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Zinc Spray Metallizing: An Overview

Imagine a protective armor that shields industrial structures from the relentless assault of corrosion, extending their lifespan and saving costs on repairs. Zinc spray metallizing offers just that—a robust, efficient solution for safeguarding steel structures against the harshest environments. But how does this process work, and what makes it superior to other protective coatings? In this article, we will delve into the intricate process of zinc spray metallizing, explore the necessary surface preparation techniques, and examine the advanced equipment used. Additionally, we will highlight the remarkable benefits, potential applications, and limitations of this innovative coating method. Ready to uncover the secrets of zinc spray metallizing and discover how it can revolutionize your corrosion protection strategy? Let’s dive in.

Introduction to Zinc Spray Metallizing

Overview of Zinc Spray Metallizing

Zinc spray metallizing, also known as thermal spray coating, is a process primarily used to protect metal and concrete surfaces from corrosion and physical wear. This technique is particularly valuable in industrial and marine environments where structures are exposed to harsh conditions.

How Zinc Spray Metallizing Works

In zinc spray metallizing, zinc powder or wire is melted and then sprayed as molten droplets onto the surface to be coated. This is achieved through a thermal spray gun that utilizes either a flame or an electric arc to melt the zinc. The molten zinc is then propelled onto the surface using compressed air or combustion gases, forming a protective coating.

Key Benefits of Zinc Spray Metallizing

Corrosion Protection and Versatility

Zinc spray metallizing offers robust corrosion protection as the zinc coating acts as a sacrificial anode, providing cathodic protection to the underlying metal. This ensures that even if the coating is damaged, the exposed steel remains protected from rust and corrosion. Moreover, the process can be applied to a wide range of structures, including those too large for traditional hot-dip galvanizing. This makes it ideal for on-site applications, especially for existing structures that cannot be easily moved or dismantled.

Environmental Benefits

The metallizing process does not use solvents, so it does not emit volatile organic compounds (VOCs), making it an environmentally friendly option compared to other coating methods. Additionally, the process has minimal cure time, allowing coated structures to be quickly returned to service.

Surface Preparation for Effective Coating

Proper surface preparation is crucial for the success of zinc spray metallizing. Surfaces must be thoroughly cleaned to remove contaminants such as oil, grease, and rust. This is typically achieved through abrasive blast cleaning, ensuring the surface is at near white metal cleanliness. Proper preparation ensures optimal adhesion of the zinc coating and maximizes its protective properties.

Application Techniques and Equipment

The application of zinc spray metallizing requires specialized equipment and skilled operators. The thermal spray gun, which can be flame or electric arc type, is used to melt and spray the zinc. The process involves spraying in horizontal overlapping lines to achieve a uniform thickness. Skilled operators are essential to ensure the consistency and quality of the coating, particularly on edges and corners where coatings tend to be thinner.

Long-Term Durability and Maintenance

Zinc spray metallizing provides long-lasting protection, often extending the lifespan of structures by decades. The coating is somewhat self-healing, as zinc corrosion products fill in any pores, maintaining the integrity of the protective layer. This reduces the need for frequent maintenance and repair, resulting in lower long-term costs.

Zinc spray metallizing is a versatile and effective method for protecting metal and concrete surfaces from corrosion and wear. Its ability to provide robust protection, environmental benefits, and applicability to large and complex structures makes it a valuable technique in various industrial and marine applications.

Surface Preparation Techniques

Cleanliness and Surface Condition

A clean surface is crucial for the success of zinc spray metallizing. The surface must be meticulously cleaned to ensure that the zinc coating adheres properly and remains durable over time.

  • Blast Cleaning Standards: The surface should be cleaned to achieve a near-white metal finish, typically to SSPC-SP5/NACE No. 1 or SSPC-SP 10/NACE No. 2 standards, ensuring all oil, grease, weld flux residue, weld spatter, and corrosion products are removed according to SSPC-SP 1, Solvent Cleaning standards.

Abrasive Blast Cleaning

Abrasive blast cleaning is the preferred method for surface preparation prior to zinc spray metallizing.

