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Difference Between Annealing and Tempering

When it comes to metal treatment, understanding the nuances between annealing and tempering is crucial for achieving desired material properties. These processes may seem similar at first glance, but they serve distinct purposes and involve different stages and parameters. Annealing and tempering can significantly alter a metal’s hardness, ductility, and toughness, making them indispensable in industries ranging from aerospace to automotive. Have you ever wondered why annealed steel is more ductile, while tempered steel is tougher? Dive into the intricate world of heat treatment as we explore the differences, process stages, and outcomes of annealing and tempering, and discover how these techniques can transform raw metal into high-performance materials.

Introduction to Annealing and Tempering

Annealing and Tempering: Understanding the Processes

What is Annealing?

Annealing is a vital heat treatment process used to improve the workability and ductility of metals by altering their physical properties. The process involves heating the metal to a specific temperature, holding it at that level, and then cooling it slowly, typically in a controlled environment. This gradual cooling refines the metal’s grain structure, making it softer, more pliable, and less prone to cracking during machining or forming.

Types of Annealing

There are several types of annealing processes, each designed to achieve specific outcomes:

  • Full Annealing: The metal is heated above its critical point and then cooled slowly to refine the grain structure, improving softness and machinability.
  • Stress Relief Annealing: This method reduces internal stresses caused by prior manufacturing processes, such as welding or machining, without significantly altering the metal’s structure.
  • Spheroidizing Annealing: Used for high-carbon steels, this process involves heating the metal just below its critical temperature for an extended period to produce a spherical carbide structure, enhancing machinability.
  • Diffusion Annealing: The metal is heated to a high temperature for a prolonged period to homogenize its chemical composition, ensuring uniformity throughout the material.

What is Tempering?

Tempering is another essential heat treatment process, typically applied to metals after quenching. While quenching hardens the metal, it often leaves it brittle. Tempering alleviates this brittleness, enhancing toughness and durability. The process involves reheating the metal to a temperature below its critical point and then allowing it to cool, which adjusts the balance between hardness and ductility.

Types of Tempering

Tempering can be performed at different temperatures to achieve specific properties:

  • Low-Temperature Tempering (below 200°C): Primarily relieves internal stresses without significantly reducing hardness, making the material more stable.
  • Medium-Temperature Tempering (200°C–400°C): Improves both toughness and ductility while maintaining moderate hardness, making it suitable for tools and structural components.
  • High-Temperature Tempering (above 400°C): Balances hardness and toughness, creating a resilient material that can withstand impact and wear, ideal for applications requiring durability.

Key Differences Between Annealing and Tempering

Understanding the distinctions between annealing and tempering is crucial when selecting the appropriate heat treatment for a given application. Key differences include:

  • Purpose: Annealing softens the metal and improves its ductility, while tempering reduces brittleness and enhances toughness.
  • Temperature: Annealing requires heating above the recrystallization temperature, whereas tempering involves heating to a lower temperature below the critical point.
  • Cooling Process: Annealing involves slow cooling to ensure uniformity, while tempering often uses more rapid cooling methods.
  • Outcome: Annealed metals become easier to machine and form, while tempered metals exhibit greater strength, resilience, and resistance to wear.

Conclusion

By understanding the unique purposes and processes of annealing and tempering, engineers and manufacturers can select the most suitable heat treatment to achieve the desired properties in metals. Whether enhancing ductility for improved machinability or balancing hardness with toughness for durability, these processes play an integral role in shaping materials for diverse industrial applications.

Purpose and Outcomes of Annealing and Tempering

Purpose of Annealing

Annealing is a heat treatment process used to soften metals, making them easier to work with and enhancing their overall durability. This process involves heating the metal and then allowing it to cool slowly, which helps to refine its internal structure and improve its properties.

Stress Relief

During manufacturing, metals can develop internal pressures that may lead to distortion or cracking. Annealing relieves these pressures, ensuring the metal remains stable and durable.

Grain Refinement and Recrystallization

By heating the metal above a certain temperature, annealing allows new, stress-free grains to form. This process restores the metal’s strength, toughness, and flexibility.

Homogenization

Annealing ensures a uniform microstructure by removing inconsistencies. This homogenization reduces defects and promotes consistent material properties throughout the metal.

