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Properties, Composition, and Uses of Haynes 188 Alloy

Imagine a material that can withstand the searing heat of a jet engine, resist the corrosive atmosphere of chemical processing plants, and maintain its strength and integrity in the most demanding environments. Meet Haynes 188 Alloy, a marvel of modern metallurgy that has become indispensable across various high-performance industries. This cobalt-based superalloy is renowned for its exceptional high-temperature strength, remarkable oxidation and corrosion resistance, and versatile fabrication capabilities. In this article, we will delve into the intricate chemical composition that gives Haynes 188 its unique properties, explore its impressive physical and mechanical characteristics, and uncover the diverse applications that benefit from this extraordinary material. Whether you are an engineer, manufacturer, or researcher, join us on this journey to understand why Haynes 188 Alloy is the go-to choice for critical applications where reliability and performance are paramount.

Chemical Composition

Chemical Composition of Haynes 188 Alloy

Haynes 188 Alloy, also known as Udimet 188, is a superalloy composed primarily of cobalt, nickel, chromium, and tungsten. This specific blend of elements imparts the alloy with its exceptional properties, making it suitable for high-temperature and corrosive environments.

Key Components

  • Cobalt (Co): Cobalt, making up 37-39% of the alloy, provides the base and contributes to high-temperature strength and stability.
  • Nickel (Ni): Nickel, at 20-24%, enhances the alloy’s resistance to oxidation and corrosion while adding to its strength and toughness.
  • Chromium (Cr): Chromium, comprising 21-23%, forms a protective oxide layer, offering excellent resistance to oxidation and sulfidation.
  • Tungsten (W): Tungsten, at 13-16%, significantly boosts the alloy’s strength at high temperatures.
  • Lanthanum (La): Lanthanum, present at 0.03-0.12%, improves the formation of the protective oxide scale, enhancing oxidation resistance.

Minor Components

Carbon (0.05-0.15%) aids in forming carbides for strength and hardness. Minor components like Manganese (up to 1.25%), Iron (up to 3%), Silicon (0.20-0.50%), Phosphorus (up to 0.02%), Sulfur (up to 0.015%), and Boron (up to 0.015%) fine-tune the alloy’s properties, enhancing its workability and overall performance.

Summary of Chemical Composition

The carefully balanced chemical composition of Haynes 188 Alloy ensures it has the high-temperature strength, oxidation and sulfidation resistance, and metallurgical stability required for demanding applications in aerospace and gas turbines.

Physical Properties

Physical Properties of Haynes 188 Alloy

Density

Haynes 188 alloy has a density of about 8.98 g/cm³ (0.324 lbs/in³), which is typical for superalloys used in high-temperature applications. This high density contributes to its strength and stability under extreme conditions.

Melting Point

The melting range of Haynes 188 alloy is between 1300°C and 1330°C (2372°F to 2426°F), making it ideal for applications involving sustained high temperatures, such as aerospace and gas turbine components.

Thermal Conductivity

Haynes 188 exhibits a thermal conductivity of 10.4 W/m°K or 72 BTUin/hrft²°F at 22°C (72°F). This property ensures efficient heat distribution, preventing localized overheating and maintaining structural integrity.

Coefficient of Thermal Expansion

With a coefficient of thermal expansion of 12.1 µm/(m°C) or 6.7 µin/(in°F), the material maintains dimensional stability even with temperature changes. This is crucial for components subjected to thermal cycling.

Electrical Resistivity

Haynes 188 has a high electrical resistivity of 101.0 µohmm (39.6 µohmin), making it suitable for applications requiring electrical insulation at elevated temperatures.

Modulus of Elasticity

The modulus of elasticity of 232 GPa (33.7 Mpsi) indicates the alloy’s strong resistance to deformation under stress. This contributes to its strength and rigidity in demanding applications.

Hardness

Parts made from Haynes 188 can achieve a hardness of up to 30 HRC (Rockwell Hardness), reflecting its resistance to surface deformation and wear. This hardness is essential for components exposed to abrasive environments.

Summary of Physical Properties

Haynes 188 alloy’s physical properties, including its high density, melting point, thermal conductivity, and electrical resistivity, make it ideal for high-temperature and high-stress applications. These properties ensure reliable performance in demanding environments like the aerospace and gas turbine industries, where both thermal and mechanical stability are crucial.

Mechanical Properties

Mechanical Properties of Haynes 188 Alloy

Tensile Strength

Haynes 188 alloy is known for its outstanding tensile strength, making it ideal for high-stress applications. Its tensile strength at room temperature can reach up to 125 ksi (862 MPa). While this strength decreases slightly at higher temperatures, it still maintains around 90 ksi (621 MPa) at 1200°F (649°C). In manufactured parts, the tensile strength can reach up to 140,000 psi (965 MPa), making it ideal for aerospace and power generation applications.