  • Creating Surface Texture: The blast cleaning process not only cleans the surface but also creates a texture by forming a series of peaks and valleys. This increases the surface area, enhancing the adhesion of the zinc coating.
  • Abrasive Material: The abrasive used should be angular and of adequate size to create a surface profile of 2.5-5 mil (63-125 µm).
  • Coverage: The blast cleaning should extend into the surrounding, undamaged, galvanized coating to ensure seamless integration of the new zinc coating.

Removal of Surface Hardening

Surface hardening from processes like torch cutting must be addressed. This can be done by grinding to ensure a uniform surface profile, which is crucial for maintaining adhesion during mechanical flexing or thermal expansion and contraction of the steel.

Additional Preparation Steps

Various other preparation steps are necessary to ensure the surface is ready for zinc spray metallizing.

  • Weld Spatter and Laminations: These must be removed according to the specifications in the contract documents.
  • Surface Salt Contamination: Salt contamination should be eliminated to prevent future issues with coating adhesion.
  • Inappropriate Methods: Hand or power tool cleaning, water jetting, or chemical stripping are not suitable for thermal spray coatings. Abrasive blast cleaning remains the recommended method.

Immediate Application After Preparation

The timing of the zinc spraying is critical to maintain the integrity of the prepared surface.

  • Prompt Application: The zinc spraying should be completed within four hours after surface preparation, or before any visible oxides develop on the cleaned surface.

Environmental Considerations

While zinc spray metallizing is generally robust, high humidity can affect adhesion. Therefore, it’s best to monitor weather conditions to ensure optimal results.

Operator Skill and Quality Control

The quality of the zinc thermal spray coating is highly dependent on the skill of the operator.

  • Skilled Workers: The spraying should be performed by skilled workers to ensure a uniform coating thickness, applied in horizontal overlapping lines.
  • Qualification Standards: Contractors performing metallizing work should be qualified according to standards such as SSPC-QP 6 to guarantee high-quality workmanship.

By following these detailed surface preparation techniques, the zinc spray metallizing process can achieve a durable and effective corrosion protection coating.

Application Process and Equipment

Surface Preparation

Proper surface preparation is essential before applying the zinc coating. This usually involves blast cleaning to SSPC-SP5/NACE No.1 standards to remove oil, grease, weld residue, spatter, and rust. This preparation ensures a strong bond between the substrate and the zinc coating.

Application Method

Zinc, in wire or powder form, is melted in a heated gun and sprayed onto the prepared surface using combustion gases or compressed air. The heat can be generated by an oxygen-fuel gas flame or an electric arc.

Application Techniques

Skilled workers should apply the zinc spray within four hours of surface preparation to prevent oxide formation. They should use horizontal overlapping lines to ensure an even coating.

Coating Characteristics and Sealants

The zinc coating is rough and slightly porous, about 80% as dense as hot-dip galvanizing. It offers reliable cathodic protection as zinc corrosion products fill the pores over time. A thin sealant layer of polyurethane, epoxy-phenolic, epoxy, or vinyl resin can further enhance its protection.

Application Locations

Zinc spray metallizing can be applied both in-shop and on-site. However, it is more commonly done in-shop where heat for melting is more readily available. On-site applications are feasible, especially for large structures that cannot be transported to a galvanizing facility.

Metallizing Guns and Equipment

Specialized guns melt zinc wire or powder before spraying it onto the substrate, powered by combustion gases or electric arcs. For example, Thermion’s Precision Arc 4.8, ideal for large-scale field use, boasts features like high deposition efficiency, heavy-duty wire straighteners, and remote monitoring.

Wire and Powder Feed Systems

The equipment includes systems for feeding zinc wire or powder into the heated gun. For example, the Precision Arc 4.8 can use 3/16" diameter wire, which is more efficient than smaller diameter wires, allowing for higher deposition rates.

Safety and Control Features

Modern metallizing equipment often includes safety features such as arc shorting control technology, emergency shut-off, and high-temperature machine components. These features ensure safe and efficient operation of the equipment.

Automation and Manual Operation

Some equipment, like the Precision Arc 4.8, can be operated either manually or automated, making it versatile for various application needs and increasing productivity.

Coating Characteristics

Texture and Porosity

Zinc spray metallizing coatings are usually rough and somewhat porous because molten zinc particles are sprayed onto the surface and harden quickly. The coating’s density is about 80% of that achieved through hot-dip galvanizing. Over time, the pores in the coating are filled with zinc corrosion products, which enhances the coating’s protective properties and ensures consistent cathodic protection.

