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Nickel Alloy C263 (UNS N07263): Composition, Properties, and Uses

When it comes to materials that can withstand extreme temperatures and harsh environments, Nickel Alloy C263 (UNS N07263) stands out as a top contender. Known by various names such as Nimonic 263, Haynes 263, and Hastelloy C-263, this remarkable alloy is revered for its robust performance in the most demanding applications. Whether you’re an engineer designing cutting-edge turbine engines, a manufacturer seeking durable materials for high-temperature components, or a researcher exploring advanced alloys, understanding the composition, properties, and uses of Nickel Alloy C263 is crucial.

In this article, we will delve into the intricate details of this versatile alloy, starting with its precise chemical composition and the significance of each element. We’ll explore its impressive physical and mechanical properties, including its strength at elevated temperatures, exceptional oxidation resistance, and remarkable formability and weldability. Additionally, we’ll highlight the key applications where Alloy C263 excels, from aircraft engines to automotive turbochargers, and discuss the best practices for fabrication and welding.

By the end of this comprehensive guide, you’ll have a thorough understanding of why Nickel Alloy C263 is a preferred choice in high-stress environments and how it can be leveraged to enhance the performance and reliability of your projects. So, let’s embark on this journey to uncover the secrets behind one of the industry’s most resilient and dependable materials.

Introduction

Overview of Nickel Alloy C263

Nickel Alloy C263, or UNS N07263, is a high-performance nickel-based superalloy designed for extreme heat environments. Developed by Rolls-Royce Ltd. in 1971, Nickel Alloy C263 was created to replace Nimonic alloy 80A, with better ductility and weldability.

Common Names and Synonyms

Nickel Alloy C263 is also known as:

  • Nimonic 263
  • Haynes 263
  • Hastelloy C-263

Key Characteristics

The unique composition of Nickel Alloy C263 offers several key properties, making it ideal for demanding applications:

  • High-Temperature Strength: Retains strength at elevated temperatures.
  • Oxidation Resistance: Resists degradation in oxidizing environments.
  • Excellent Formability and Weldability: Easy to form and weld, suitable for complex assemblies.

Typical Uses

Thanks to its robust performance, Nickel Alloy C263 is widely used in various high-stress applications, including:

  • Aircraft and Land-Based Gas Turbines: Essential for parts exposed to extreme temperatures.
  • Automotive Turbochargers: Ideal for high-performance engines.
  • Fabricated Components: Perfect for various industrial high-temperature uses.

Nickel Alloy C263’s versatility and reliability make it a preferred choice in industries where material performance under high-stress and high-temperature conditions is critical.

Chemical Composition

Chemical Composition of Nickel Alloy C263

Nickel Alloy C263, also known as Nimonic 263, is a high-performance material designed for demanding environments. Its balanced composition gives it unique properties that make it suitable for high-temperature and high-stress situations. Each element contributes to its strength and durability in these challenging conditions.

Key Elements and Their Ranges

  • Nickel (Ni): Approximately 51% (balance)
  • Chromium (Cr): 19.0% – 21.0%
  • Cobalt (Co): 19.0% – 21.0%
  • Molybdenum (Mo): 5.60% – 6.10%
  • Titanium (Ti): 1.90% – 2.40%
  • Aluminum (Al): 0.30% – 0.60%
  • Iron (Fe): Up to 0.70%
  • Manganese (Mn): Up to 0.60%
  • Silicon (Si): Up to 0.40%
  • Carbon (C): 0.04% – 0.08%
  • Sulfur (S): Up to 0.007%
  • Boron (B): Up to 0.005%

Role of Each Element

  • Nickel (Ni): Nickel, the main component, provides the base structure and is essential for high-temperature strength and corrosion resistance.
  • Chromium (Cr): Improves resistance to oxidation, important for use in harsh environments.
  • Cobalt (Co): Adds to the alloy’s strength and stability at high temperatures.
  • Molybdenum (Mo): Boosts high-temperature strength and resistance to corrosion.
  • Titanium (Ti): Helps harden the alloy, increasing its strength.
  • Aluminum (Al): Collaborates with titanium to harden the alloy and improve oxidation resistance.
  • Iron (Fe): Iron, though present in small amounts, affects the alloy’s toughness and strength.
  • Manganese (Mn): Improves hot working and helps remove oxygen during melting.
  • Silicon (Si): Acts as a deoxidizer and enhances casting properties.
  • Carbon (C): Small amounts of carbon strengthen the alloy by forming carbides.
  • Sulfur (S): Kept low to maintain ductility and weldability.
  • Boron (B): Tiny amounts of boron strengthen grain boundaries, enhancing high-temperature performance.

