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Difference Between Incoloy 800 and Incoloy 825: A Comparative Study

When it comes to selecting the right alloy for demanding applications, the choice between Incoloy 800 and Incoloy 825 can be crucial. These high-performance alloys are renowned for their exceptional resistance to corrosion and their robustness in extreme environments, but their specific properties and ideal applications can vary significantly. Understanding these differences is vital for engineers, designers, and procurement teams who need to make informed decisions that balance performance, cost, and durability.

In this comparative study, we delve into the intricate details that set Incoloy 800 and Incoloy 825 apart. From their chemical compositions to their mechanical properties, we explore how each alloy performs under various conditions. We will also examine their corrosion resistance, a key factor for applications in industries such as chemical processing and power generation. Additionally, we will highlight the typical uses for each alloy, providing insights into where they excel and where they may fall short.

Whether you’re looking to understand the nuances of their physical properties or to determine which alloy offers better cost-effectiveness for your specific needs, this comprehensive analysis will equip you with the knowledge necessary to make the best choice. Join us as we uncover the key differences between Incoloy 800 and Incoloy 825 and guide you through selecting the optimal material for your next project.

Introduction

Overview of Incoloy 800 and Incoloy 825

Incoloy 800 and Incoloy 825 are high-performance alloys recognized for their exceptional resistance to high temperatures and corrosion. They belong to the family of nickel-iron-chromium alloys. These alloys are widely used in various industrial applications due to their robust mechanical properties and resistance to oxidation and carburization.

Understanding the differences between Incoloy 800 and Incoloy 825 is crucial for selecting the appropriate material for specific applications. Each alloy has unique characteristics that make it suitable for certain environments and operational conditions. By comparing their chemical composition, corrosion resistance, physical and mechanical properties, and typical applications, engineers and decision-makers can choose the right material to improve performance, safety, and cost-effectiveness in their projects.

Chemical Composition

Chemical Composition of Incoloy 800 and Incoloy 825

Incoloy 800 and Incoloy 825 are notable for their exceptional performance in challenging environments, thanks to their unique chemical compositions.

Incoloy 800

Incoloy 800 is a nickel-iron-chromium alloy known for its high-temperature strength and corrosion resistance. Its specific chemical composition ensures these properties:

  • Nickel (Ni): 30.0-35.0%
  • Chromium (Cr): 19.0-23.0%
  • Iron (Fe): 39.5% minimum
  • Carbon (C): Up to 0.10% (Incoloy 800), 0.06-0.10% (Incoloy 800H/HT)
  • Aluminium (Al): 0.15-0.60%
  • Titanium (Ti): 0.15-0.60%
  • Sum of Aluminium and Titanium: 0.30-1.20%

This combination provides Incoloy 800 with excellent resistance to oxidation and carburization at high temperatures, making it ideal for high-temperature environments.

Incoloy 825

Incoloy 825 stands out for its superior corrosion resistance in acidic environments. Its additional elements boost its resistance to corrosion in acidic conditions:

  • Nickel (Ni): 38.0-46.0%
  • Chromium (Cr): 19.5-23.5%
  • Iron (Fe): 22.0% minimum
  • Molybdenum (Mo): 2.5-3.5%
  • Copper (Cu): 1.5-3.0%
  • Titanium (Ti): 0.6-1.2%
  • Other Elements:
  • Manganese: 1.0% maximum
  • Silicon: 0.5% maximum
  • Sulphur: 0.03% maximum
  • Aluminium: 0.2% maximum

The presence of molybdenum and copper significantly improves Incoloy 825’s resistance to pitting and crevice corrosion, making it highly effective in environments containing sulfuric and phosphoric acids.

Main Differences in Composition

  • Nickel Content: Incoloy 825 contains more nickel (38.0-46.0%) than Incoloy 800 (30.0-35.0%).
  • Molybdenum and Copper: The presence of molybdenum (2.5-3.5%) and copper (1.5-3.0%) in Incoloy 825 is a major difference. These elements are not present in Incoloy 800 and contribute to Incoloy 825’s superior resistance to certain types of corrosion.
  • Aluminium and Titanium: Both alloys have aluminium and titanium, but in different amounts and roles. Incoloy 800 has aluminium and titanium in the range of 0.15-0.60%, whereas Incoloy 825 has titanium in a higher range (0.6-1.2%) and aluminium up to 0.2%.