Yield Strength

The yield strength of Haynes 188 alloy is equally important, as it marks the stress level where the material starts to deform permanently. At room temperature, the yield strength is about 55 ksi (379 MPa), but it drops to 36 ksi (248 MPa) at 1200°F (649°C). Optimal processing can increase yield strengths to between 45,000 psi (310 MPa) and 65,000 psi (448 MPa), ensuring robustness under operational stresses.

Ductility

Haynes 188 alloy has excellent ductility, meaning it can undergo significant deformation before breaking. Typically, the alloy elongates between 40% and 50%. This high ductility indicates that the material can absorb considerable energy and deform without fracturing, which is beneficial in applications where flexibility and toughness are required.

Hardness

Haynes 188 alloy can reach a hardness of up to 30 HRC on the Rockwell scale. This balance ensures the alloy can withstand wear and high stress without becoming brittle. The hardness ensures the alloy’s surface can resist deformation and abrasion, extending the lifespan of parts used in demanding environments.

Impact of Cold Working

Cold working, which deforms the material at room temperature, significantly enhances its yield and tensile strengths. For example, at 0% cold work, the yield strength is about 136 ksi (938 MPa) and the tensile strength is 192 ksi (1324 MPa). At 20% cold work, these values rise to 161 ksi (1110 MPa) and 224 ksi (1544 MPa), respectively. With higher cold work levels (37% and 50%), yield strengths can reach up to 238 ksi (1641 MPa) and tensile strengths up to 314 ksi (2165 MPa). These enhanced properties make cold-worked Haynes 188 alloy ideal for applications requiring superior mechanical strength and durability.

High-Temperature Performance

Haynes 188 alloy retains excellent mechanical properties even at high temperatures, up to 2000°F (1095°C). This makes it ideal for gas turbine engines, combustion chambers, and other extreme heat environments. Its ability to maintain strength and integrity at high temperatures ensures reliable performance and durability in demanding conditions.

Applications and Industries

Aerospace

Haynes 188 alloy is extensively utilized in the aerospace industry due to its remarkable high-temperature strength and oxidation resistance, making it ideal for critical components that must endure extreme temperatures and corrosive environments. Key applications in this sector include:

  • Turbine Engines: The alloy is used for turbine blades and vanes, which operate under high-stress conditions and require materials that can maintain integrity at elevated temperatures.
  • Combustion Chambers: Haynes 188 is used in combustion chambers where high temperatures and pressures are common, requiring materials with excellent thermal stability.
  • Afterburner Parts: The alloy is chosen for afterburner liners and other components because it can withstand high-temperature oxidation.
  • Flame Holders: The alloy’s resistance to thermal fatigue makes it suitable for flame holders in jet engines.
  • Transition Ducts: Haynes 188 is used in transition ducts, which connect various sections of turbine engines and must endure significant thermal cycles.

Chemical Processing

Haynes 188’s resistance to various corrosive environments makes it invaluable in the chemical processing industry. In this field, the alloy is used in several key areas, including:

  • Reactor Vessels: Used in reactors where chemical reactions occur at elevated temperatures, requiring materials that resist corrosion and maintain structural integrity.
  • Heat Exchangers: The alloy’s thermal conductivity and resistance to oxidation make it suitable for heat exchangers, which transfer heat between different fluids.
  • Piping Systems: Haynes 188 is employed in piping systems that handle corrosive chemicals, ensuring long-term reliability and performance.

Gas Turbines

In gas turbines, Haynes 188 alloy’s high-temperature strength and oxidation resistance are critical. The alloy is crucial for components like:

  • Combustion Cans: These components are exposed to intense heat and require materials that can withstand thermal cycling without degrading.
  • Spray Bars: Used in fuel injection systems, spray bars made from Haynes 188 ensure efficient fuel distribution and combustion.
  • Turbine Blades and Vanes: The alloy’s ability to maintain mechanical properties at high temperatures makes it ideal for blades and vanes in gas turbines.

Industrial Heating

Haynes 188 alloy is also used in industrial heating applications, where components are exposed to high temperatures and cyclic thermal stresses. Notable uses include:

  • Burner Nozzles: The alloy’s thermal stability and resistance to oxidation make it suitable for burner nozzles in industrial furnaces and kilns.
  • Flame Holders: In both aerospace and industrial heating systems, flame holders made from Haynes 188 benefit from the alloy’s resistance to thermal fatigue.
  • High-Temperature Components: Various other components in industrial heating systems utilize Haynes 188 for its durability and performance under extreme conditions.

