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Nitronic 60 (UNS S21800): Composition, Properties, and Uses

In the world of industrial materials, Nitronic 60 stands out as a versatile and high-performance alloy, known for its remarkable resistance to wear and galling. Whether you’re an engineer, industry professional, or researcher, understanding this alloy’s unique composition and properties can unlock new possibilities for your projects. With its superior corrosion resistance and impressive mechanical properties, Nitronic 60 is not just another stainless steel—it’s a game-changer in applications ranging from valve stems to pump parts. In this article, we’ll dive into the intricate details of Nitronic 60, exploring its chemical makeup, physical and mechanical characteristics, and the diverse applications that benefit from its exceptional performance. Get ready to discover why Nitronic 60 is a material of choice for demanding environments and critical components.

Introduction

Overview of Nitronic 60

Nitronic 60, also known as UNS S21800, is a specialized type of austenitic stainless steel. It is well-regarded for its exceptional mechanical strength, corrosion resistance, and wear resistance, making it ideal for demanding industrial applications.

Chemical Composition

Nitronic 60’s unique blend of chromium, nickel, silicon, and manganese gives it superior resistance to wear, galling, and corrosion.

Mechanical Strength

Nitronic 60 has significantly higher yield and tensile strength compared to conventional stainless steels like 304 and 316, making it suitable for applications requiring robust performance under stress.

Corrosion Resistance

Nitronic 60 offers excellent resistance to corrosion, particularly in chloride environments, outperforming 304 stainless steel and rivaling 316 stainless steel in many conditions.

Wear and Galling Resistance

Its outstanding wear and galling resistance are due to the presence of silicon and manganese, which reduce the tendency to seize or gall under sliding contact, making it ideal for applications with moving parts or repeated friction.

Applications

Given its exceptional properties, Nitronic 60 is widely used in manufacturing valve stems, pump shafts, fasteners, and other components that require high strength and wear resistance, as well as in chemical processing, petrochemical, and marine applications.

Conclusion

In summary, Nitronic 60 (UNS S21800) is a versatile, high-performance stainless steel alloy known for its mechanical strength, corrosion resistance, and wear resistance, making it a reliable choice for various demanding industrial applications.

Chemical Composition

Composition and Properties of Nitronic 60

Nitronic 60 contains a maximum of 0.10% carbon. This low carbon content helps maintain the alloy’s austenitic structure and prevents carbide formation at grain boundaries, which can lead to intergranular corrosion.

Chromium, which makes up 16.0% to 18.0% of Nitronic 60, significantly enhances the alloy’s corrosion resistance by forming a protective oxide layer on the surface.

With 8.0% to 9.0% nickel, the alloy benefits from improved toughness, ductility, and resistance to corrosion and oxidation.

Manganese, present in 7.0% to 9.0%, stabilizes the austenitic structure and improves wear resistance and resistance to galling.

Containing 3.5% to 4.5% silicon, the alloy gains enhanced high-temperature oxidation resistance, strength, and toughness.

Nitrogen, ranging from 0.08% to 0.18%, boosts the alloy’s yield and tensile strength without affecting ductility, and also improves resistance to pitting and crevice corrosion.

Low levels of phosphorus (below 0.06%) and sulfur (below 0.03%) are essential to maintain the alloy’s toughness and prevent embrittlement.

With up to 0.75% molybdenum, Nitronic 60’s resistance to pitting and crevice corrosion, especially in chloride environments, is enhanced.

The balanced combination of these elements provides Nitronic 60 with its unique properties, including excellent mechanical strength, superior wear and galling resistance, and robust corrosion resistance.

Physical Properties

Physical and Mechanical Properties of Nitronic 60

Nitronic 60 is known for its unique physical properties that make it a popular choice in various industries. One of its key properties is its density, approximately 0.275 lb/in³, which provides a good balance between weight and structural integrity.

Yield and Tensile Strength

In its annealed condition, Nitronic 60 has a minimum yield strength of 50 ksi (345 MPa) and a minimum tensile strength of 95 ksi (655 MPa), showcasing its ability to handle significant stress and tensile forces.

