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Copper C110 vs C122: A Comprehensive Comparison

Copper is a vital material that powers our modern world, from the plumbing systems in our homes to the intricate electrical networks that keep our devices running. Among the various types of copper available, C110 and C122 stand out for their unique properties and applications. But how do you decide which one is right for your project? Whether you’re a homeowner, engineer, or manufacturer, understanding the differences between these two types of copper is crucial for making informed decisions.

In this article, we’ll delve into the specifics of Copper C110 and C122, comparing their chemical compositions, mechanical properties, and corrosion resistance. We’ll explore their suitability for plumbing and electrical applications, as well as their performance in various industrial settings. Additionally, we’ll discuss the fabrication and forming characteristics of each type, and provide insights into their cost and availability. By the end of this comprehensive comparison, you’ll have a clear understanding of which copper alloy best meets your needs, ensuring the success and longevity of your projects. So, let’s get started and uncover the unique advantages that Copper C110 and C122 have to offer.

Introduction

Introduction to Copper and Its Importance

Copper is a highly versatile metal that has been utilized by humans for thousands of years. Its unique properties—including excellent electrical and thermal conductivity, high ductility, and corrosion resistance—make it essential in many industries. Copper has been crucial in enhancing the functionality and durability of products, from ancient artifacts to modern infrastructure.

Significance of Choosing the Right Type of Copper

Choosing the right type of copper for specific applications ensures optimal performance and longevity. Different copper alloys have unique properties suited to various needs. Copper C110 and Copper C122 are two commonly used alloys, each with characteristics suited to specific applications.

Overview of Copper C110 and Copper C122

Copper C110

Copper C110, also known as Electrolytic Tough Pitch (ETP) Copper, is famous for its excellent electrical and thermal conductivity. Containing a small amount of oxygen, this alloy has enhanced conductivity, making it ideal for electrical components, wiring, and telecommunication materials. Its high formability and workability contribute to its widespread use.

Copper C122

Copper C122 is a deoxidized copper alloy, often called DHP (Deoxidized High Phosphorus) Copper. It is known for its high purity and excellent resistance to oxidation and corrosion. These properties make Copper C122 ideal for plumbing and applications requiring high ductility and environmental resistance.

Importance of This Comparison

Understanding the differences between Copper C110 and Copper C122 is crucial for choosing the right material for specific projects. Each alloy has unique advantages and limitations, and choosing the right one can significantly impact the efficiency, durability, and cost-effectiveness of the final product.

This comparison will explore the chemical and mechanical properties, corrosion resistance, electrical and thermal conductivity, applications, fabrication and forming processes, and costs of Copper C110 and Copper C122. By examining these aspects, you will understand which copper alloy best suits your needs.

Chemical and Mechanical Properties

Chemical Composition and Properties of Copper Alloys

Copper alloys are known for their excellent conductivity and versatility in various applications. This section focuses on two popular copper alloys, Copper C110 and Copper C122, detailing their composition, mechanical properties, and key differences.

Copper C110

Copper C110, also known as Electrolytic Tough Pitch (ETP) Copper, is almost entirely pure copper, boasting a 99.9% purity level. A minor constituent, oxygen, is present in small amounts (up to 0.04%). This small oxygen content enhances electrical conductivity but can affect welding performance.

Copper C122

Copper C122, referred to as Deoxidized High Phosphorus (DHP) Copper, also has a high copper purity of at least 99.9%. The presence of phosphorus, ranging from 0.015% to 0.040%, helps remove oxygen, making Copper C122 easier to weld and less prone to hydrogen damage.

Mechanical Properties

Tensile Strength

The tensile strength of Copper C110 varies with its temper:

  • Annealed (Soft): 31,900 psi
  • Half Hard (H02): 42,100 psi
  • Full Hard (H04): 50,000 psi

In comparison, Copper C122 in its annealed form has a similar tensile strength of around 32,000 psi.

Yield Strength

Yield strength, the stress at which a material starts to deform, varies for Copper C110:

  • Annealed (Soft): 10,000 psi
  • Half Hard (H02): 36,300 psi
  • Full Hard (H04): 45,000 psi

Copper C122 in its annealed state has a yield strength of approximately 10,000 psi.