Power Generation

The power generation industry, particularly those involving gas turbines, uses Haynes 188 alloy for several high-temperature components. Its applications include:

  • Burner Cans: These components are essential in power plants, where they must withstand high temperatures and corrosive environments.
  • Transition Ducts: Similar to aerospace applications, transition ducts in power plants benefit from the alloy’s thermal stability and resistance to oxidation.

Haynes 188 alloy’s exceptional performance in high-temperature and corrosive environments makes it a preferred choice across aerospace, chemical processing, gas turbines, industrial heating, and power generation industries.

Fabrication and Welding

Fabrication Properties

Haynes 188 alloy exhibits excellent fabrication properties, making it suitable for various manufacturing processes. The alloy can be formed, forged, hot-worked, or cold-worked to produce complex components used in demanding applications.

Forming

Haynes 188 alloy is highly formable, allowing it to be shaped through various processes such as forging, rolling, and more. However, due to its rapid work-hardening behavior, frequent intermediate annealing treatments are recommended during complex forming operations to maintain workability and prevent cracking.

Cold Working

Cold working involves deforming the alloy at room temperature, which significantly increases its yield and tensile strengths. Due to rapid work-hardening, intermediate annealing is necessary to relieve stresses and maintain ductility.

Hot Working

Hot working, such as forging and rolling at high temperatures, is also suitable for Haynes 188 alloy. The alloy must be heated to the right temperature range to ensure it remains plastic and doesn’t crack. Hot working typically occurs between 1800°F and 2150°F (982°C to 1177°C).

Annealing

Annealing is a key heat treatment process for Haynes 188 alloy, usually done at 2150°F (1175°C). This treatment, followed by rapid air or water quenching, helps achieve the alloy’s best properties. It’s important to avoid annealing below the solution heat-treating temperature to prevent carbide precipitation, which can harm the alloy’s properties.

Welding Properties

Haynes 188 alloy is known for its excellent weldability, suitable for various welding techniques in manufacturing high-performance components.

Welding Methods

The alloy can be welded using several methods, including:

  • Gas Tungsten Arc Welding (TIG): Ideal for precise control, thin sections, and intricate welds.
  • Gas Metal Arc Welding (MIG): Suitable for thicker sections with high deposition rates.
  • Electron Beam Welding: Provides deep penetration and minimal distortion, perfect for high-precision applications.
  • Resistance Welding: Best for joining thin sheets and small components with minimal heat input.

Post-Weld Treatment

After welding, it’s recommended to anneal the alloy and cool it quickly to restore optimal properties. This post-weld heat treatment helps relieve residual stresses, improve ductility, and maintain high-temperature performance and corrosion resistance.

Summary of Fabrication and Welding

Haynes 188 alloy’s fabrication and welding properties make it a versatile material for high-performance components. Its formability, suitability for hot and cold working, and excellent weldability ensure that complex parts can be produced with the desired mechanical and thermal properties. Proper heat treatment and intermediate annealing are crucial to maintaining the alloy’s optimal characteristics throughout the fabrication process.

High-Temperature Strength and Corrosion Resistance

High-Temperature Service

Haynes 188 alloy is known for its outstanding performance in high-temperature environments. This cobalt-based superalloy maintains its strength and ductility even after prolonged exposure to elevated temperatures, making it ideal for applications requiring sustained high-temperature service.

  • Strength Retention: The alloy retains good strength up to 1800°F (982°C), ensuring that components can handle mechanical stresses in such conditions.
  • Creep Resistance: The tungsten content significantly improves the alloy’s resistance to creep, which is the tendency to deform under mechanical stress at high temperatures.

Oxidation Resistance

Haynes 188 alloy has excellent oxidation resistance due to its high chromium content and the presence of lanthanum, which together form a protective oxide scale.

  • Protective Oxide Layer: The alloy can resist oxidation up to 2100°F (1149°C) by forming a protective oxide layer on its surface.
  • Durability in Harsh Environments: This oxidation resistance ensures components remain durable and maintain structural integrity in oxidizing environments at high temperatures.

Sulfidation Resistance

Haynes 188 alloy also resists sulfidation, a type of high-temperature corrosion caused by sulfur-bearing gases.

  • Protection Against Sulfur Compounds: The chromium and nickel in the alloy help protect against the corrosive effects of sulfur compounds found in industrial applications.

Corrosion Resistance in Diverse Environments

Haynes 188 alloy performs exceptionally well in various corrosive environments, making it suitable for many industrial applications.

  • Chemical Processing: The alloy’s resistance to corrosive chemicals makes it ideal for reactor vessels, heat exchangers, and piping systems in the chemical processing industry.
  • Aerospace and Gas Turbines: In aerospace and gas turbines, the alloy’s resistance to oxidation, sulfidation, and other corrosion ensures reliable performance and longevity of critical components.