Influence of Composition on Properties

  • High-Temperature Strength: Incoloy 800’s composition, particularly its nickel and chromium content, provides excellent high-temperature strength and resistance to oxidation and carburization.
  • Corrosion Resistance: Incoloy 825’s additional elements greatly improve its resistance to pitting, crevice corrosion, and stress corrosion cracking. This makes it highly suitable for use in highly corrosive environments.
  • Stabilization: The titanium content in both alloys stabilizes the structure, preventing sensitization and intergranular corrosion. However, the higher titanium content in Incoloy 825 provides additional stabilization benefits.

In conclusion, while both Incoloy 800 and Incoloy 825 are nickel-iron-chromium alloys, their differing compositions make them suitable for different applications. Incoloy 800 is ideal for high-temperature environments, whereas Incoloy 825 offers superior corrosion resistance in acidic and reducing environments.

Corrosion Resistance

Corrosion Resistance Comparison: Incoloy 800 vs. Incoloy 825

Introduction

Incoloy 800 and Incoloy 825 are renowned for their excellent corrosion resistance, largely attributed to their primary composition of nickel, iron, and chromium. This composition forms a robust foundation against various forms of corrosion, particularly in oxidizing environments, enabling both alloys to maintain their structural integrity in demanding applications.

Enhanced Resistance Through Additional Elements

Incoloy 825 includes extra elements like molybdenum, copper, and titanium, which boost its corrosion resistance. Molybdenum enhances resistance to pitting and crevice corrosion, copper improves performance in reducing environments, and titanium stabilizes the alloy against sensitization and intergranular attack. Incoloy 800, lacking these elements, is less effective in certain corrosive media, such as sulfuric and phosphoric acids.

Resistance in Specific Environments

Acidic Environments: Incoloy 825 excels in resisting sulfuric and phosphoric acids, making it ideal for chemical processing. In contrast, Incoloy 800 is effective but not as robust in these acidic conditions.

Chloride-Containing Environments: Incoloy 825 is highly resistant to chloride-induced issues like stress-corrosion cracking and pitting, making it suitable for marine environments. While Incoloy 800 is also resistant, it is not as effective in these conditions.

Oxidizing Environments: Incoloy 800 thrives in high-temperature oxidizing environments, thanks to its stable chromium oxide layer. This makes it ideal for thermal processing and heat treatment applications.

Stress-Corrosion Cracking and High-Temperature Corrosion

Both alloys resist stress-corrosion cracking well, but Incoloy 825 performs better in chloride-rich environments due to its higher nickel, molybdenum, and copper content. Additionally, Incoloy 800H (a variant of Incoloy 800) can handle higher temperatures (up to 1100°C) compared to Incoloy 825, which is effective up to 540°C.

Application Specialization

Incoloy 800: Ideal for thermal processing and heat treatment furnaces due to its high-temperature oxidation resistance.

Incoloy 825: Best for chemical processing, oil and gas, and marine applications, offering robust resistance to various corrosive environments.

Physical Properties

Density

Incoloy 800 and Incoloy 825 have different densities due to their unique compositions. Incoloy 825 is slightly denser at about 8.14 g/cm³, mainly due to additional elements like molybdenum and copper.

Melting Point

The melting point is crucial for high-temperature applications. Incoloy 825’s higher melting range of 2500-2550°F (1370-1400°C) allows it to maintain structural integrity at elevated temperatures, making it ideal for heat-resistant applications.

Thermal Properties

Both Incoloy 800 and Incoloy 825 are known for their excellent thermal stability, but they have some differences in thermal properties:

  • Specific Heat Capacity: Incoloy 825 is 0.105 Btu/lb•°F (440 J/kg•°C).
  • Thermal Conductivity: Incoloy 825 is 6.4 BTU/h-ft-°F (11.1 W/m-°K) at 70°F (21°C).

Magnetic Properties

Incoloy 825 has better magnetic properties at low temperatures due to its lower Curie temperature. This makes it more suitable for applications where magnetic properties are a consideration.

