Alloy 20 Heat Treatment

  • Solution Annealing: Heat the alloy to 1750°F to 1850°F.
  • Rapid Cooling: Ensure rapid cooling to maintain corrosion resistance and prevent stress-corrosion cracking.

Maintenance Tips and Common Issues

Regular Inspections

  • Periodically check CN7M and Alloy 20 components for signs of corrosion, pitting, or cracks.
  • Look for surface discoloration that may indicate underlying problems.

Cleaning

  • Regularly clean surfaces to remove corrosive residues.
  • Use non-abrasive cleaners to protect the oxide layer.

Temperature Monitoring

  • Ensure components are not exposed to temperatures beyond their tolerance.
  • Continuous monitoring helps prevent sensitization and maintain mechanical properties.

Surface Protection

  • Protect surfaces from scratches or mechanical damage during handling and installation.

Stress-Corrosion Cracking Prevention

  • Inspect Alloy 20 components for signs of stress-corrosion cracking, especially in chloride environments.
  • Reduce stress concentrations with proper support and alignment.

Chemical Exposure Control

  • Avoid excessive chemical concentrations that could lead to corrosion.
  • Regularly clean surfaces to remove corrosive substance buildup.

Mechanical Integrity

  • Monitor components for signs of deformation or wear.
  • Ensure components are not subjected to excessive stress or cyclic loading.

Proper Handling

  • Handle components with care to avoid surface damage.
  • Use appropriate tools and techniques to prevent scratches or dents.

Application-Specific Maintenance

CN7M Applications

  • Focus on keeping pump parts, tank accessories, and valve components free from corrosive residues.
  • Regular inspections and cleanings are essential for performance in aggressive environments.

Alloy 20 Applications

  • Regularly check for corrosion or stress-corrosion cracking in acid production plants and pharmaceutical processing.
  • Ensure material is not subjected to excessive stress or cyclic loading to prolong service life.

Conclusion

Proper heat treatment and regular maintenance are crucial for ensuring the longevity and performance of CN7M and Alloy 20 in demanding environments. By following these guidelines, you can help prevent common issues and maintain the integrity of your components.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What are the key differences between CN7M and Alloy 20 stainless steels?

The key differences between CN7M and Alloy 20 stainless steels lie in their chemical composition, corrosion resistance, heat resistance, and stress-corrosion cracking resistance. CN7M has slightly lower nickel content (27.5-30.5%) compared to Alloy 20 (32-38%), but both contain similar levels of chromium, molybdenum, and copper. CN7M excels in high-temperature applications due to its superior heat tolerance, making it ideal for equipment like pumps that are exposed to prolonged high temperatures. Alloy 20, on the other hand, offers better stress-corrosion cracking resistance, making it suitable for industrial valves and environments where long-term performance under stress is crucial. While both alloys exhibit excellent corrosion resistance, Alloy 20 is particularly effective against pitting and chloride ion corrosion. The choice between CN7M and Alloy 20 depends on the specific application requirements, such as the need for heat resistance, stress-corrosion cracking resistance, and the type of corrosive environment.

Which alloy offers superior corrosion resistance?

Both CN7M and Alloy 20 offer superior corrosion resistance as they are essentially the same alloy in different forms—CN7M being the cast version and Alloy 20 the wrought version. They are particularly resistant to sulfuric acid and other reducing chemicals, making them highly suitable for aggressive chemical environments. Therefore, there is no significant difference in corrosion resistance between the two; the choice depends more on whether a cast or wrought form is required for the application.

How do CN7M and Alloy 20 perform in high-temperature applications?

Both CN7M and Alloy 20 exhibit strong performance in high-temperature applications due to their unique composition and properties. Alloy 20 can maintain its mechanical strength up to moderately high temperatures, performing well up to 1000°F (538°C). It retains its tensile strength and other mechanical properties effectively within this range. Additionally, both alloys show excellent resistance to sulfuric acid, even at high temperatures, and perform well in environments containing other acids such as phosphoric, nitric, and hydrofluoric acids. This makes them suitable for various chemical processing environments at elevated temperatures. Alloy 20 is also stabilized with columbium (niobium) to minimize carbide precipitation during welding, which helps maintain its corrosion resistance and mechanical properties after exposure to high temperatures. These characteristics make CN7M and Alloy 20 highly valuable in industries like chemical processing and power plants, where high-temperature and corrosive environments are common.

Which alloy is better suited for industrial valves versus pumps and other equipment?

Alloy 20 stainless steel is generally better suited for industrial valves and pumps compared to CN7M. Alloy 20 offers superior corrosion resistance, especially in highly corrosive and acidic environments, making it ideal for chemical processing, offshore oil and gas, and petrochemical industries. It also handles a broader temperature range and provides higher strength and durability, which are crucial for critical applications in valves and pumps. CN7M, while excellent for marine and certain petrochemical applications due to its high corrosion resistance and good ductility, may not match Alloy 20’s performance in the most corrosive or high-temperature environments. Therefore, for demanding applications requiring high reliability and resistance to harsh conditions, Alloy 20 is the preferred choice.

What are the typical applications for CN7M and Alloy 20 in the chemical processing industry?

In the chemical processing industry, CN7M and Alloy 20 are typically used in applications requiring high corrosion resistance, particularly against sulfuric acid and other aggressive chemicals. These applications include equipment such as heat exchangers, mixing tanks, piping, and valves. Both alloys are also employed in the fabrication of reactors, storage tanks, and other components exposed to harsh acidic environments. Additionally, they are favored in the production of pharmaceuticals, food and beverage processing, and petrochemical industries due to their excellent resistance to pitting, crevice corrosion, and stress-corrosion cracking. Their mechanical properties and ease of fabrication further enhance their suitability for these demanding applications.

What are the maintenance requirements for CN7M and Alloy 20 stainless steels?

The maintenance requirements for CN7M and Alloy 20 stainless steels focus on preserving their corrosion resistance and mechanical properties. For CN7M, it is essential to perform solution annealing after exposure to temperatures between 800°F and 1600°F to restore optimal corrosion resistance and prevent sensitization. Regular inspections for signs of wear or corrosion, especially in harsh chemical environments, are necessary. Proper cleaning and storage can help prevent surface contamination and maintain the alloy’s properties.

Alloy 20, on the other hand, requires careful attention during welding to minimize carbide precipitation, which is achieved by stabilizing the alloy with Columbium. This ensures good intergranular corrosion resistance. Regular monitoring of the environment to ensure the alloy is not exposed to conditions beyond its corrosion resistance capabilities is also crucial. Both alloys benefit from routine inspections to maintain their integrity in corrosive environments.

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