Hardness

The Rockwell hardness of Copper C110 ranges from:

  • Annealed (Soft): F40
  • Half Hard (H02): B40
  • Full Hard (H04): B50

Copper C122’s hardness, though less detailed, is similar to the annealed state of C110.

Machinability

Both Copper C110 and C122 have a machinability rating of 20% compared to free-cutting brass (C360), meaning they are more challenging to machine and require more effort.

Key Differences

Understanding these differences helps engineers and designers choose the right copper alloy for their needs:

  • Deoxidization: C122 contains phosphorus for better weldability.
  • Formability: C122 is easier to shape.
  • Strength: C110 generally has higher strength in hardened states.
  • Applications: C122 is ideal for plumbing; C110 excels in electrical applications.

By understanding these chemical and mechanical differences, engineers and designers can make more informed decisions when selecting the appropriate copper alloy for their specific applications.

Corrosion Resistance

Corrosion Resistance

Copper alloys are renowned for their excellent corrosion resistance, which is a crucial factor in their selection for various applications. This section examines the corrosion resistance of Copper C110 and Copper C122 in different environments, highlighting their suitability for specific conditions based on their chemical composition.

Chemical Composition and Corrosion Resistance

The corrosion resistance of copper alloys largely depends on their chemical composition.

Copper C110 (ETP Copper):

  • Copper C110 is a very pure form of copper, containing at least 99.9% copper and up to 0.05% oxygen.
  • This high purity significantly contributes to its excellent corrosion resistance in many environments, as it lacks impurities that could promote corrosion.

Copper C122 (Phosphorized Copper):

  • Copper C122 has at least 99.9% copper and contains 0.015% to 0.040% phosphorus.
  • Phosphorus acts as a deoxidizer, which improves the alloy’s resistance to corrosion, especially in water and soil.

Environmental Corrosion Resistance

Copper C110:

  • Copper C110 has good corrosion resistance in many indoor and outdoor environments, making it suitable for general atmospheric conditions.
  • However, in environments with significant exposure to water or soil, C110’s performance may not be as robust compared to C122.

Copper C122:

  • The phosphorus in C122 makes it highly resistant to corrosion from water, weather, and soil, making it ideal for plumbing and underground applications.

Comparative Analysis

  • Water Environments: Both C110 and C122 resist corrosion in water, but C122’s phosphorus content gives it an advantage in more aggressive water conditions.
  • Soil Environments: C122 outperforms C110 due to its enhanced resistance to soil-induced corrosion, making it more suitable for underground installations.
  • Atmospheric Conditions: Both alloys perform well in atmospheric conditions, but C110’s high purity ensures strong resistance to atmospheric corrosion.

Practical Implications

Understanding the corrosion resistance of these copper alloys is essential for choosing the right material for specific applications.

  • Plumbing: Copper C122 is preferred for plumbing due to its excellent resistance to water and soil corrosion, ensuring long-lasting and reliable systems.
  • Electrical and General Construction: Copper C110, with its strong atmospheric corrosion resistance and high electrical conductivity, is ideal for electrical components and general construction where exposure to severe water or soil conditions is minimal.

By considering the specific environmental conditions and the corrosion resistance properties of Copper C110 and Copper C122, engineers and designers can make informed decisions to ensure the durability and performance of their projects.

Electrical and Thermal Conductivity

Electrical Conductivity and Thermal Conductivity of Copper Alloys

Copper is widely recognized for its outstanding electrical and thermal conductivity, making it a top choice for various electrical and heat transfer applications. Let’s explore the differences between two popular copper alloys: Copper C110 and Copper C122.

Copper C110

Copper C110, also known as Electrolytic Tough Pitch (ETP) Copper, is highly pure and contains 99.9% copper with minimal oxygen. Its electrical conductivity is 101% IACS (International Annealed Copper Standard), the highest among copper alloys. This exceptional conductivity makes it ideal for electrical wiring, busbars, and connectors.

Copper C122

Copper C122, or Deoxidized High Phosphorus (DHP) Copper, also offers excellent electrical conductivity, though slightly lower than C110. The presence of phosphorus, which deoxidizes the copper, results in a conductivity that is still high but not as optimal as C110. This slight reduction in conductivity is balanced by improved corrosion resistance and weldability.

Thermal Conductivity

Copper’s excellent thermal conductivity makes it perfect for heat transfer applications. Let’s compare the thermal properties of Copper C110 and C122.