Elongation and Hardness

Nitronic 60 also offers excellent ductility with a minimum elongation of 35% and a hardness of less than 241 HBW (Brinell Hardness) and 100 HRBW (Rockwell Hardness), indicating its resistance to stretching and surface indentation.

Thermal and Electrical Properties

Modulus of Elasticity

The modulus of elasticity for Nitronic 60 is 26.2 x 10^6 psi, demonstrating the material’s stiffness and resistance to deformation under load.

Coefficient of Thermal Expansion

With a coefficient of thermal expansion of 8.8 x 10^-6 per °F (between 68-212°F), Nitronic 60 remains stable through temperature changes, minimizing expansion or contraction.

Thermal Conductivity and Specific Heat

Nitronic 60 has a thermal conductivity of 9.0 Btu/ft hr °F and a specific heat of 0.12 Btu/lb °F, allowing it to effectively manage and store thermal energy.

Electrical Resistivity

Its electrical resistivity is 28.7 microhm-in, making Nitronic 60 suitable for applications requiring minimal electrical conductivity.

Summary of Physical Properties

Overall, the physical properties of Nitronic 60—its density, strength, ductility, thermal stability, and electrical resistivity—make it an ideal material for a wide range of demanding applications.

Mechanical Properties

Mechanical Properties of Nitronic 60

Nitronic 60 is known for its impressive mechanical strength, especially when annealed.

Yield Strength

With a minimum yield strength of 50 ksi (345 MPa), Nitronic 60 can withstand substantial stress before permanently deforming, making it ideal for high-integrity applications.

Tensile Strength

The tensile strength of Nitronic 60 is a minimum of 95 ksi (655 MPa). This means that Nitronic 60 can endure significant pulling forces, which is crucial for load-bearing applications.

Elongation

Elongation refers to the ability of a material to stretch significantly before breaking. Nitronic 60 has an elongation of at least 35%. This high ductility is important for applications requiring materials to absorb energy and deform without fracturing, such as in seismic conditions.

Hardness

In its annealed state, Nitronic 60 has a hardness of less than 241 HBW and 100 HRBW, balancing wear resistance with machinability.

Modulus of Elasticity

The modulus of elasticity of Nitronic 60 is 26.2 x 10^6 psi. This high stiffness means the material resists elastic deformation, which is beneficial for structural applications needing stability.

Impact Resistance

Nitronic 60 has excellent impact resistance, meaning it can absorb energy during deformation and resist fractures under sudden loads. This property is particularly valuable in applications where the material may be subjected to sudden forces or shocks, ensuring reliability and durability.

Fatigue Strength

Nitronic 60’s good fatigue strength makes it suitable for applications involving repeated loading cycles, such as rotating machinery.

Wear and Galling Resistance

A key feature of Nitronic 60 is its exceptional resistance to wear and galling. Silicon and manganese in the alloy reduce the chances of parts seizing or galling during sliding contact. This makes Nitronic 60 ideal for components that frequently experience friction and wear, like bushings, shafts, and fasteners.

Summary of Mechanical Properties

In summary, Nitronic 60 offers a robust combination of high yield and tensile strength, excellent ductility, moderate hardness, and superior wear and galling resistance. These properties make it perfect for demanding applications across industries like chemical processing, petrochemical, and marine environments, where reliability and performance are critical.

Performance Characteristics

Corrosion Resistance

Nitronic 60 is highly resistant to corrosion, making it ideal for use in tough environments. Thanks to its composition, including chromium and silicon, Nitronic 60 outperforms 304 stainless steel in many environments and rivals the pitting resistance of 316 stainless steel. This makes it an excellent choice for applications in marine, chemical, and petrochemical industries where exposure to corrosive elements is a concern.

Wear and Galling Resistance

Nitronic 60 stands out for its excellent wear and galling resistance. Manganese and silicon in the alloy help prevent the material from seizing or galling during sliding contact. This durability extends the lifespan of components and reduces maintenance costs. It is particularly beneficial for applications involving frequent assembly and disassembly, as well as components that experience repetitive friction, such as fasteners, bushings, and valve stems.

Oxidation Resistance

Nitronic 60 is also highly resistant to oxidation, making it ideal for high-temperature applications. Thanks to chromium and silicon, the alloy can resist oxidation and maintain its strength up to 1800°F. This makes Nitronic 60 comparable to 309 stainless steel and suitable for high-temperature applications like automotive valves and furnace parts.