Improved Ductility and Machinability

The process reduces the hardness of the metal, making it more pliable and easier to machine. This is essential for subsequent manufacturing steps like bending and cutting.

Enhanced Electrical and Magnetic Properties

Annealing can also improve a metal’s electrical conductivity and magnetic characteristics by refining its crystal lattice. This is particularly beneficial for materials used in electrical and electronic applications.

Purpose of Tempering

Tempering is a heat treatment process applied after hardening to achieve a balance between hardness and flexibility, making the metal more practical for everyday use. This involves reheating the metal to a specific temperature below its critical point and then cooling it down.

Reduction of Excess Hardness

Tempering decreases the brittleness that can result from hardening. By reheating and slowly cooling the metal, it becomes more resilient and less prone to breaking.

Toughness Improvement

The process enhances the metal’s toughness, which is its ability to withstand impact and stress without fracturing.

Optimal Balance of Hardness and Ductility

Tempering aims to find the right balance between hardness and flexibility. This makes the material more wear-resistant and suitable for a variety of applications.

Practical Use and Visual Identification

Tempering not only improves the metal’s practical properties but also results in distinct colors that indicate the tempering conditions. This helps in identifying the material’s properties and suitability for specific applications.

Outcomes of Annealing

  • Stress Relief: Alleviates internal pressures, preventing distortion and cracking.
  • Grain Refinement: Forms new, stress-free grains, restoring mechanical properties.
  • Homogenization: Ensures uniform microstructure and consistent properties.
  • Improved Ductility: Enhances formability and machinability.
  • Enhanced Electrical Conductivity: Improves electrical and magnetic properties.

Outcomes of Tempering

  • Reduced Brittleness: Decreases brittleness caused by hardening.
  • Increased Toughness: Enhances the ability to resist fracture.
  • Balanced Hardness and Ductility: Achieves an optimal mix for various uses.
  • Enhanced Practicality and Identification: Improves usability and visual identification through distinct coloring.

Process Stages: Heating

Heating Stages in Annealing

Recovery Stage

The recovery stage focuses on alleviating internal stresses and distortions caused by earlier mechanical operations, such as cold working. This process restores dimensional stability and reduces brittleness, helping the material regain some of its original properties.

Recrystallization Stage

In this stage, new strain-free grains form, replacing deformed ones. This transformation improves ductility, reduces hardness, and refines the material’s microstructure.

Grain Growth Stage

During this stage, larger, uniform grains develop, enhancing ductility while further softening the material. Slow cooling afterward ensures the desired properties without reintroducing stress.

Heating Stages in Tempering

Heating Below the Critical Temperature

Tempering begins by reheating the previously quenched or hardened material to a temperature below its critical point. This phase initiates controlled changes in the microstructure, targeting the reduction of brittleness while retaining sufficient hardness.

Dwelling Phase

This soaking period allows internal stresses to relax and redistributes carbon atoms, partially transforming the brittle martensite into a tougher, more balanced structure.

Key Differences in Heating Between Annealing and Tempering

Annealing softens the material by refining its structure and promoting grain growth. In contrast, tempering adjusts hardness and toughness by modifying an already hardened microstructure.

Process Stages: Cooling

Cooling in Annealing

The cooling phase in annealing is essential for shaping the metal’s internal structure and achieving the right material properties.

Slow Cooling Process

In annealing, the metal is gradually cooled after heating above its recrystallization temperature to form new, uniform grains. This gradual cooling can be achieved through:

  • Furnace Cooling: In furnace cooling, the metal cools slowly inside the furnace, with the temperature decreasing at a controlled rate.
  • Sand or Insulating Medium: Alternatively, the metal can be buried in sand or other insulating materials that retain heat, promoting slow cooling when extreme control over cooling rates is required.

The prolonged cooling time ensures that internal stresses are relieved, making the material softer, more ductile, and easier to machine or form.

Impact on Material Properties

Slow cooling in annealing refines the grain structure, increases ductility, and enhances machinability. It also ensures uniform mechanical and chemical properties throughout the metal.

Cooling in Tempering

The cooling stage in tempering is faster than in annealing but slower than in processes like quenching. It stabilizes the material’s structure and optimizes the balance between hardness and toughness.