Summary of Properties

Haynes 188 alloy’s high-temperature strength, oxidation, and sulfidation resistance make it a preferred material for applications demanding durability and performance in extreme conditions. These properties ensure components made from Haynes 188 withstand the harsh environments typical in aerospace, chemical processing, and power generation industries.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the chemical composition of Haynes 188 Alloy?

Haynes 188 Alloy, also known as Udimet 188, is a cobalt-based superalloy with the following chemical composition: Cobalt (Co) is the primary element, comprising approximately 37-39%. Nickel (Ni) ranges between 20-24%, Chromium (Cr) is 21-24%, and Tungsten (W) is 13-16%. The alloy also contains Iron (Fe) up to 3%, Manganese (Mn) up to 1.25%, Silicon (Si) between 0.20-0.50%, Carbon (C) from 0.05-0.15%, and Lanthanum (La) between 0.03-0.12%. Additionally, it includes Phosphorus (P) up to 0.02%, Sulfur (S) up to 0.015%, and Boron (B) up to 0.015%. This precise combination of elements contributes to the alloy’s exceptional high-temperature strength and corrosion resistance.

What are the physical properties of Haynes 188 Alloy?

Haynes 188 Alloy has several notable physical properties. It has a density of 8.98 g/cm³ (0.324 lbs/in³). The modulus of elasticity is 232 GPa (33.7 Mpsi) at 22 °C (72 °F), and the modulus of rigidity at 20°C (70°F) is 90 GPa (13 x 10^3 ksi). The coefficient of thermal expansion is 12.1 µm/(m°C) or 6.7 µin/(in°F) at 22 °C (72 °F). The electrical resistivity is 101.0 µohmm (39.6 µohmin), and the thermal conductivity is 10.4 W/m°K (72 BTUin/hrft²°F). Various hardness measurements include Brinell hardness of 282, Knoop hardness of 323, Rockwell C hardness of 31.1, and Vickers hardness of 309. The melting point range of the alloy is 1315 – 1410 °C (2399 – 2570 °F).

What are the mechanical properties of Haynes 188 Alloy?

The mechanical properties of Haynes 188 Alloy include high tensile and yield strength, good ductility, and significant hardness. The tensile strength in the annealed condition is about 125 ksi (862 MPa), increasing with cold working: 224 ksi (1544 MPa) at 20% cold work, 292 ksi (2013 MPa) at 37%, and 314 ksi (2165 MPa) at 50%. The yield strength is typically 55 ksi (379 MPa) in the solution-treated condition. The elongation at break ranges from 34% in the annealed state to 3.3% at 50% cold working. Hardness is generally ≤302 HB in the solution-treated state. The alloy retains its strength at high temperatures, with a tensile strength of 90 ksi (621 MPa) at 1200°F (649°C), and demonstrates good oxidation and sulfidation resistance up to 2000°F (1095°C).

What are the typical applications of Haynes 188 Alloy?

Haynes 188 Alloy is widely used in high-performance applications due to its exceptional high-temperature strength, oxidation resistance, and corrosion resistance. Typical applications include:

  1. Aerospace: It is used in turbine engines for components such as combustion chambers, flame holders, transition ducts, and afterburner liners.
  2. Power Generation: In gas turbines, it is utilized for burner cans and transition ducts.
  3. Chemical Processing: The alloy’s resistance to corrosive substances makes it suitable for various components in chemical processing environments.
  4. Automotive and Aerospace Exhaust Systems: It is employed in exhaust systems and components that must resist thermal oxidation and degradation.
  5. Weld Overlay and Cladding: The alloy is used to provide surface protection against wear and corrosion.
  6. Nuclear Applications: Its high-temperature strength and corrosion resistance make it suitable for use in nuclear environments.

Can Haynes 188 Alloy be cold worked?

Yes, Haynes 188 Alloy can be cold worked. However, it work-hardens very rapidly, which necessitates frequent intermediate annealing treatments to maintain its formability and optimal properties during complex forming operations. This alloy’s good ductility allows it to be readily formed by cold working, but the need for annealing is crucial to restore the balance of properties.

What welding techniques are suitable for Haynes 188 Alloy?

Suitable welding techniques for Haynes 188 Alloy include Gas Tungsten Arc Welding (GTAW/TIG), Gas Metal Arc Welding (GMAW/MIG), Electron Beam Welding (EBW), and Resistance Welding. These methods are preferred due to their ability to provide precise control over the weld area, minimal heat input, and preservation of the alloy’s high-temperature properties and corrosion resistance. Submerged Arc Welding (SAW) is generally discouraged because its high heat input can lead to undesirable effects such as distortion and hot cracking.

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