Fatigue Resistance

Nitronic 60 is also highly resistant to fatigue. Its ability to endure repeated loading cycles without failing is essential for rotating machinery and dynamic environments. This ensures reliable and long-lasting components, making Nitronic 60 a preferred choice for critical industrial applications.

Impact Resistance

Nitronic 60 can absorb energy during deformation and resist fractures under sudden loads. This is especially valuable in environments with shocks or sudden forces, like aerospace and military applications. Its toughness ensures durability and reliability in tough conditions.

Summary of Performance Characteristics

With its resistance to corrosion, wear, galling, oxidation, fatigue, and impact, Nitronic 60 is a versatile and reliable material for many applications. These qualities make Nitronic 60 ideal for various industries, offering long-lasting and dependable service in challenging environments.

Applications

Industries and Applications

Nitronic 60 finds extensive use across various industries due to its unique combination of mechanical strength, corrosion resistance, and wear resistance. Below are some key industries and their specific applications of Nitronic 60:

Chemical, Petrochemical, and Pharmaceutical Industries

Nitronic 60 is highly valued in the chemical, petrochemical, and pharmaceutical industries for its resistance to corrosive environments and high temperatures. Typical applications include:

  • Valves and Flanges: Used in pipelines and processing equipment where resistance to corrosion and wear is critical.
  • Pump Components: Such as shafts, impellers, and casings, which benefit from its strength and resistance to wear.
  • Heat Exchangers: Ideal for heat exchangers due to its resistance to corrosion and oxidation.

Food Processing Industry

Nitronic 60’s non-magnetic properties and excellent corrosion resistance make it ideal for the food processing industry, including applications such as:

  • Processing Equipment: Mixers, conveyor systems, and cutting tools benefit from its durability and ease of cleaning.
  • Storage Tanks and Vessels: Used for handling food products, ensuring resistance to corrosion and ease of cleaning.

Aerospace Industry

In aerospace, Nitronic 60 is valued for its strength, wear resistance, and performance at high temperatures:

  • Engine Components: Such as valves, shafts, and fasteners, which require materials that can withstand high stresses and temperatures.
  • Structural Components: Used in areas where high strength-to-weight ratios are needed.

Oil and Gas Industry

The oil and gas industry benefits from Nitronic 60’s robust mechanical properties and resistance to wear and corrosion:

  • Downhole Tools and Equipment: Drill collars, stabilizers, and rotary steerable tools benefit from its resistance to wear.
  • Pipeline Components: Valve stems, seats, and fittings require materials that resist corrosion.

Marine Industry

Nitronic 60’s resistance to corrosion in marine environments makes it suitable for various applications:

  • Boat Shafts and Propellers: Beneficial for their strength and resistance to seawater corrosion.
  • Marine Hardware: Fasteners, pins, and fittings benefit from its durability and resistance to wear.

Specific Components

Nitronic 60 is also used in the manufacture of specific mechanical components that require high strength, corrosion resistance, and wear resistance:

Fasteners and Pins

  • Bolts and Nuts: Used in assemblies that require frequent disassembly, benefiting from its resistance to galling and corrosion.
  • Shear Pins and Bushings: Utilized in mechanical systems where high strength and wear resistance are essential.

Valve Components

  • Valve Stems and Seats: High strength and wear resistance are crucial for maintaining performance in harsh environments.
  • Valve Trim: Ensures long service life and resistance to wear in control valves.

Compressor and Pump Shafts

  • Compressor Shafts: Employed in industrial compressors where resistance to fatigue and wear is necessary.
  • Pump Shafts: Used in various pumping systems requiring materials that can withstand high stress and corrosive media.

Miscellaneous Mechanical Parts

  • Wear Rings: In pumps and compressors, maintaining efficiency and reducing maintenance due to their wear resistance.
  • Engine Valves: In internal combustion engines, benefiting from its high-temperature strength and resistance to galling.

Nitronic 60’s combination of mechanical properties, corrosion resistance, and wear resistance makes it a versatile and valuable material for a wide range of demanding applications across multiple industries.