Air Cooling

In most tempering applications, the metal is cooled in still air at room temperature after being held at the desired tempering temperature. This method ensures uniform cooling and avoids introducing new stresses.

Controlled Cooling Rate

While tempering does not require the prolonged cooling times of annealing, the cooling rate is still carefully managed to prevent rapid temperature changes that might cause warping or cracking. The relatively faster cooling compared to annealing helps retain some hardness while reducing brittleness.

Effects on Metal Properties

The cooling process in tempering ensures that the desired toughness and flexibility are achieved without sacrificing too much hardness. This balance is critical for applications requiring durable yet resilient materials.

Key Differences in Cooling Between Annealing and Tempering

  • Speed of Cooling: Annealing needs very slow cooling to increase ductility and relieve stress, while tempering uses moderate cooling to balance hardness and toughness.
  • Cooling Environment: Annealing often uses furnace cooling or insulating mediums, while tempering typically involves air cooling.
  • Resulting Properties: Annealing produces softer, more workable metals, whereas tempering focuses on reducing brittleness and enhancing toughness.

The cooling phase in both processes plays a pivotal role in determining the final properties of the metal, tailored to specific industrial requirements.

Effects on Material Properties

Mechanical Properties

Ductility and Malleability

  • Annealing: Annealing increases ductility and malleability, making metals easier to shape without cracking. This softening effect is particularly useful in processes like bending, rolling, or machining, where the material’s pliability is crucial.
  • Tempering: Tempering enhances impact resistance by reducing brittleness, ensuring metals can deform under stress without fracturing. This balance of properties is essential for applications requiring both durability and flexibility.

Hardness and Strength

  • Annealing: The annealing process reduces hardness to make the material softer and easier to work with. While this typically lowers strength, it enhances machinability and formability, which are advantageous in many manufacturing applications.
  • Tempering: Tempering adjusts hardness and strength in a controlled way, reducing excessive hardness from quenching while maintaining durability. This creates a material that is tough yet resistant to wear, making it suitable for tools and structural components.

Toughness

  • Annealing: Although annealing primarily focuses on softening the material, the refined grain structure it produces can moderately improve toughness by reducing internal stresses and defects.
  • Tempering: Tempering is highly effective at enhancing toughness. By transforming brittle martensite into tempered martensite, it creates a microstructure capable of withstanding impact and dynamic loads, making it ideal for critical applications.

Stress Relief

  • Annealing: Annealing relieves internal stresses caused by manufacturing processes like welding, machining, or cold working. This process prevents distortion and cracking, ensuring the material remains dimensionally stable and structurally sound.
  • Tempering: Tempering also reduces internal stresses, particularly those introduced during quenching. By alleviating these stresses, the material gains improved fatigue resistance, making it more reliable under repetitive loading.

Microstructural Changes

Grain Structure

  • Annealing: Annealing promotes grain growth and refinement, replacing deformed grains with new, uniform ones. This refined grain structure enhances machinability, improves ductility, and reduces the likelihood of defects, resulting in a more consistent and reliable material.
  • Tempering: In tempering, the hardened microstructure is modified by redistributing carbon atoms to form tempered martensite. This adjustment reduces brittleness while maintaining sufficient hardness, creating a balanced microstructure ideal for demanding applications.

Alloying Element Redistribution

  • Annealing: Heating during annealing redistributes alloying elements evenly, creating a homogeneous microstructure. This uniformity can improve properties such as corrosion resistance, electrical conductivity, and thermal stability.
  • Tempering: Tempering stabilizes the microstructure by redistributing carbon and alloying elements, enhancing wear resistance and ensuring the material retains its mechanical integrity under stress.

Electrical and Magnetic Properties

  • Annealing: Annealing improves electrical conductivity and restores magnetic properties altered during manufacturing. These enhancements are critical in applications like electrical components and magnetic systems.
  • Tempering: While tempering focuses on mechanical properties, it also stabilizes the microstructure, supporting consistent electrical and magnetic performance in certain materials.

Key Differences in Material Property Effects

  • Softness vs. Toughness: Annealing produces softer, more ductile materials, while tempering creates tougher metals with a balance of hardness and flexibility.
  • Stress Relief Focus: Annealing addresses stresses from prior manufacturing processes, whereas tempering targets stresses introduced during quenching.
  • Microstructural Goals: Annealing refines grain structure and uniformity, while tempering modifies hardened structures for enhanced performance.