The precise balance of these elements ensures Nickel Alloy C263’s exceptional mechanical properties, making it ideal for applications requiring high strength, excellent formability, and resistance to oxidation and corrosion.

Physical and Mechanical Properties

Strength at Elevated Temperatures

Nickel Alloy C263 maintains exceptional strength at high temperatures, making it ideal for demanding, high-stress applications.

Tensile and Yield Strength

At room temperature, Nickel Alloy C263 exhibits a tensile strength of 850-1100 MPa and a yield strength of 550-900 MPa. At elevated temperatures, the alloy retains significant strength: at 700°C, the yield strength is 495 MPa and the tensile strength is 772 MPa; at 800°C, the yield strength is 460 MPa and the tensile strength is 587 MPa; at 900°C, the yield strength is 145 MPa and the tensile strength is 232 MPa; and at 1000°C, the yield strength is 70 MPa and the tensile strength is 108 MPa.

Oxidation Resistance

Nickel Alloy C263 is very resistant to oxidation, which is crucial for high-temperature environments. Chromium and aluminum in the alloy help form a protective oxide layer, preventing damage and extending the material’s life.

Ductility, Formability, and Weldability

Nickel Alloy C263 is known for its ductility, formability, and weldability. It shows good elongation properties, typically between 20% and 35% at room temperature, meaning it can absorb significant deformation without breaking. The alloy can also be easily shaped into complex forms without cracking, which is ideal for intricate designs. Additionally, it can be welded using common techniques like TIG, GMAW, electron beam, and resistance welding, with no risk of cracking after welding, ensuring strong and durable joints.

Density and Modulus of Elasticity

The alloy has a density of about 8.36 g/cm³, balancing strength and weight, which is important for weight-sensitive applications. Its modulus of elasticity is around 213 GPa, indicating its stiffness and resistance to deformation.

High-Temperature Mechanical Properties

Nickel Alloy C263 maintains excellent mechanical properties at high temperatures. Its hardness ranges from 30 HRC to 40 HRC, providing good wear resistance. The alloy also has good impact toughness, essential for applications subjected to sudden loads. It can withstand repeated cyclic loading without failure, making it suitable for dynamic applications, and demonstrates excellent creep resistance, ensuring long-term performance under sustained high-temperature stress.

Applications

Applications of Nickel Alloy C263

Nickel Alloy C263 is widely used in the aerospace and energy industries because of its impressive high-temperature strength and resistance to oxidation. In aircraft turbine engines, it is typically used in low-temperature combustors, transition liners, and ring components, which must withstand extreme temperatures and maintain mechanical integrity. Similarly, in land-based gas turbines, Alloy C263 ensures reliable performance and longevity in power generation applications.

In the automotive industry, Nickel Alloy C263 is used to make turbocharger components that operate at high temperatures, where thermal fatigue and oxidation resistance are crucial. This enhances the efficiency and performance of high-performance engines, making it a preferred material in the automotive sector.

Beyond aerospace, Nickel Alloy C263 is also used in gas turbine components. Its high-temperature strength and oxidation resistance ensure these parts operate efficiently and reliably, even under harsh conditions. This makes it an invaluable material for various gas turbine applications.

In the nuclear industry, Nickel Alloy C263 is used in reactors and other critical components that require high-temperature strength and corrosion resistance. Its robust properties make it suitable for ensuring safety and durability in nuclear reactors, where reliability is paramount.

In industrial settings, the alloy is used in high-temperature processes due to its excellent creep resistance and mechanical stability. This includes chemical processing applications where corrosion and oxidation resistance are essential. Its ability to withstand sustained high-temperature stress makes it ideal for a range of industrial applications.