Standards and Specifications

Chemical Composition Standards

Nitronic 60 meets strict chemical composition standards to ensure consistent properties. The chemical composition limits include:

  • Carbon (C): max 0.10%
  • Chromium (Cr): 16.0-18.0%
  • Nickel (Ni): 8.0-9.0%
  • Manganese (Mn): 7.0-9.0%
  • Silicon (Si): 3.5-4.5%
  • Nitrogen (N): 0.08-0.18%
  • Molybdenum (Mo): max 0.75%
  • Phosphorus (P): max 0.060%
  • Sulfur (S): max 0.030%

Mechanical Properties Standards

Annealed Condition

  • Ultimate Tensile Strength: 95-105 ksi
  • Yield Strength (0.2%): 50-55 ksi
  • Elongation in 4D: 35%
  • Reduction of Area: 55%
  • Hardness HB: 170-255

High Strength Conditions

  • Level 1:
  • Ultimate Tensile Strength: 110 ksi
  • Yield Strength: 90 ksi
  • Elongation: 35%
  • Reduction of Area: 55%
  • Level 2:
  • Ultimate Tensile Strength: 135 ksi
  • Yield Strength: 105 ksi
  • Elongation: 20%
  • Reduction of Area: 50%
  • Level 3:
  • Ultimate Tensile Strength: 160 ksi
  • Yield Strength: 130 ksi
  • Elongation: 15%
  • Reduction of Area: 45%
  • Level 4:
  • Ultimate Tensile Strength: 180 ksi
  • Yield Strength: 145 ksi
  • Elongation: 12%
  • Reduction of Area: 45%
  • Level 5:
  • Ultimate Tensile Strength: 200 ksi
  • Yield Strength: 180 ksi
  • Elongation: 10%
  • Reduction of Area: 45%

Physical Properties Standards

Nitronic 60’s physical properties are regulated to ensure its performance in various applications:

  • Density: 0.275 lb/in³
  • Modulus of Elasticity: 26.2 x 10^6 psi
  • Coefficient of Thermal Expansion: 8.8 x 10^-6 /°F (68-212°F)
  • Thermal Conductivity: 9.0 Btu/ft hr °F
  • Specific Heat: 0.12 Btu/lb °F
  • Electrical Resistivity: 28.7 microhm-in

Applicable Standards and Specifications

Nitronic 60 complies with several industry standards to ensure reliability and performance:

  • AMS 5848: Bars, Forgings, Wire
  • ASTM A240: Sheet and Plate
  • ASTM A276 / ASME SA276: Bars and Shapes
  • ASTM A479 / ASME SA479: Forgings and Bars
  • ASTM A193 Grade B8S: Bolts and Studs
  • ASTM A194 / ASME SA194: Nuts

Comparison with Other Stainless Steel Grades

Chemical Composition

Nitronic 60 (UNS S21800) stands out due to its unique chemical composition, setting it apart from other stainless steel grades. Nitronic 60 contains 8-9% Nickel, 16-18% Chromium, 7-9% Manganese, 3.5-4.5% Silicon, 0.08-0.18% Nitrogen, and a maximum of 0.10% Carbon. In comparison, 304 Stainless Steel typically includes 18-20% Chromium, 8-12% Nickel, and a maximum of 0.08% Carbon, with no significant Silicon or Manganese. Similarly, 316 Stainless Steel contains 16-18% Chromium, 10-14% Nickel, 2% Molybdenum, and a maximum of 0.08% Carbon, and 309 Stainless Steel features 22-24% Chromium and 12-15% Nickel, without notable amounts of Silicon or Manganese.

Mechanical Properties

Yield and Tensile Strength

Nitronic 60 has a significantly higher yield strength (50-55 ksi) and ultimate tensile strength (95-105 ksi) compared to 304 and 316 stainless steels, which have yield strengths around 30 ksi and ultimate tensile strengths around 70 ksi.

Elongation and Hardness

Nitronic 60 offers high elongation (35%) and moderate hardness, making it more ductile and wear-resistant than 304 and 316 stainless steels.

Corrosion and Oxidation Resistance

Nitronic 60 provides superior corrosion and chloride pitting resistance compared to 304 and 316 stainless steels. Its oxidation resistance is comparable to 309 stainless steel and better than 304.