By carefully selecting and applying these heat treatment processes, engineers can tailor materials to meet specific mechanical, structural, and functional requirements.

Applications and Industrial Uses

Applications of Annealing

Automotive Industry

In the automotive industry, annealing is essential for making metals easier to shape and machine. This process is particularly critical for forming body panels, as it prevents cracking during shaping. Additionally, engine components such as crankshafts and camshafts are annealed to relieve internal stresses induced by prior manufacturing processes like forging or machining, ensuring dimensional stability and durability.

Aerospace Sector

In the aerospace industry, annealing is crucial for producing components that require high levels of ductility and structural integrity. Aircraft frames and turbine blades undergo annealing to facilitate forming and ensure the material can withstand operational stresses. It ensures consistent material properties, which are crucial for safety.

Construction Industry

Structural materials used in construction, such as reinforcement bars and steel beams, benefit from annealing to improve their formability. Annealing allows these materials to be bent and shaped more easily, making them suitable for use in reinforced concrete structures and load-bearing applications. This process is also employed to ensure consistency and reliability in large-scale structural projects.

Tool-Making Industry

Annealing is crucial in tool-making, as it softens tool steels, relieves stress, and extends the lifespan of tools, molds, and dies. This process is particularly beneficial for high-carbon steels used in cutting tools, as it prepares the material for subsequent hardening and tempering treatments.

General Manufacturing

In general manufacturing, annealing is employed to make metals easier to cut, machine, and form. This is especially important for components that require precise shaping, such as gears, brackets, and housings. The process also ensures uniformity in material properties, which is critical for maintaining product quality and performance.

Applications of Tempering

Automotive Industry

Tempering is essential in the automotive industry to achieve the desired balance of hardness and toughness in critical components. Engine parts like gears, crankshafts, and valves are tempered to enhance their wear resistance and durability under high stress and cyclic loading conditions. Body panels also benefit from tempering to improve their impact resistance without compromising flexibility.

Aerospace Sector

In aerospace applications, tempering is indispensable for components subjected to extreme stress and temperature variations. Landing gear, structural supports, and turbine blades are tempered to enhance their fatigue resistance and ensure long-term reliability. This process is critical for materials that must perform consistently in demanding environments.

Construction Industry

Steel used in construction, such as beams and columns, is tempered to improve its toughness and load-bearing capacity. This treatment ensures that the materials can withstand heavy loads and dynamic forces without failure. Tempered steel is also employed in earthquake-resistant structures due to its ability to absorb and dissipate energy effectively.

Tool-Making Industry

Cutting tools, such as drills, saw blades, and chisels, undergo tempering to achieve the necessary hardness for cutting while reducing brittleness. This balance ensures that the tools are not only sharp but also durable under continuous use. Additionally, molds and dies used in industrial production are tempered to improve their resistance to wear and deformation.

Heavy-Duty Machinery

Tempered metals are widely used in the manufacturing of industrial machinery and equipment, where components must endure high stress and abrasive conditions. Examples include gears, shafts, and bearings, which require enhanced toughness and wear resistance to perform reliably in heavy-duty applications.

Combined Applications of Annealing and Tempering

Enhanced Durability and Workability

In many industries, annealing and tempering are used in sequence to optimize both ductility and strength. For example, annealing prepares the material by relieving stress and improving machinability, while tempering adjusts the hardness and toughness to meet specific operational requirements. This combination is particularly valuable in applications like automotive and aerospace components.

Stress Relief and Dimensional Stability

In addition to improving durability, these processes are also critical for relieving internal stresses and stabilizing materials for precision applications. This approach minimizes the risk of warping or dimensional changes over time, which is critical for components like molds, dies, and high-precision machine parts.

Wear and Fatigue Resistance

Components that experience repetitive loading or abrasive conditions, such as turbine blades and machine gears, benefit from the enhanced wear resistance and fatigue strength achieved through these heat treatments. The dual processes ensure that the materials can withstand prolonged use without premature failure.