Adhesion

Zinc spray metallizing creates a strong mechanical bond as molten zinc particles stick to the surface with kinetic energy, but it does not form zinc-iron alloy layers like hot-dip galvanizing. The adhesion quality is highly dependent on surface preparation and the skill of the operator, ensuring that the coating is well-bonded to the substrate.

Thickness and Consistency

The coating thickness is usually over 10 mils (254 µm), providing good coverage for welds and seams. Consistent thickness can be tricky and depends on the operator’s skill. Coatings tend to be thinner on corners and edges, and the process is not suitable for coating recesses and cavities. Skilled operators can mitigate these inconsistencies to some extent by adjusting their techniques.

Corrosion Resistance and Durability

Zinc spray metallizing offers top-notch corrosion resistance, often rivaling or surpassing hot-dip galvanizing. The zinc coating sacrifices itself to protect the underlying metal, ensuring lasting durability. The durability of the coating is enhanced as zinc corrosion products fill the pores, maintaining continuous protection.

Environmental Adaptability

A key advantage of zinc spray metallizing is its adaptability. It can be applied in various temperatures and humidity levels without losing quality. This makes it suitable for on-site applications in diverse climates and conditions.

Additional Treatments and Benefits

To enhance the protective qualities of the zinc coating, it can be sealed with a thin layer of low viscosity polyurethane, epoxy-phenolic, epoxy, or vinyl resin. This sealing process improves the coating’s durability and resistance to environmental factors. Additionally, the metallizing process is cost-effective in the long term and offers the advantage of being portable, allowing for on-site application.

Summary

Zinc spray metallizing offers a robust, corrosion-resistant coating with several unique characteristics. Its rough, porous texture and mechanical adhesion provide reliable protection, while its adaptability and additional sealing treatments enhance its durability and versatility. These characteristics make zinc spray metallizing an excellent choice for protecting metal surfaces in various industrial applications.

Benefits and Advantages of Metallizing

Corrosion Resistance

Zinc spray metallizing offers exceptional corrosion resistance. As zinc corrodes, it fills in pores and maintains a consistent barrier, ensuring long-term durability and rust protection. This sacrificial anode effect means the zinc coating continues to protect the underlying steel, providing robust defense against corrosion.

Versatility and Portability

You can apply zinc spray metallizing both in-shop and on-site, unlike hot-dip galvanizing that requires a galvanizing kettle. This makes it an ideal choice for large structures that cannot be deconstructed or transported. The portability of the process reduces logistical challenges and allows for on-site application, enhancing its versatility for various projects.

Cost-Effectiveness

Although the initial cost of zinc spray metallizing may be higher than some other methods, it offers significant long-term savings. The durable coating reduces maintenance needs and extends the lifespan of structures. Additionally, the process eliminates the need for large galvanizing vats and related equipment, making it more cost-effective for items of any size.

Environmental Benefits

Zinc spray metallizing is an environmentally friendly option. The process does not involve the use of solvents, meaning no volatile organic compounds (VOCs) are emitted. This is particularly important as environmental regulations on VOC emissions become more stringent. Its minimal environmental impact makes it a preferred choice for sustainable projects.

Immediate Use

One of the significant advantages of zinc spray metallizing is that the coated surfaces can be used immediately after the process is completed. Unlike many paint-based coatings that require curing time, metallized surfaces have virtually no downtime. This immediate usability reduces operational interruptions and associated revenue losses.

Adaptability to Conditions

The metallizing process works under various temperatures and humidity levels, extending the coating season and allowing projects to proceed even during off-season periods. This adaptability increases the feasibility and flexibility of metallizing for different environments.

Superior Surface for Painting

Metallized zinc coatings provide an excellent surface for paint application. The rough texture of the coating enhances the adhesion and durability of subsequent paint layers. This makes zinc spray metallizing an ideal choice for items that will be painted, ensuring a long-lasting and aesthetically pleasing finish.

FDA Approval and Multi-Industry Use

FDA approval for zinc spray metallizing makes it ideal for food preparation equipment and various other food industry applications. Beyond this, the process is utilized across multiple industries, including construction and kitchen equipment manufacturing. Its broad applicability makes it a versatile solution for many industrial needs.