Copper C110

Copper C110 excels in thermal conductivity with a rating of 388 W/m.K at 212°F. This high thermal performance makes it ideal for applications such as heat exchangers, radiators, and plumbing systems for hot water.

Copper C122

Copper C122 also has impressive thermal conductivity, although it is slightly lower due to its phosphorus content. Despite this, it remains highly effective for similar applications, offering a balance of good thermal performance and enhanced corrosion resistance.

Considerations for Selection

When choosing between Copper C110 and C122, consider the application’s specific needs. Copper C110 is preferred for maximum electrical and thermal conductivity, making it suitable for electrical wiring and heat exchangers. In contrast, Copper C122 offers enhanced corrosion resistance and easier fabrication, making it ideal for plumbing and heating systems.

Conclusion

Understanding the differences in electrical and thermal conductivity between Copper C110 and C122 helps engineers and designers select the right material for optimal performance and efficiency in their projects.

Applications

Plumbing Applications

When choosing copper for plumbing, both Copper C110 and Copper C122 offer distinct benefits and drawbacks.

Copper C110

Copper C110, although less common in plumbing, can be used due to its excellent forming characteristics and ductility, despite its primary use being in electrical applications.

Copper C122

Copper C122 is the top choice for plumbing due to its high resistance to corrosion in water and soil. The addition of phosphorus improves its resistance to hydrogen embrittlement, making it ideal for brazing and soldering. This makes C122 perfect for pipes, tubes, and other plumbing components.

Electrical Applications

The right copper alloy for electrical use depends on its conductivity and related properties.

Copper C110

Copper C110 is popular in electrical work because of its excellent conductivity (101% IACS). It is perfect for bus bars, wiring, wave guides, and power components due to its high purity and minimal resistance.

Copper C122

Copper C122 also conducts electricity well, though slightly less than C110 because of the phosphorus content. This makes it less suitable for high-conductivity requirements but still a viable option for applications where corrosion resistance and ease of forming are prioritized.

Industrial Manufacturing

In industrial manufacturing, copper alloy properties are crucial for their suitability in different applications.

Copper C110

Copper C110’s high thermal and electrical conductivity make it ideal for heat exchangers and resistance welding electrodes, though its hydrogen embrittlement limits high-temperature use.

Copper C122

Copper C122’s excellent formability and resistance to hydrogen embrittlement make it perfect for industrial tubing like evaporator and heat exchanger tubes. Its ability to handle severe forming and high-temperature processes, such as brazing and welding, makes it versatile for various industrial uses.

Summary of Applications

In summary, Copper C122 is preferred for plumbing due to its corrosion resistance and formability; Copper C110 is best for electrical applications thanks to its superior conductivity; and Copper C122 excels in industrial manufacturing due to its formability and weldability.

Fabrication and Forming

Mechanical Properties and Formability

The mechanical properties and formability of Copper C110 and Copper C122 are critical when considering their use in fabrication and forming.

Copper C110

Copper C110 is highly formable and ductile, making it easy to bend and shape without breaking. It requires minimal force for forming and exhibits excellent cold workability. It can be readily cold drawn with high reductions between annealing cycles, making it suitable for various forming operations. Depending on the temper, its tensile strength can range from 42,100 psi (H02) to 50,000 psi (H04), and yield strength from 36,300 psi (H02) to 45,000 psi (H04).

Copper C122

Copper C122 is also highly formable and offers better weldability and brazing compared to C110. Its tensile strength is typically around 32,000 psi, and yield strength about 10,000 psi, though these can vary depending on temper and treatment.

Welding and Brazing

Welding and brazing are important considerations in the fabrication process.

Copper C110

Copper C110 can be welded, but it requires careful control to prevent oxidation and embrittlement. Using inert gases can help, but this process needs careful handling.

Copper C122

Copper C122 is easier to weld and braze than C110 because its phosphorus content reduces oxidation risk during welding.

Machinability

Both Copper C110 and C122 have moderate machinability, rated at about 20% of free-cutting brass rod (C360), meaning they require appropriate tooling and effort.

Fabrication Processes

The suitability of an alloy for various fabrication processes is essential for its application potential.