Materials Commonly Treated

  • Steels: Carbon steels, alloy steels, and stainless steels are frequently annealed and tempered to improve machinability, strength, and durability.
  • Tool Steels: These materials are annealed for easier machining and then tempered to reduce brittleness, making them suitable for cutting and shaping applications.
  • Cast Iron: Annealing and tempering improve the machinability and mechanical properties of cast iron, making it more versatile for industrial use.
  • Non-Ferrous Metals: Aluminum and copper alloys can also benefit from annealing and tempering processes to enhance ductility and mechanical performance.

Step-by-Step Instructions for Annealing and Tempering

Annealing

Annealing is designed to soften the metal, increase its ductility, and relieve internal stresses, making it more workable.

Steps

  1. Gradual Heating

    • Gradually heat the metal until it reaches a temperature above its recrystallization point but remains below its melting point. For steel, this typically ranges from 1450°F to 1650°F (790°C to 900°C).
  2. Soaking

    • Maintain the metal at this temperature to allow it to heat uniformly. A common guideline is to soak for 1 hour per inch of thickness.
  3. Cooling and Grain Growth

    • Allow the metal to cool slowly in a controlled manner, such as by turning off the heat and letting it cool in the furnace or by burying it in sand. Cool the metal at a maximum rate of 70°F (39°C) per hour to promote uniform grain growth and achieve a stress-free structure.

Tempering

Tempering reduces the excess hardness in hardened steel, balancing hardness and ductility while relieving internal stresses.

Steps

  1. Quenching (Prior to Tempering)

    • Initially, the steel must be quenched to harden it. This involves rapid cooling from a high temperature to room temperature, often using water or oil.
  2. Heating

    • Heat the quenched steel to a precise temperature below its critical point. This temperature varies depending on the desired properties of the steel.
  3. Soaking

    • Keep the steel at this temperature for a set time to allow changes in its internal structure. The exact time depends on the material and the desired properties.
  4. Cooling

    • Cool the steel using an appropriate method for the material. This can range from air cooling to quenching in a medium like oil or water, as per the manufacturer’s requirements.
  5. Visual Inspection (Optional)

    • Tempered steel can exhibit various colors depending on the temperature used, providing a visual clue to its properties. For instance, a straw-yellow color indicates a lower tempering temperature, while a blueish-green hue shows a higher tempering temperature.

Key Differences

  • Temperature: Annealing involves heating to a higher temperature (above the recrystallization point) compared to tempering, which heats to a lower temperature below the critical point.
  • Cooling Process: Annealing typically involves a slower cooling process than tempering. Annealing can take hours to cool slowly, while tempering can use faster cooling methods depending on the material.
  • Purpose and Outcome: Annealing aims to soften and make the material more ductile, while tempering aims to balance hardness and ductility after hardening.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the primary purpose of annealing and tempering in metal treatment?

The primary purpose of annealing in metal treatment is to soften metals, increase ductility, relieve internal stresses, improve machinability, refine grain structure, and enhance properties like corrosion resistance and electrical conductivity. In contrast, tempering aims to reduce excess hardness and brittleness in metals, improve toughness and strength, relieve internal stresses, and achieve a balance between hardness and ductility. These processes are essential for making metals more workable and suitable for various industrial applications, as discussed earlier.

How do the processes of annealing and tempering differ in terms of temperature and cooling?

The processes of annealing and tempering differ significantly in terms of temperature and cooling. Annealing involves heating the metal above its recrystallization temperature (950°C to 1,200°C for ferrous materials) and then cooling it slowly in the furnace, which softens the material and relieves internal stresses. In contrast, tempering is done at lower temperatures (450°C to 700°C) and involves faster cooling rates, either by air or controlled cooling, to reduce excess hardness and brittleness without fully recrystallizing the metal. Thus, annealing aims to make the material more workable, while tempering balances hardness and ductility.

What are the effects of annealing and tempering on the mechanical properties of steel?

Annealing and tempering have distinct effects on the mechanical properties of steel. Annealing softens steel, increases its ductility, and enhances its machinability by reducing internal stresses and refining its microstructure. This process results in steel that is more pliable and easier to work with. On the other hand, tempering reduces the brittleness of hardened steel while maintaining a balance between hardness and toughness. It enhances ductility to a lesser extent than annealing but ensures the steel can withstand impact and stress without failing. Thus, annealing makes steel more workable, while tempering optimizes strength and toughness for demanding applications.

What are the common applications of annealed and tempered steel?