Galling Resistance

Nitronic 60 is renowned for its exceptional galling resistance, even at high temperatures, due to its Silicon and Manganese content. In contrast, 304 and 316 stainless steels do not offer the same level of resistance.

Industrial Applications

Nitronic 60 is extensively used in industries like Aerospace, Food and Drug, Oil Field, Petrochemical, Surgical, and Chemical Processing, ideal for high-strength and corrosion-resistant applications such as fasteners, valves, and pump parts. In comparison, 304 stainless steel is common in kitchen utensils and food processing equipment, while 316 is preferred for marine equipment and medical devices.

Summary

Overall, Nitronic 60 excels with its high strength, exceptional galling resistance, and superior corrosion and oxidation resistance, making it a top choice for demanding applications over standard grades like 304 and 316.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the chemical composition of Nitronic 60?

Nitronic 60, also known as UNS S21800, has the following chemical composition: Carbon (C) maximum 0.10%, Manganese (Mn) 7.00-9.00%, Phosphorus (P) maximum 0.060%, Sulphur (S) maximum 0.030%, Silicon (Si) 3.50-4.50%, Chromium (Cr) 16.00-18.00%, Nickel (Ni) 8.00-9.00%, Nitrogen (N) 0.08-0.18%, Molybdenum (Mo) maximum 0.75%, Copper (Cu) 0.75%, and Iron (Fe) balance. This unique composition enhances its properties, such as wear and galling resistance, corrosion resistance, and high-temperature performance.

What are the mechanical properties of Nitronic 60?

Nitronic 60 (UNS S21800) possesses notable mechanical properties in its annealed condition. It has a minimum tensile strength of approximately 95 ksi (655 MPa) and a minimum yield strength of around 50 ksi (345 MPa) at 0.2% offset. The alloy also exhibits a minimum elongation of 35% in 4D (50mm) and a reduction of area typically greater than 55%. The hardness of Nitronic 60 is less than 241 HBW (Brinell hardness) and less than 100 HRBW (Rockwell B hardness). It maintains good strength up to 1800°F (982°C) and can be cold worked to achieve higher strength levels. These mechanical properties, along with its excellent galling resistance and good corrosion resistance, make Nitronic 60 suitable for various demanding applications.

How does Nitronic 60 resist corrosion and galling?

Nitronic 60 resists corrosion and galling due to its unique chemical composition and mechanical properties. The alloy offers superior chloride pitting resistance, stress corrosion cracking resistance, and crevice corrosion resistance compared to Type 316 stainless steel. This is primarily due to the presence of elements like chromium, nickel, manganese, silicon, and nitrogen in its composition. Additionally, Nitronic 60 is specifically designed to prevent galling and fretting, even in the annealed condition, thanks to its high silicon and manganese content. Its significant wear resistance, maintained even at high temperatures, further enhances its performance in applications where both corrosion and galling are concerns.

What are the typical applications of Nitronic 60?

Nitronic 60 is utilized in various demanding applications due to its unique combination of high strength, excellent corrosion resistance, and superior resistance to galling and wear. Typical applications include components in the chemical, petrochemical, and pharmaceutical industries such as valves, flanges, pump parts, and heat exchangers. It is also used in machine and hydraulic systems for hydraulic components and engine valves, in the food industry for pump wear rings and other food processing equipment, and in the aerospace sector for various high-strength, wear-resistant parts. Additionally, Nitronic 60 is used for fasteners, pins, valve stems, seats, trim, shafts, bushings, springs, chains, surgical instruments, and oil field components.

What standards apply to Nitronic 60?

Several standards apply to Nitronic 60 (UNS S21800), ensuring its composition, properties, and applications are well-defined. Key standards include:

  • AMS 5848: For bars, forgings, and wire.
  • ASTM A240: For sheet and plate.
  • ASTM A193 Grade B8S: For bolts and studs.
  • ASTM A194 / ASME SA194: For nuts.
  • ASTM A276 / ASME SA276: For bars and shapes.
  • ASTM A479 / ASME A479: For bars and forgings.
  • ASME SA194 and SA479 Grade B8S: Additional specifications for nuts and bars/forgings.

These standards ensure that Nitronic 60 meets the necessary requirements for its diverse applications across various industries.

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