Nickel Alloy C263 is also used in specialized high-temperature applications like low-temperature combustors, transition liners, and ring components. Its unique properties provide reliable performance and longevity, making it a versatile choice for engineers and designers working with high-temperature systems.

Fabrication and Welding

Forming Characteristics

Nickel Alloy C263 is known for its excellent formability and weldability, making it ideal for complex geometries and high-temperature applications. This alloy can be shaped into intricate designs without cracking, a critical advantage for applications requiring precise and complex components. Cold working techniques, which involve mechanical deformation at room temperature, are particularly effective in enhancing its mechanical properties.

Cold Working

Cold working processes such as rolling, bending, and drawing can be performed at room temperature. These techniques not only enhance the alloy’s strength by introducing dislocations into the metal’s crystal structure but also make it ideal for producing thin-walled components and intricate shapes.

Welding Characteristics

Nickel Alloy C263 can be welded using various techniques, ensuring strong and durable joints suitable for high-temperature environments. This versatility in welding methods allows for the creation of robust components that maintain their integrity and performance.

Recommended Welding Techniques

  • Tungsten Inert Gas (TIG) Welding: Offers excellent control and high-quality welds with minimal contamination.
  • Gas Metal Arc Welding (GMAW): Suitable for both manual and automated applications.
  • Electron Beam Welding: Ideal for producing precise, high-quality welds with minimal distortion.
  • Resistance Welding: Effective for spot welding using electrical resistance.

Using a matching filler metal, like C-263 filler, ensures consistent properties across the weld and base metal. This approach prevents weld metal cracking and maintains mechanical strength, ensuring the welded joints are as robust as the base material.

Post-Weld Heat Treatment

Post-weld heat treatment (PWHT) is crucial to relieve residual stresses and restore mechanical properties. This involves:

  • Solution Annealing: Heating the welded components to 1121°C-1177°C (2050°F-2150°F) followed by rapid cooling to dissolve precipitates and homogenize the structure.
  • Aging: Heating to 800°C-900°C (1472°F-1652°F) for several hours to precipitate the γ’ phase, which enhances the alloy’s strength and performance.

By adhering to these welding and heat treatment guidelines, Nickel Alloy C263 components achieve optimal mechanical properties and long-term reliability in high-temperature applications.

Specifications and Certifications

Overview of Specifications

Nickel Alloy C263 is regulated by various specifications to ensure its quality, performance, and suitability for high-temperature applications. These specifications outline the material’s chemical composition, mechanical properties, and acceptable forms, ensuring consistency and reliability across different batches and suppliers.

AMS Specifications

AMS 5872E covers Nickel Alloy C263 in sheet form, detailing its chemical composition, mechanical properties, and heat treatment conditions, while AMS 5966 pertains to welding wire, ensuring the filler metal matches the base material’s performance.

GE Specifications

GE B50A771 focuses on Nickel Alloy C263 for aircraft engine components, specifying its composition, mechanical properties, and heat treatment for high-stress environments. Additionally, GE B50A783 includes specific testing and quality control measures for turbine engine applications.

Rolls-Royce Specifications

RR 9500/16 outlines Nickel Alloy C263 requirements for aerospace applications, including guidelines for composition, properties, and manufacturing to meet aviation standards.

DIN Standard

DIN 17750 specifies Nickel Alloy C263’s composition, mechanical properties, and permissible deviations for industrial applications.

UNS Number

UNS N07263 is the standard designation for Nickel Alloy C263, ensuring clear communication across industries.

Availability in Different Forms

Nickel Alloy C263 is available in sheet, plate, wire, bar, rod, and forgings, catering to various manufacturing and application needs with high strength and durability.

These specifications ensure that Nickel Alloy C263 consistently meets performance and reliability standards in demanding high-temperature environments.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the chemical composition of Nickel Alloy C263?