Combination with Other Metals

Zinc can be combined with other metals, such as aluminum, to create specialized coatings like zinc-aluminum alloys. These combinations offer enhanced benefits, including improved corrosion resistance and additional protective properties. The flexibility to tailor the coating composition further extends the advantages of zinc spray metallizing.

By offering superior corrosion resistance, versatility, cost-effectiveness, environmental benefits, and immediate usability, zinc spray metallizing stands out as a highly advantageous method for protecting metal surfaces in various industrial applications.

Applications and Limitations

Key Applications of Zinc Spray Metallizing

Zinc spray metallizing is a versatile coating method used across many industries because of its strong protective qualities. Here are some primary applications:

Corrosion Protection for Steel Structures

The zinc coating protects the steel underneath by sacrificing itself. This is particularly beneficial in marine environments, industrial plants, and infrastructure projects where steel is exposed to harsh conditions.

On-Site and Field Applications

One of the significant advantages of zinc spray metallizing is its adaptability for on-site applications. Unlike hot-dip galvanizing, which requires immersion in a zinc bath, metallizing can be performed directly on large or immovable structures. This makes it ideal for large structures like bridges and pipelines, which cannot be easily moved.

Maintenance and Repair

Zinc spray metallizing is frequently used for maintenance and repair, especially for touching up areas where the original coating is damaged or worn. This provides a quick and effective solution to extend the lifespan of the structure.

Complex and Irregular Shapes

The metallizing process is suitable for coating complex and irregular shapes that might be difficult to treat with other methods. This includes components with recesses, hollows, and cavities, as long as they are accessible for the spraying equipment.

Limitations of Zinc Spray Metallizing

Despite its many benefits, zinc spray metallizing has several limitations that must be considered:

Skilled Labor and Equipment Requirements

The process requires skilled operators and specialized equipment. Proper application is crucial to ensure consistent coating thickness and adhesion. The need for skilled labor can increase the overall cost and limit the availability of qualified personnel.

Coating Thickness Consistency

Achieving a uniform coating thickness can be challenging, especially on corners and edges. The coating tends to be thinner in these areas, which can compromise its protective properties. Skilled operators can mitigate this issue, but it remains a potential drawback.

Adhesion Issues in High Humidity

High humidity during the application process can affect the adhesion of the zinc coating. Ensuring optimal environmental conditions is essential to achieve the best results. Additionally, excessively thick coatings can also lead to adhesion problems.

Access Limitations

While zinc spray metallizing is effective for many shapes and sizes, it is less suitable for structures with deep recesses, hollows, or cavities that are difficult to reach with spraying equipment. This can limit its application in certain complex structures.

Longevity Compared to Hot-Dip Galvanizing

The longevity of zinc spray metallizing coatings is generally shorter than that of hot-dip galvanizing. This means that metallized coatings may require more frequent maintenance and repair, potentially increasing long-term costs.

Cost Considerations

Specialized equipment and skilled labor make zinc spray metallizing more expensive than some other methods. While it offers long-term savings through reduced maintenance, the initial investment can be higher.

Conclusion

Zinc spray metallizing offers numerous advantages, particularly in terms of corrosion protection and versatility for on-site applications. However, its limitations, such as the need for skilled labor, potential adhesion issues, and cost considerations, must be carefully evaluated to ensure it is the right choice for a given project.

Cost Considerations and Skilled Operator Requirements

Zinc Spray Metallizing: Costs and Skilled Operator Requirements

Initial Costs

Zinc spray metallizing, also known as thermal spray coating, has higher initial costs compared to methods like painting. This is primarily due to the need for specialized equipment and skilled labor. However, these upfront expenses are often justified by the long-term benefits and durability of the coating.

Life-Cycle Costs and Application Versatility

One of the main advantages of zinc spray metallizing is its cost-effectiveness over the life cycle of the coated structure. The long-term corrosion protection provided by the zinc coating significantly reduces the need for frequent maintenance and repairs. This results in substantial savings over time, especially in harsh environments such as marine or industrial settings where corrosion is a major concern. For example, a bridge in a coastal environment coated with zinc spray metallizing may require less frequent maintenance, saving significant costs over its lifespan.