Copper C110

Copper C110 can be hot or cold formed, but heating should be minimized to avoid oxidation. It has excellent cold working properties and should be annealed in a reducing or neutral atmosphere to prevent grain growth, making it ideal for precise cold forming.

Copper C122

Copper C122 is versatile for both hot and cold forming due to its improved weldability and brazing properties. Its phosphorus content enhances formability during heavy-forming operations, making it suitable for various fabrication processes.

Summary of Fabrication and Forming

  • Formability: Both Copper C110 and C122 are highly formable, with C122 being easier to shape in heavy-forming operations.
  • Welding and Brazing: C122 is easier to weld and braze than C110 due to its phosphorus content.
  • Machinability: Both alloys have similar moderate machinability, requiring appropriate tooling.
  • Fabrication Processes: Both can be hot or cold formed, but C122 is more versatile due to its phosphorus content.

Cost and Availability

Material Cost

The cost of Copper C110 and Copper C122 is influenced by their purity, specific properties, and market demand.

Copper C110

Copper C110, also known as Electrolytic Tough Pitch (ETP) Copper, is usually more expensive due to its high purity and exceptional electrical and thermal conductivity. The stringent control over impurities in its composition contributes to its elevated cost. This alloy is often more expensive than other copper types, reflecting its superior performance in applications requiring maximum conductivity and minimal contamination.

Copper C122

Copper C122, or Deoxidized High Phosphorus (DHP) Copper, is generally less expensive than Copper C110. The presence of phosphorus deoxidizes the copper, making it slightly less pure but still effective for many uses. The cost of Copper C122 is lower, making it a more economical choice for projects where the highest conductivity is not the primary requirement.

Machining Cost

The machinability of copper alloys also impacts their overall cost, particularly in manufacturing and fabrication processes.

Copper C110

Copper C110 has a lower machinability rating compared to other materials like brass, resulting in higher machining costs. Machining it is relatively costly due to the difficulty in cutting and shaping, which requires specialized tools and processes. This can increase the overall expenditure in projects where extensive machining is necessary.

Copper C122

Copper C122, although also challenging to machine, generally costs less to machine than C110. Its improved formability and mechanical properties facilitate easier machining, which can reduce tooling and labor costs. This makes Copper C122 a cost-effective option for applications involving significant forming and machining.

Availability

The availability of Copper C110 and Copper C122 depends on their demand and the capacity of suppliers to meet market needs.

Copper C110

Copper C110 is widely available from many suppliers, reflecting its popularity in electrical and high-conductivity applications. It is commonly stocked in various forms, including sheets, bars, and machined parts, ensuring that it can be readily sourced for most projects. Suppliers often maintain a robust inventory of Copper C110 due to its high demand in industries that prioritize conductivity.

Copper C122

Copper C122 is also readily available, especially from suppliers focused on plumbing and industrial uses. It is typically stocked in forms such as pipes, fittings, and other standard shapes, catering to its widespread use in plumbing and fabrication. The availability of Copper C122 is bolstered by its versatility and the broad range of applications it supports.

Considerations for Selection

When choosing between Copper C110 and Copper C122, it’s essential to consider both cost and availability in relation to your project requirements.

  • Cost-Effectiveness: If budget constraints are a primary concern and the highest conductivity is not required, Copper C122 offers a more economical solution without significantly compromising on performance.
  • High Conductivity Needs: For applications requiring superior electrical and thermal conductivity, Copper C110 is the preferred choice despite its higher cost.
  • Supply Chain: Ensuring a reliable supply of the chosen copper alloy is vital. Both C110 and C122 are widely available, but verifying supplier capabilities and stock levels can prevent delays and ensure project timelines are met.

By weighing these factors, engineers and project managers can make informed decisions that align with both their technical needs and budgetary constraints.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What are the differences in chemical composition between C110 and C122?

The primary difference in chemical composition between C110 and C122 copper alloys lies in their oxygen and phosphorus content. C110 is essentially pure copper with a minimum copper content of 99.9%, and it contains up to 0.04% oxygen. This small amount of oxygen is naturally present in the copper. In contrast, C122 also has a minimum copper content of 99.9% but includes 0.015% to 0.040% phosphorus. The presence of phosphorus in C122 acts as a deoxidizer, resulting in negligible oxygen content. These differences influence their properties and applications: C110 is valued for its high electrical and thermal conductivity, while C122, with its phosphorus content, is better suited for heavy-forming processes, welding, and environments requiring corrosion resistance.