Coefficient of Thermal Expansion

The coefficient of thermal expansion is important for materials in fluctuating temperatures. Incoloy 825 has a mean coefficient of thermal expansion of 7.7 x 10^-6 in/in/°F (13.9 x 10^-6 mm/m/°C) between 70°F and 212°F (20°C to 100°C), ensuring it can handle thermal cycling without significant changes.

Modulus of Elasticity

The modulus of elasticity measures a material’s stiffness. Incoloy 825 has a modulus of elasticity of 28.4 x 10^3 ksi (196 x 10^3 MPa) in tension, indicating its ability to deform elastically under stress.

Creep-Rupture Strength

Incoloy 800 has slightly higher creep-rupture strength at high temperatures. This makes Incoloy 800 more suitable for high-temperature services like furnace components and heat exchangers, where prolonged thermal stress is common.

By understanding these physical properties, engineers and designers can select the appropriate alloy for their specific application needs, ensuring optimal performance and durability in various industrial environments.

Mechanical Properties

Mechanical Properties of Incoloy 800 and Incoloy 825

The mechanical properties of Incoloy 800 and Incoloy 825 are crucial in determining their suitability for various applications. Key properties include tensile strength, creep-rupture strength, impact strength, and performance at different temperatures.

Tensile Strength

At room temperature, Incoloy 800 exhibits a tensile strength of approximately 86.5 ksi (596 MPa) and maintains high tensile properties at elevated temperatures, making it reliable for high-temperature applications.

Incoloy 825 has a higher tensile strength at room temperature, around 104,500 psi (720 MPa), which can be further enhanced through cold work.

Creep and Rupture Strength

Incoloy 800 is known for its high creep-rupture strength, enduring prolonged stress at elevated temperatures, with variants like Incoloy 800H and 800HT offering even higher strengths due to their specialized chemistries and heat treatments.

Incoloy 825, while having good mechanical properties at moderately high temperatures, is less suitable for applications requiring critical creep-rupture properties.

Cold Work and Strengthening

Cold work significantly increases the tensile properties of Incoloy 800, enhancing its strength in the cold-drawn condition, which is beneficial for applications requiring higher strength without additional heat treatment.

Cold work also strengthens Incoloy 825, maintaining consistent mechanical properties across various forms and conditions, such as tubing, bar, plate, and sheet.

Impact Strength

Both Incoloy 800 and 825 exhibit good impact strength at room temperature and maintain it at cryogenic temperatures. However, the impact strength can vary depending on the specific form and condition of Incoloy 800.

Temperature Tolerance

Incoloy 800 has higher creep-rupture strength at elevated temperatures, suitable for services up to about 1500°F (816°C). In contrast, Incoloy 825 is generally used up to 1000°F (540°C) before significant changes affect its ductility and impact strength.

Understanding these mechanical properties helps engineers select the appropriate alloy for specific applications, ensuring optimal performance and durability in various industrial environments.

Applications

Applications of Incoloy 800

Incoloy 800 excels in high-temperature environments and resists oxidation and carburization, making it indispensable in various industries.

High-Temperature Environments

  • Automotive Industry: Used in exhaust systems and catalytic converters that operate at high temperatures.
  • Resistors: Ideal for electrical resistors that require stability and performance at elevated temperatures.
  • Heat Treatment Equipment: Employed in furnaces, heat exchangers, and other equipment exposed to high thermal loads.

Chemical and Petrochemical Processing

  • Heat Exchangers: Perfect for systems where heat transfer occurs in corrosive environments.
  • Piping Systems: Ideal for transporting fluids in chemical processing plants, particularly in nitric acid media.

Power Plants

  • Super-Heater and Re-Heater Tubing: Crucial for boilers in power plants, handling high steam temperatures and pressures.
  • Industrial Furnaces: Used in furnace components operating at high temperatures, ensuring longevity and reliability.

Pressure Vessels and Heat Exchangers

  • High Fracture and Creep Strengths: Excellent for pressure vessels and heat exchangers, ensuring safety and efficiency under extreme conditions.