The versatility of zinc spray metallizing in terms of application conditions also contributes to its cost-effectiveness. The process does not require solvents or curing time, allowing it to be applied in various environmental conditions, which can help reduce downtime and meet project timelines more efficiently. This flexibility can extend the application season, making it possible to complete projects that might otherwise be delayed due to weather constraints.

Skilled Operator Requirements

Surface Preparation

Proper surface preparation is critical to the success of zinc spray metallizing. Operators must ensure that the surface is thoroughly cleaned and free of contaminants such as oil, grease, and corrosion products. This typically involves abrasive blasting to high cleanliness standards. Proper surface preparation is essential for the adhesion and performance of the zinc coating.

Application Techniques

The application process requires skilled operators who can achieve a uniform coating thickness by spraying in horizontal overlapping lines. The coating must be applied within a specific timeframe after surface preparation to prevent the formation of visible oxides, which can compromise adhesion and coating quality.

Qualification and Training

Operators need to meet specific qualification standards to ensure the quality of the metallizing process. Standards such as AWS C2.20 and SSPC-QP 6 outline the necessary job control records, operator qualifications, and portable adhesion testing. Adherence to these standards ensures that the coatings meet the required specifications and provide long-term protection.

Process Control

Maintaining strict control over the metallizing process is crucial for achieving high-quality coatings. This includes managing factors such as moisture and surface contamination during both preparation and application. Process control helps ensure strong bond strength and uniform coating quality, which are essential for the durability and effectiveness of the zinc coating.

Safety and Quality Assurance

Operators must follow stringent safety guidelines and quality assurance protocols to prevent defects and ensure the integrity of the coatings. This includes post-spray sealing and regular inspections to maintain the protective properties of the coating. Ensuring safety and quality in the metallizing process not only protects the workers but also guarantees the longevity and performance of the coating.

In conclusion, while zinc spray metallizing may have higher initial costs, its long-term cost savings and the need for skilled operators to ensure high-quality coatings make it a worthwhile investment for corrosion protection in various industrial applications.

Case Studies and Real-World Applications

Application in Various Industries

Bridge Structures

Zinc spray metallizing is a highly effective method used to protect bridge structures from corrosion, extending their lifespan significantly. For instance, bridges coated with zinc thermal spraying have demonstrated remarkable durability, with some showing minimal corrosion after decades of exposure to harsh environmental conditions. This extended lifespan reduces the frequency of maintenance and repairs, ultimately lowering the overall lifecycle costs of the bridge.

Marine Environments

In marine environments, zinc spray metallizing offers both a physical barrier and cathodic protection, making it ideal for ships and offshore structures. The sacrificial anode effect of zinc ensures that even if the coating is damaged, the underlying metal remains protected, thereby maintaining the structural integrity of these marine vessels and installations.

Pipelines

Pipelines, especially those located in challenging environments, benefit greatly from zinc spray metallizing. This process ensures long-term protection, which is crucial for pipeline integrity and safety. It is particularly beneficial for pipelines in remote or inaccessible areas where regular maintenance is difficult and costly.

Existing Galvanized Structures

Zinc spray metallizing is also used to extend the life of existing galvanized structures. It is particularly effective in areas where traditional hot-dip galvanizing is not feasible, such as large or complex structures. By applying zinc spray metallizing, these structures receive renewed protection without the need for dismantling or extensive downtime.

Corrosion Protection Mechanism

The effectiveness of zinc spray metallizing lies in its corrosion protection mechanism. The zinc coating acts as a sacrificial anode, corroding preferentially to the steel substrate. This cathodic protection ensures that the underlying steel remains intact even if the zinc layer is compromised. Over time, zinc corrosion products fill the pores in the coating, enhancing its protective properties and maintaining a robust barrier against environmental factors.

Case Studies and Longevity

Numerous case studies highlight the longevity and effectiveness of zinc thermal sprayed coatings:

  • Bridges: Some bridge structures coated with zinc thermal spraying have shown minimal corrosion after several decades of exposure to harsh conditions. This long-term protection has been well-documented in various case histories, demonstrating the reliability of zinc spray metallizing in extending the lifespan of critical infrastructure.
  • Cold-Sprayed Zinc Coatings: Emerging technologies like cold-sprayed zinc coatings have been investigated for their corrosion behavior. These low-temperature variants of thermal spraying can deposit thick, dense coatings rapidly, making them suitable for on-site applications and further enhancing the versatility of zinc spray metallizing.