Which type of copper is more resistant to corrosion?

Both Copper C110 and Copper C122 exhibit strong corrosion resistance and are suitable for various applications where this property is important. The presence of phosphorus in C122 does not provide a significant advantage in corrosion resistance compared to C110. Therefore, neither alloy is distinctly more resistant to corrosion than the other; they are largely equivalent in this aspect.

How do the mechanical properties (tensile strength, yield strength) of C110 and C122 compare?

When comparing the mechanical properties of C110 and C122 copper, C110 generally has higher tensile and yield strengths. In its soft (annealed) temper, C110 has an ultimate tensile strength of 31,900 psi and a yield strength of 10,000 psi. These values increase significantly in its half-hard (H02) and full-hard (H04) tempers, reaching up to 42,100 psi and 50,000 psi in tensile strength, and 36,300 psi and 45,000 psi in yield strength, respectively. On the other hand, C122 copper typically has an ultimate tensile strength of 32,000 psi and a yield strength of 10,000 psi, comparable to the soft temper of C110. However, C122 is particularly noted for its excellent weldability, brazing capabilities, and ease of shaping, making it well-suited for applications such as pipes and tubing. In summary, while C110 offers higher mechanical strength, C122 provides better formability and welding properties.

Which material is better for electrical and thermal conductivity?

Both Copper C110 and C122 have excellent electrical and thermal conductivity due to their high purity levels. C110, known as Electrolytic Tough Pitch (ETP) Copper, and C122, which is deoxidized copper, both maintain similar electrical conductivity and thermal conductivity properties. Therefore, neither material is definitively better than the other in terms of electrical and thermal conductivity. The choice between them should be based on other factors such as cost, ductility, weldability, and specific application requirements.

What are the advantages and disadvantages of using C110 versus C122 in plumbing applications?

When comparing Copper C110 and C122 for plumbing applications, each has distinct advantages and disadvantages.

Copper C110, also known as Electrolytic Tough Pitch (ETP) copper, is generally more cost-effective and offers excellent heat transfer properties, making it suitable for a variety of general plumbing tasks. It also has good durability and corrosion resistance. However, C110 is less ductile, making it more challenging to shape and bend during installation, and it has limited weldability due to the presence of small amounts of oxygen.

On the other hand, Copper C122, or deoxidized copper, is highly valued for its superior corrosion resistance, making it an excellent choice for drinking water pipes and environments where corrosion is a major concern. C122 is more ductile than C110, which facilitates easier bending and shaping during installation. It also boasts better weldability and brazing capabilities, reducing the risk of leaks and simplifying the installation process. The main drawback of C122 is its higher cost, which can be a significant factor in budget-sensitive projects. Additionally, while its enhanced properties are beneficial for specific uses, they may not be necessary for all general plumbing applications, potentially making it less cost-effective.

In summary, C110 is ideal for general plumbing applications due to its cost-effectiveness and good overall properties, while C122 is better suited for applications requiring high corrosion resistance and ease of installation, despite its higher cost.

How do the costs of C110 and C122 compare?

When comparing the costs of C110 and C122 copper, C110 is generally more cost-effective. C110, also known as Electrolytic Tough Pitch (ETP) Copper, is relatively inexpensive due to its 99.9% purity and small oxygen content, making it suitable for general plumbing and electrical applications. On the other hand, C122, or deoxidized copper, is purer and more ductile with added phosphorus for deoxidation, leading to higher costs. C122’s superior corrosion resistance and ductility make it ideal for applications requiring these properties, such as drinking water pipes, but at a higher price point compared to C110. Therefore, while C110 is more economical for many applications, the choice should be based on specific project needs, including corrosion resistance, ductility, and budget constraints.

Which material is easier to form, weld, and braze?

Copper C122 is generally easier to form, weld, and braze compared to Copper C110. C122’s deoxidized nature and higher ductility make it more suitable for forming and bending operations. Unlike C110, which can suffer from embrittlement due to the presence of oxygen when heated, C122 avoids these issues, making it a better choice for welding and brazing applications. Therefore, for processes involving forming, welding, and brazing, Copper C122 is the more appropriate material.

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