Applications of Incoloy 825

Incoloy 825 is highly valued for its exceptional corrosion resistance, especially in acidic environments, making it perfect for specific applications.

Chemical Industry

  • Chemical Processing Equipment: Handles sulfuric, sulfurous, phosphoric, nitric, and hydrofluoric acids, as well as alkalis.
  • Acidic Chloride Solutions: Used in environments with acidic chloride solutions, ensuring durability and resistance to pitting and crevice corrosion.

Marine and Offshore Oil and Gas

  • Seawater Heat Exchangers: Ideal for heat exchangers exposed to seawater, preventing corrosion and extending equipment life.
  • Piping Systems: Used in offshore oil and gas platforms for fluid transport in harsh marine environments.

Air Pollution Control

  • Scrubbers: Utilized in scrubbers and other air pollution control devices operating in corrosive environments, ensuring long-term performance.

Nuclear Industry

  • Fuel Reprocessing: Used in equipment for reprocessing nuclear fuel, where corrosion resistance is critical.
  • Waste Handling: Suitable for handling and processing radioactive waste materials.

Food Processing and Other Industries

  • Food Processing Equipment: Employed in equipment exposed to corrosive food processing environments.
  • Ore and Copper Refining: Used in refining equipment for ore and copper, ensuring resistance to corrosive by-products.
  • Petroleum Refining and Steel Pickling Equipment: Ideal for equipment in petroleum refining and steel pickling processes due to its resistance to corrosive chemicals.

Key Differences in Application

  • Temperature Range: Incoloy 800 is better for high-temperature applications up to 1500°F (816°C), while Incoloy 825 is typically used up to 540°C (1004°F) in corrosive environments.
  • Corrosion Resistance: Incoloy 825 offers superior corrosion resistance, especially in reducing environments and against sulfuric and phosphoric acids, making it more suitable for chemical and marine applications.
  • Cost and Complexity: Incoloy 825 is generally more expensive due to its more complex composition and superior corrosion resistance, making Incoloy 800 a cost-effective option for less severe conditions.

Price and Cost Considerations

Price Comparison

When comparing Incoloy 800 and Incoloy 825, one crucial factor to consider is their price, which is influenced by their chemical compositions and the presence of expensive elements.

Incoloy 800

Incoloy 800 is generally less expensive due to its simpler composition, which includes lower amounts of costly elements like nickel and molybdenum, resulting in a typical price range of $16 to $23 per kilogram.

Incoloy 825

Incoloy 825 is more expensive because it contains higher levels of nickel, chromium, molybdenum, and copper, which enhance its corrosion resistance, particularly in acidic environments. Prices for Incoloy 825 typically range from $25.50 to $35.00 per kilogram, depending on the supplier and product form.

Costs for Specific Applications

High-Temperature Applications

For applications requiring high heat resistance, such as thermal processing or power plant components, Incoloy 800 is often the preferred choice. It can withstand temperatures up to 1100°C, making it suitable for high-temperature environments without the need for higher costs. Its lower overall price makes it an economical choice for these applications.

Corrosive Environments

Incoloy 825’s superior corrosion resistance makes it worth the higher cost in environments with acidic or corrosive substances. The additional expense is offset by its enhanced performance, ensuring a longer service life and reduced maintenance costs. This makes Incoloy 825 a cost-effective option for chemical processing, marine, and oil and gas industries.

Fabrication and Manufacturing Costs

Incoloy 800

Incoloy 800 is relatively easier to fabricate and can be processed using techniques similar to those used for stainless steel alloys. This ease of fabrication can lead to reduced manufacturing costs, making it an attractive option where lower production expenses are important.

Incoloy 825

Although Incoloy 825 can also be fabricated, its more complex composition might require specialized processing techniques. This could increase the overall cost of fabrication, but the specific requirements of the application often justify these specialized processes, ensuring the alloy’s performance in demanding environments.

Balancing Cost and Performance

Choosing between Incoloy 800 and Incoloy 825 involves balancing cost and performance. Incoloy 800 is often selected for its cost-effectiveness in high-temperature applications with less demanding corrosion requirements. In contrast, Incoloy 825 is chosen for its superior corrosion resistance in harsh environments, despite its higher price.