Practical Considerations

While zinc spray metallizing offers significant advantages, there are practical considerations to keep in mind:

  • The process requires skilled operators and specialized equipment to ensure consistent quality. Additionally, controlling environmental conditions, like humidity, is crucial to maintain coating adhesion.
  • Achieving uniform coating on complex structures can be challenging. Skilled operators can mitigate these inconsistencies, but it remains a factor to consider when planning the application.

Conclusion

Zinc spray metallizing is a proven, versatile solution for protecting steel from corrosion across various industries. Despite some practical challenges, its effectiveness and long-term performance make it invaluable for extending the lifespan of critical infrastructure.

Frequently Asked Questions

Below are answers to some frequently asked questions:

What is the process of zinc spray metallizing?

Zinc spray metallizing is a process where a zinc coating is applied to metal surfaces to protect against corrosion. The process involves thorough surface preparation, typically through abrasive cleaning, followed by feeding zinc wire or powder into a heated gun. The zinc is melted using either a combustion gas flame or an electric arc and then sprayed onto the prepared surface using compressed air. This method is beneficial for large or complex structures that cannot be hot-dip galvanized, although it requires skilled operators and specialized equipment to ensure consistent coating quality.

How is the surface prepared for zinc spray metallizing?

Surface preparation for zinc spray metallizing involves thorough cleaning and blasting to remove contaminants and achieve a near-white metal finish. This process also roughens the surface, enhancing the mechanical bond between the substrate and the zinc coating. The zinc spraying should follow within four hours to prevent oxidation, with environmental conditions controlled to maintain adhesion. Inspections ensure the surface is free of loose material, and any damaged areas are repaired as needed. Compliance with standards like ASTM A780 and SSPC specifications ensures proper adhesion and effective corrosion protection.

What are the benefits of using zinc spray metallizing for corrosion protection?

Zinc spray metallizing offers significant benefits for corrosion protection by forming a protective layer that prevents moisture and oxygen from reaching the metal, thus inhibiting rust formation. The zinc acts as a sacrificial anode, corroding instead of the underlying metal, even if the surface is scratched. This method is known for its quick-drying nature, high durability, and superior anti-corrosive properties due to its high zinc content. Additionally, it is cost-effective, versatile for various applications, and environmentally friendly, generating no toxic by-products and requiring lower temperatures compared to traditional galvanization.

Can zinc spray metallizing be applied to large structures?

Yes, zinc spray metallizing can be applied to large structures. This process involves melting zinc and spraying it onto the surface, making it suitable for field applications where immersion in a galvanizing kettle is impractical. As discussed earlier, the technique allows for uniform coating without the risk of damage from high temperatures and can be applied in various environmental conditions, making it ideal for large-scale projects. However, it requires skilled operators and specialized equipment to ensure consistent quality, which can increase costs. Despite some limitations, it offers effective corrosion protection and flexibility in application.

What are the limitations and costs associated with zinc spray metallizing?

Zinc spray metallizing, while effective for corrosion protection, has several limitations and costs. It requires meticulous surface preparation and skilled labor, increasing both initial and maintenance expenses. The process can result in thinner, rougher coatings that may need frequent repairs, especially compared to hot-dip galvanizing. Environmental conditions can also affect the coating’s adhesion, further complicating the application. Overall, the higher initial costs, need for specialized equipment, and shorter longevity of the coating contribute to the significant expenses associated with zinc spray metallizing.

What are the environmental benefits of zinc spray metallizing?

Zinc spray metallizing offers several environmental benefits, including the absence of volatile organic compound (VOC) emissions, immediate usability without the need for cure time, and the ability to be applied under various ambient conditions, which reduces the need for controlled environments and energy consumption. Its long-lasting corrosion protection minimizes the frequency of maintenance and repairs, thereby reducing the environmental impact over the structure’s lifecycle. Additionally, the process is energy-efficient and versatile, allowing for applications in both shop and field settings, which lowers transportation-related emissions and enhances overall sustainability.

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