Annealed steel is commonly used in the automotive industry for engine parts, in the aerospace sector for turbine blades, in construction for structural beams and columns, and in manufacturing for precision tools and cold-rolled sheet steel due to its enhanced ductility and reduced hardness. Tempered steel, on the other hand, is utilized in the automotive industry for chassis and axles, in aerospace for high-strength aluminum alloys, in construction for bridges and gears, and in manufacturing for gears and shafts, owing to its balanced hardness, strength, and toughness. These applications highlight the specific mechanical properties achieved through annealing and tempering, as discussed earlier.

Case Studies and Examples

Annealing in Automotive Manufacturing

Annealing is crucial in automotive manufacturing, especially for creating components that need to be both highly ductile and machinable. One notable example involves the production of engine blocks and crankshafts. These components undergo extensive machining and shaping, which can introduce significant internal stresses. To address this, manufacturers anneal the cast iron or steel parts by heating them above their recrystallization temperature and cooling them slowly in a controlled environment.

This process refines the grain structure and relieves internal stresses, preventing warping or cracking during machining. As a result, the annealed components exhibit improved formability and dimensional stability, ensuring their performance and durability under the demanding conditions of automotive engines.

Tempering in Aerospace Applications

In the aerospace sector, tempering is essential for achieving the strength and toughness required for critical components. Landing gear assemblies, made from high-strength alloy steels, are initially quenched to achieve maximum hardness, which unfortunately introduces brittleness. To mitigate this, the quenched components are tempered by reheating them to a temperature below their critical point, followed by controlled cooling. This process reduces brittleness while retaining sufficient hardness and toughness. The tempered landing gear components can withstand repetitive stress and impact, ensuring safety and reliability in aerospace operations.

Example: Annealing for Electrical Conductivity

Annealing is commonly used to enhance the electrical conductivity of metals like copper and aluminum, particularly in the production of electrical wiring. Copper wires are annealed after being drawn into thin strands to restore their ductility and improve conductivity. This is achieved by heating the wires to a specific temperature and then allowing them to cool slowly.

The annealed wires exhibit improved flexibility, making them easier to bend and install without breaking. Additionally, the enhanced conductivity ensures efficient energy transmission, which is critical in power distribution systems and electronic devices.

Example: Tempering for Tool Durability

Tempering is widely used in the tool-making industry to improve the durability and performance of cutting tools. For example, high-carbon steel used in the production of chisels and saw blades is initially hardened through quenching. While this hardening process increases wear resistance, it also makes the tools brittle.

To balance hardness with toughness, the tools are tempered by reheating them to a specific temperature, depending on the desired properties. After tempering, the tools can withstand repeated use and impact without chipping or breaking, making them suitable for demanding industrial applications.

Comparative Example: Annealing vs. Tempering in Construction Materials

In construction, both annealing and tempering are used to optimize the properties of structural materials. For instance, steel reinforcement bars (rebars) used in reinforced concrete structures are often annealed to improve their ductility, allowing them to be bent and shaped during installation. This ensures that the rebars can adapt to the design requirements without cracking.

On the other hand, structural beams used in load-bearing applications are tempered to achieve the necessary combination of strength and toughness. This ensures that the beams can support heavy loads and resist dynamic forces like wind or earthquakes, without failing.

Practical Example: Visual Identification in Tempering

A unique aspect of tempering is the ability to visually identify the achieved properties through color changes on the metal’s surface. For example, in the production of springs, the steel is tempered to specific temperatures that produce a blueish hue, indicating the material’s toughness and flexibility. This color serves as a visual indicator of the tempering conditions, ensuring quality control and consistency in the manufacturing process. In contrast, annealed metals retain their original color but exhibit a softer and more ductile structure, suitable for forming and machining.

Example: Combined Use in Heavy Machinery

In heavy machinery manufacturing, annealing and tempering are often used in combination to optimize performance. For example, the gears and shafts in industrial machinery are first annealed to improve their machinability. This allows precise shaping and cutting without introducing excessive stress. After machining, the components are tempered to enhance their toughness and wear resistance, ensuring reliable operation under high loads and abrasive conditions.

By integrating both processes, manufacturers can produce components that meet stringent performance and durability requirements, making them suitable for heavy-duty industrial applications.

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