By understanding the price and cost considerations of Incoloy 800 and Incoloy 825, decision-makers can make informed choices that optimize both performance and budget for their specific applications.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What are the key differences in chemical composition between Incoloy 800 and Incoloy 825?

The key differences in the chemical composition between Incoloy 800 and Incoloy 825 primarily lie in their nickel, molybdenum, and copper content. Incoloy 825 contains a higher percentage of nickel (38-46%) compared to Incoloy 800 (30-35%), which enhances its overall corrosion resistance. Additionally, Incoloy 825 includes significant amounts of molybdenum (2.5-3.5%) and copper (1.5-3%), which are not present in Incoloy 800. These elements contribute to Incoloy 825’s superior resistance to localized corrosion, pitting, and stress corrosion cracking. Both alloys contain small amounts of aluminum and titanium, but these elements do not significantly differ between the two. These compositional differences result in Incoloy 825 being more suited for harsh corrosive environments, while Incoloy 800 is preferred for high-temperature applications.

How do Incoloy 800 and Incoloy 825 compare in terms of corrosion resistance?

Incoloy 825 offers superior corrosion resistance compared to Incoloy 800, primarily due to its enhanced chemical composition, which includes additional elements such as molybdenum, copper, and titanium. These elements provide Incoloy 825 with better resistance to reducing environments, such as sulfuric and phosphoric acids, and improve its ability to withstand pitting and crevice corrosion. Incoloy 825 also demonstrates excellent resistance in seawater and marine atmospheres, making it ideal for offshore and coastal applications. While Incoloy 800 is better suited for high-temperature environments and maintains good oxidation resistance, it does not match the comprehensive corrosion resistance of Incoloy 825 in various corrosive conditions.

What are the typical applications for each alloy?

Incoloy 800 is typically used in chemical and petrochemical processing, heat-treating equipment, power plants, industrial furnaces, pressure vessels, heat exchangers, domestic appliances, and the paper pulp industry due to its excellent high-temperature strength, heat resistance, and general corrosion resistance. Incoloy 825, on the other hand, is preferred for chemical processing involving sulfuric and phosphoric acids, marine and offshore applications, high-corrosion environments, the oil and gas industry, and certain nuclear and power generation applications, thanks to its enhanced corrosion resistance from its molybdenum and copper content.

How do the physical properties (density, melting range, etc.) of Incoloy 800 and Incoloy 825 differ?

Incoloy 800 and Incoloy 825 differ in several physical properties. Incoloy 800 has a density of approximately 7.94 g/cm³, while Incoloy 825 has a slightly higher density of about 8.14 g/cm³. The melting range of Incoloy 800 is between 2475-2525°F (1357-1385°C), whereas Incoloy 825 has a melting range of 2500-2550°F (1370-1400°C). Incoloy 800 has a Curie temperature of around -175°F (-115°C), while Incoloy 825 has a Curie temperature below -320°F (-196°C), indicating better magnetic properties at low temperatures. These differences in physical properties, along with variations in chemical composition and corrosion resistance, influence their suitability for different industrial applications.

Which alloy is more cost-effective for high-temperature applications?

Incoloy 800 is generally more cost-effective for high-temperature applications compared to Incoloy 825. This is due to its simpler and less expensive chemical composition, which lacks the additional molybdenum and copper found in Incoloy 825. Incoloy 800 is specifically designed for high-temperature resistance, withstanding temperatures up to 1100°C (2000°F), making it ideal for applications such as furnace components, heat exchangers, and chemical processing equipment. Hence, Incoloy 800 offers the necessary high-temperature performance at a lower cost.

In what environments does Incoloy 825 offer superior performance over Incoloy 800?

Incoloy 825 offers superior performance over Incoloy 800 in environments that require high corrosion resistance, particularly in reducing environments and chloride-rich conditions. This is primarily due to the presence of molybdenum and copper in Incoloy 825, which enhance its resistance to localized corrosion, such as pitting and stress corrosion cracking. Incoloy 825 is especially effective in handling sulfuric and phosphoric acids, making it ideal for chemical processing, marine and oil & gas applications, pollution control equipment, and nuclear industries.

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