Nickel Alloy C263, also known as Nimonic 263 or HAYNES® 263, has a specific chemical composition that includes the following elements: Nickel (Ni) as the balance at 52.00%, Cobalt (Co) ranging from 19.0% to 21.0%, Chromium (Cr) also between 19.0% and 21.0%, and Molybdenum (Mo) from 5.6% to 6.1%. Minor elements include Titanium (Ti) at 1.9% to 2.4% and Aluminum (Al) at 0.3% to 0.6%, with the combined total of Titanium and Aluminum being 2.4% to 2.8%. Trace elements are Carbon (C) at 0.04% to 0.08%, Silicon (Si) up to 0.40%, Manganese (Mn) up to 0.60%, Iron (Fe) up to 0.70%, Copper (Cu) up to 0.20%, Phosphorus (P) up to 0.015%, Sulfur (S) up to 0.007%, Boron (B) up to 0.005%, Silver (Ag) up to 0.0005%, Bismuth (Bi) up to 0.0001%, and Lead (Pb) up to 0.002%. This precise chemical composition contributes to the alloy’s notable properties such as high strength, oxidation resistance, and good weldability.

What are the key properties of Alloy C263?

Nickel Alloy C263 (UNS N07263) exhibits several key properties that make it suitable for high-temperature applications. It has high strength at elevated temperatures, maintaining its mechanical integrity up to 850°C with oxidation resistance up to 1000°C. The alloy also offers excellent ductility, formability, and weldability, allowing for ease of fabrication and assembly. Additionally, it possesses a high modulus of elasticity and good thermal properties, including a thermal expansion coefficient of 11.1 µm/m°C and thermal conductivity of 11.7 W/mK. These characteristics make Alloy C263 particularly valuable in demanding environments such as aircraft turbine engines, land-based turbines, and other high-temperature components.

In which applications is Alloy C263 commonly used?

Nickel Alloy C263 is commonly used in applications that require high-temperature strength and oxidation resistance. It is widely utilized in aircraft and industrial turbine engines, particularly for components like low-temperature combustors, transition liners, and ring components. The alloy is also employed in automotive turbochargers, where its ability to withstand high temperatures and resist oxidation is crucial. Additionally, its excellent fabrication characteristics make it suitable for various fabricated components that require good tensile ductility at intermediate temperatures.

What are the recommended welding techniques for Alloy C263?

The recommended welding techniques for Nickel Alloy C263 (UNS N07263) include Tungsten Inert Gas (TIG) welding, Gas Metal Arc Welding (GMAW or MIG), electron beam welding, and resistance welding. TIG welding, both automatic and manual, is suitable for material thicknesses up to 3.25 mm and for more complex joints. MIG welding is preferred for thicker materials above 4.8 mm, using "dip" transfer conditions. Electron beam welding is employed for high precision and minimal heat input requirements, while resistance welding methods like spot, stitch, and seam welding are also effective. It is crucial to use NIMONIC filler metal 263 for all argon-shielded processes and to avoid argon-oxygen mixtures or carbon dioxide as shielding gases. Pre-weld heat treatment is generally unnecessary, but post-weld age-hardening treatment may be required to restore mechanical properties.

What specifications and certifications are relevant for Alloy C263?

Relevant specifications and certifications for Nickel Alloy C263 (UNS N07263) include AMS 5872, AMS 5872E, AMS 5886, and AMS 5966, which cover various forms including weld wire. Additional specifications include GE B50A771 and B50A783, as well as RR 9500/16. These standards ensure the material meets the required quality and performance criteria for high-temperature applications, particularly in the aerospace and energy sectors. The alloy is also identified by UNS N07263 and W. Nr./EN 2.4650.

How does Alloy C263 compare to other high-temperature alloys?

Nickel Alloy C263 (UNS N07263) is a high-temperature alloy known for its excellent fabrication characteristics and weldability. Compared to other high-temperature alloys like Waspaloy or Rene 41, Alloy C263 offers moderate high-temperature strength but is easier to form and weld, making it advantageous in applications where these properties are critical. It has good oxidation resistance up to 1800°F (982°C), comparable to other gamma-prime-strengthened superalloys. However, for applications demanding the highest possible strength at elevated temperatures, other alloys like Haynes 282 may be preferred due to their superior tensile, creep-rupture, and fatigue strength. Overall, Alloy C263 strikes a balance between strength, formability, and weldability, making it suitable for a variety of high-temperature applications.

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